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SY-MOF-1 composites with distinctive structures and properties were successfully synthesized using precursors containing hydroxyl, carboxyl, amino and other functional groups. The effects of SY-MOF-1 composites with different functional groups on lead removal from soil were investigated. The results reveal that surface functional groups, specific surface area and pore structure of the functionalized all composites all change remarkably, providing abundant adsorption sites for lead ions. The functionalized SY-MOF-1 composites were used in the remediation of lead-contaminated soil, and the optimal adsorption conditions were determined as follows:solution pH of 6, reaction temperature of 25 ℃ and reaction time of 20 min. It is found that under such conditions, SY-MOF-1-AMP presents a higher adsorption capacity for lead in soil, reaching 146.5 mg/g. The adsorption process of lead onto functionalized SY-MOF-1 composites conforms to the pseudo-second-order kinetic model and Langmuir isothermal adsorption model, indicating that the adsorption is dominated by chemical adsorption and features monolayer adsorption. The functionalized SY-MOF-1 composites exhibit excellent performance in the remediation of lead-contaminated soil. It can serve as an efficient material and a feasible technical route for the treatment of lead-polluted soil, thus possessing promising application prospects.

, authors=Shuwei PANG1, Quanguo CHENG1, Yong ZHAO2, authorsList=Shuwei PANG, Quanguo CHENG, Yong ZHAO, authorCompany=null, correspAuthors=Quanguo CHENG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314908024544781124, articleId=1314908022745424706, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=功能化SY-MOF-1材料的制备及其对土壤中铅的去除, columnId=1236276107322913000, journalTitle=矿冶工程杂志, columnName=冶金, runingTitle=null, highlight=null, articleAbstract=

分别采用含有羟基、羧基、氨基等官能团的前驱体,成功制备出具有独特结构和性能的SY-MOF-1材料,研究了带有不同官能团的SY-MOF-1材料对土壤中铅去除效果的影响。结果表明,功能化SY-MOF-1材料表面官能团、比表面积和孔结构发生显著变化,为铅离子提供了更多吸附位点。将功能化SY-MOF-1材料应用于含铅土壤修复,吸附优化条件为:溶液pH值6、反应温度25 ℃、反应时间20 min,在此条件下,SY-MOF-1-AMP对土壤中铅的吸附容量达到146.5 mg/g。功能化SY-MOF-1材料对铅的吸附过程符合准二级动力学模型以及Langmuir等温吸附模型,表明吸附过程以化学吸附为主,且存在单层吸附特征。功能化SY-MOF-1材料在土壤铅污染修复方面表现出优异的性能,可为土壤铅污染的治理提供一种高效的材料和可行的技术方案,具有良好的应用前景。

, authors=逄淑伟1, 程全国1, 赵勇2, authorsList=逄淑伟, 程全国, 赵勇, authorCompany=null, correspAuthors=程全国, authorNote=

逄淑伟(1979—),山东青岛人,女,硕士,副教授,主要研究方向为环境科学与工程。E-mail:

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程全国(1966—),辽宁鞍山人,男,博士,教授,主要从事环境可持续发展与规划、环境风险管理领域的科研和教学工作。E-mail:
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逄淑伟(1979—),山东青岛人,女,硕士,副教授,主要研究方向为环境科学与工程。E-mail:

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逄淑伟(1979—),山东青岛人,女,硕士,副教授,主要研究方向为环境科学与工程。E-mail:

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功能化SY-MOF-1材料的制备及其对土壤中铅的去除
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逄淑伟 1 , 程全国 1 , 赵勇 2
矿冶工程杂志 | 冶金 2026,46(3): 186-191
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矿冶工程杂志 |冶金 2026 , 46 (3) : 186 -191
功能化SY-MOF-1材料的制备及其对土壤中铅的去除
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逄淑伟1 , 程全国1 , 赵勇2
作者信息
  • 1.沈阳大学 环境学院,辽宁 沈阳 110044
  • 2.辽宁中医药大学杏林学院 就业创业学院,辽宁 沈阳 110135
通讯作者:
程全国(1966—),辽宁鞍山人,男,博士,教授,主要从事环境可持续发展与规划、环境风险管理领域的科研和教学工作。E-mail:
作者简介:

逄淑伟(1979—),山东青岛人,女,硕士,副教授,主要研究方向为环境科学与工程。E-mail:

