Article(id=1314908323992924953, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.04.017, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1770220800000, receivedDateStr=2026-02-05, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428174255, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428174255, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428174255, creator=13701087609, updateTime=1791428174255, updator=13701087609, issue=Issue{id=1314908074188562588, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='4', pageStart='1', pageEnd='266', issueExtLink='null', onlineDate='null', pubDate='1785513600000', pubDateStr='2026-08-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1791428114697, creator='13701087609', updateTime=1791430419337, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314917740654191268, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314917740654191269, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=120, endPage=126, ext={EN=ArticleExt(id=1314908324420743963, articleId=1314908323992924953, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Enhanced Flotation of High-Silicon Bauxite with Combined Collectors and Surfactants and Its Mechanism, columnId=1236276106932842717, journalTitle=Mining and Metallurgical Engineering, columnName=MINERAL PROCESSING, runingTitle=null, highlight=null, articleAbstract=

To realize quality improvement and desiliconization of high-silicon bauxite, binary and ternary collectors were prepared with sodium oleate as the main component, compounded with benzohydroxamic acid, sodium dodecyl sulfonate, sodium dodecyl sulfate and n-octanol, respectively. The effects of single collector, binary collector and ternary collector on the flotation of high-silicon bauxite were systematically investigated. The interaction mechanisms between diaspore and kaolinite in bauxite and the collectors were revealed via contact angle measurement, zeta potential test, Fourier transform infrared spectroscopy and reagent adsorption capacity analysis. The results indicate that flotation performance of binary collectors is obvious superior to that of single collector. Flotation with sodium oleate combined with benzohydroxamic acid at a total dosage of 800 g/t can produce the concentrate with an Al2O3 grade of 56.49% at a recovery of 64.85% and an alumina-to-silica ratio of 2.96. While with a ternary collector composed of sodium oleate, benzohydroxamic acid and sodium dodecyl sulfonate at a total dosage of 1 200 g/t, the flotation can yield the concentrate with an Al2O3 grade of 61.17% at a recovery of 79.84% and an alumina-to-silica ratio of 3.80. The contact angle, zeta potential, infrared spectroscopy and adsorption capacity results demonstrate that both the binary collector and the ternary collector interact more strongly with diaspore than with kaolinite, suggesting that the collectors possess better selective collection of diaspore.

, authors=Jidong GUO1, Yiqing ZHAI1, Biyang TUO1, Ping ZHENG1, Shuanglang LI1, Zhijie WANG1, 2, authorsList=Jidong GUO, Yiqing ZHAI, Biyang TUO, Ping ZHENG, Shuanglang LI, Zhijie WANG, authorCompany=null, correspAuthors=Biyang TUO, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314908324802425628, articleId=1314908323992924953, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=组合捕收剂与表面活性剂强化高硅铝土矿浮选及其机理研究, columnId=1236276107125780707, journalTitle=矿冶工程杂志, columnName=选矿, runingTitle=null, highlight=null, articleAbstract=

为了实现高硅铝土矿的提质脱硅,以油酸钠为主体,分别与苯甲羟肟酸、十二烷基磺酸钠、十二烷基硫酸钠和正辛醇复配成二元、三元组合捕收剂,研究了单一捕收剂、二元组合捕收剂以及三元组合捕收剂对高硅铝土矿浮选效果的影响。通过接触角、Zeta电位、红外光谱和药剂吸附量测试等探究了铝土矿中一水硬铝石和高岭石分别与组合捕收剂的作用机理。结果表明,二元组合捕收剂的浮选效果明显优于单一捕收剂,油酸钠与苯甲羟肟酸组合,总用量800 g/t时,精矿Al2O3品位56.49%、回收率64.85%、铝硅比为2.96;油酸钠、苯甲羟肟酸与十二烷基磺酸钠三元组合,总用量1200 g/t时,精矿Al2O3品位61.17%、回收率79.84%、铝硅比为3.80。接触角、Zeta电位、红外光谱及药剂吸附量测试结果表明,组合捕收剂对一水硬铝石的作用大于对高岭石的作用,表明组合捕收剂对一水硬铝石有着更强的选择捕收性。

, authors=郭吉东1, 翟益庆1, 庹必阳1, 郑平1, 黎双浪1, 王志杰1, 2, authorsList=郭吉东, 翟益庆, 庹必阳, 郑平, 黎双浪, 王志杰, authorCompany=null, correspAuthors=庹必阳, authorNote=

郭吉东(2000—),男,贵州安顺人,硕士研究生,主要研究方向为高硅铝土矿分选。E-mail:

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庹必阳(1979—),男,云南镇雄人,教授,博士研究生导师,主要从事矿石分选和矿物材料方面的教学与科研工作。E-mail:
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组合捕收剂与表面活性剂强化高硅铝土矿浮选及其机理研究
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郭吉东 1 , 翟益庆 1 , 庹必阳 1 , 郑平 1 , 黎双浪 1 , 王志杰 1, 2
矿冶工程杂志 | 选矿 2026,46(4): 120-126
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矿冶工程杂志 |选矿 2026 , 46 (4) : 120 -126
组合捕收剂与表面活性剂强化高硅铝土矿浮选及其机理研究
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郭吉东(2000—),男,贵州安顺人,硕士研究生,主要研究方向为高硅铝土矿分选。E-mail:

