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The effects of pre-oxidation and coating on the structure and sodium storage performance of resin-based hard carbon were investigated. The study reveals that the combined regulation of pre-oxidation and coating can effectively modify closed pores, graphite microcrystals and defect structures of hard carbon, thereby increasing available sodium ion storage and reversible deintercalation/intercalation sites. The as-synthesized hard carbon delivers a discharge capacity of 399 mAh/g at 0.1C rate, with an initial Coulombic efficiency of 87.3%, and retains 96.4% of this capacity after 50 cycles, which can satisfy the demand of sodium-ion batteries for hard carbon materials with high initial efficiency and long cycling life.

, authors=Gang TANG, Yanhua WANG, Danyang LI, Luhua HE, authorsList=Gang TANG, Yanhua WANG, Danyang LI, Luhua HE, authorCompany=null, correspAuthors=Luhua HE, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314908164978471803, articleId=1314908162508026744, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=树脂基硬碳预氧化与包覆调控机制及储钠性能研究, columnId=1236276110049202322, journalTitle=矿冶工程杂志, columnName=材料, runingTitle=null, highlight=null, articleAbstract=

研究了预氧化和包覆对树脂基硬碳结构以及储钠性能的影响。结果表明，预氧化和包覆联合调控可有效调节硬碳中的闭孔、石墨微晶和缺陷结构，提升钠离子储存位点和可逆钠脱嵌位点。合成的硬碳在0.1C倍率下放电比容量达399 mAh/g，首次库仑效率为87.3%，50次循环后容量保持率达96.4%，满足钠离子电池对高首次库仑效率、长循环性能硬碳负极的需求。

, authors=汤刚, 王艳华, 李丹杨, 何鲁华, authorsList=汤刚, 王艳华, 李丹杨, 何鲁华, authorCompany=null, correspAuthors=何鲁华, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=fjocYk7T+ccM4OxO/JUoUQ==, magXml=9gRxCvtilnnSeXYHHUXLmg==, pdfUrl=null, pdf=MOGbpEVhFGlrD9sfSy65WA==, pdfFileSize=6108447, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=LN1jSrc60voPFZJD/P9tfg==, mapNumber=null, fund=null)}, authors=[Author(id=1314908165813138304, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1314908162508026744, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=20221801055g@stu.cqu.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1314908166219985794, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1314908162508026744, authorId=1314908165813138304, language=EN, stringName=Gang TANG, firstName=Gang, middleName=null, lastName=TANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=Changsha Research Institute of Mining and Metallurgy Co., Ltd., Changsha 410012, Hunan, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1314908166329037699, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1314908162508026744, authorId=1314908165813138304, language=CN, stringName=汤刚, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=长沙矿冶研究院有限责任公司，湖南 长沙 410012, bio={"content":"

汤刚（1990—），男，湖南岳阳人，硕士，主要研究方向为锂/钠离子电池负极材料开发。E-mail: 20221801055g@stu.cqu.edu.cn

"}, bioImg=null, bioContent=

汤刚（1990—），男，湖南岳阳人，硕士，主要研究方向为锂/钠离子电池负极材料开发。E-mail: 20221801055g@stu.cqu.edu.cn

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