Preparation of Functionalized SY-MOF-1 Composites and Their Application in Lead Removal from Soil
Shuwei PANG1 , Quanguo CHENG1 , Yong ZHAO2
Affiliations
  • 1.School of Environment, Shenyang University, Shenyang 110044, Liaoning, China
  • 2.School of Employment and Entrepreneurship, Xinglin College of Liaoning University of Traditional Chinese Medicine, Shenyang 110135, Liaoning, China
doi: 10.3969/j.issn.0253-6099.2026.03.027
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分别采用含有羟基、羧基、氨基等官能团的前驱体,成功制备出具有独特结构和性能的SY-MOF-1材料,研究了带有不同官能团的SY-MOF-1材料对土壤中铅去除效果的影响。结果表明,功能化SY-MOF-1材料表面官能团、比表面积和孔结构发生显著变化,为铅离子提供了更多吸附位点。将功能化SY-MOF-1材料应用于含铅土壤修复,吸附优化条件为:溶液pH值6、反应温度25 ℃、反应时间20 min,在此条件下,SY-MOF-1-AMP对土壤中铅的吸附容量达到146.5 mg/g。功能化SY-MOF-1材料对铅的吸附过程符合准二级动力学模型以及Langmuir等温吸附模型,表明吸附过程以化学吸附为主,且存在单层吸附特征。功能化SY-MOF-1材料在土壤铅污染修复方面表现出优异的性能,可为土壤铅污染的治理提供一种高效的材料和可行的技术方案,具有良好的应用前景。

吸附材料  /  金属有机框架材料  /  铅离子  /  土壤修复  /  吸附性能  /  动力学  /  单层吸附

SY-MOF-1 composites with distinctive structures and properties were successfully synthesized using precursors containing hydroxyl, carboxyl, amino and other functional groups. The effects of SY-MOF-1 composites with different functional groups on lead removal from soil were investigated. The results reveal that surface functional groups, specific surface area and pore structure of the functionalized all composites all change remarkably, providing abundant adsorption sites for lead ions. The functionalized SY-MOF-1 composites were used in the remediation of lead-contaminated soil, and the optimal adsorption conditions were determined as follows:solution pH of 6, reaction temperature of 25 ℃ and reaction time of 20 min. It is found that under such conditions, SY-MOF-1-AMP presents a higher adsorption capacity for lead in soil, reaching 146.5 mg/g. The adsorption process of lead onto functionalized SY-MOF-1 composites conforms to the pseudo-second-order kinetic model and Langmuir isothermal adsorption model, indicating that the adsorption is dominated by chemical adsorption and features monolayer adsorption. The functionalized SY-MOF-1 composites exhibit excellent performance in the remediation of lead-contaminated soil. It can serve as an efficient material and a feasible technical route for the treatment of lead-polluted soil, thus possessing promising application prospects.

absorbent  /  metal-organic framework material  /  lead ions  /  soil remediation  /  adsorption performance  /  dynamics  /  monolayer adsorption
逄淑伟, 程全国, 赵勇. 功能化SY-MOF-1材料的制备及其对土壤中铅的去除. 矿冶工程杂志, 2026 , 46 (3) : 186 -191 . DOI: 10.3969/j.issn.0253-6099.2026.03.027
Shuwei PANG, Quanguo CHENG, Yong ZHAO. Preparation of Functionalized SY-MOF-1 Composites and Their Application in Lead Removal from Soil[J]. Mining and Metallurgical Engineering, 2026 , 46 (3) : 186 -191 . DOI: 10.3969/j.issn.0253-6099.2026.03.027
  • 国家自然科学基金面上项目(41571085)
  • 辽宁省民办教育协会课题(LMJX2021358)
  • 沈阳市教科工委课题(SDSZ-2021-141)
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doi: 10.3969/j.issn.0253-6099.2026.03.027
  • 接收时间:2025-11-20
  • 首发时间:2026-10-08
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  • 收稿日期:2025-11-20
基金
国家自然科学基金面上项目(41571085)
辽宁省民办教育协会课题(LMJX2021358)
沈阳市教科工委课题(SDSZ-2021-141)
作者信息
    1.沈阳大学 环境学院,辽宁 沈阳 110044
    2.辽宁中医药大学杏林学院 就业创业学院,辽宁 沈阳 110135

通讯作者:

程全国(1966—),辽宁鞍山人,男,博士,教授,主要从事环境可持续发展与规划、环境风险管理领域的科研和教学工作。E-mail:
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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