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郭吉东1 , 翟益庆1, 庹必阳1 , 郑平1, 黎双浪1, 王志杰1, 2
作者信息
  • 1.贵州大学 矿业学院,贵州 贵阳 550025
  • 2.攀钢集团攀枝花钢铁研究院有限公司,四川 攀枝花 617099
通讯作者:
庹必阳(1979—),男,云南镇雄人,教授,博士研究生导师,主要从事矿石分选和矿物材料方面的教学与科研工作。E-mail:
作者简介:

郭吉东(2000—),男,贵州安顺人,硕士研究生,主要研究方向为高硅铝土矿分选。E-mail:

Enhanced Flotation of High-Silicon Bauxite with Combined Collectors and Surfactants and Its Mechanism
Jidong GUO1 , Yiqing ZHAI1, Biyang TUO1 , Ping ZHENG1, Shuanglang LI1, Zhijie WANG1, 2
Affiliations
  • 1.School of Mining, Guizhou University, Guiyang 550025, Guizhou, China
  • 2.Pangang Group Panzhihua Iron & Steel Research Institute Co., Ltd., Panzhihua 617099, Sichuan, China
doi: 10.3969/j.issn.0253-6099.2026.04.017
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为了实现高硅铝土矿的提质脱硅,以油酸钠为主体,分别与苯甲羟肟酸、十二烷基磺酸钠、十二烷基硫酸钠和正辛醇复配成二元、三元组合捕收剂,研究了单一捕收剂、二元组合捕收剂以及三元组合捕收剂对高硅铝土矿浮选效果的影响。通过接触角、Zeta电位、红外光谱和药剂吸附量测试等探究了铝土矿中一水硬铝石和高岭石分别与组合捕收剂的作用机理。结果表明,二元组合捕收剂的浮选效果明显优于单一捕收剂,油酸钠与苯甲羟肟酸组合,总用量800 g/t时,精矿Al2O3品位56.49%、回收率64.85%、铝硅比为2.96;油酸钠、苯甲羟肟酸与十二烷基磺酸钠三元组合,总用量1200 g/t时,精矿Al2O3品位61.17%、回收率79.84%、铝硅比为3.80。接触角、Zeta电位、红外光谱及药剂吸附量测试结果表明,组合捕收剂对一水硬铝石的作用大于对高岭石的作用,表明组合捕收剂对一水硬铝石有着更强的选择捕收性。

铝土矿  /  捕收剂  /  表面活性剂  /  组合捕收剂  /  浮选  /  脱硅  /  一水硬铝石  /  高岭石

To realize quality improvement and desiliconization of high-silicon bauxite, binary and ternary collectors were prepared with sodium oleate as the main component, compounded with benzohydroxamic acid, sodium dodecyl sulfonate, sodium dodecyl sulfate and n-octanol, respectively. The effects of single collector, binary collector and ternary collector on the flotation of high-silicon bauxite were systematically investigated. The interaction mechanisms between diaspore and kaolinite in bauxite and the collectors were revealed via contact angle measurement, zeta potential test, Fourier transform infrared spectroscopy and reagent adsorption capacity analysis. The results indicate that flotation performance of binary collectors is obvious superior to that of single collector. Flotation with sodium oleate combined with benzohydroxamic acid at a total dosage of 800 g/t can produce the concentrate with an Al2O3 grade of 56.49% at a recovery of 64.85% and an alumina-to-silica ratio of 2.96. While with a ternary collector composed of sodium oleate, benzohydroxamic acid and sodium dodecyl sulfonate at a total dosage of 1 200 g/t, the flotation can yield the concentrate with an Al2O3 grade of 61.17% at a recovery of 79.84% and an alumina-to-silica ratio of 3.80. The contact angle, zeta potential, infrared spectroscopy and adsorption capacity results demonstrate that both the binary collector and the ternary collector interact more strongly with diaspore than with kaolinite, suggesting that the collectors possess better selective collection of diaspore.

bauxite  /  collector  /  surfactant  /  combined collector  /  flotation  /  desiliconization  /  diaspore  /  kaolinite
郭吉东, 翟益庆, 庹必阳, 郑平, 黎双浪, 王志杰. 组合捕收剂与表面活性剂强化高硅铝土矿浮选及其机理研究. 矿冶工程杂志, 2026 , 46 (4) : 120 -126 . DOI: 10.3969/j.issn.0253-6099.2026.04.017
Jidong GUO, Yiqing ZHAI, Biyang TUO, Ping ZHENG, Shuanglang LI, Zhijie WANG. Enhanced Flotation of High-Silicon Bauxite with Combined Collectors and Surfactants and Its Mechanism[J]. Mining and Metallurgical Engineering, 2026 , 46 (4) : 120 -126 . DOI: 10.3969/j.issn.0253-6099.2026.04.017
  • 贵州省研究生科研基金项目(2024YJSKYJJ136)
  • 贵州省科技计划项目(〔2021〕一般482)
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doi: 10.3969/j.issn.0253-6099.2026.04.017
  • 接收时间:2026-02-05
  • 首发时间:2026-10-08
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  • 收稿日期:2026-02-05
基金
贵州省研究生科研基金项目(2024YJSKYJJ136)
贵州省科技计划项目(〔2021〕一般482)
作者信息
    1.贵州大学 矿业学院,贵州 贵阳 550025
    2.攀钢集团攀枝花钢铁研究院有限公司,四川 攀枝花 617099

通讯作者:

庹必阳(1979—),男,云南镇雄人,教授,博士研究生导师,主要从事矿石分选和矿物材料方面的教学与科研工作。E-mail:
参考文献
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https://castjournals.cast.org.cn/joweb/kygczz/CN/10.3969/j.issn.0253-6099.2026.04.017
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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