Article(id=1314907832525349798, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907832038810534, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.02.024, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1768233600000, receivedDateStr=2026-01-13, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428057079, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428057079, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428057079, creator=13701087609, updateTime=1791428057079, updator=13701087609, issue=Issue{id=1314907832038810534, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='2', pageStart='1', pageEnd='214', issueExtLink='null', onlineDate='null', pubDate='1774972800000', pubDateStr='2026-04-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791428056964, creator='13701087609', updateTime=1791430468655, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314917947500486818, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907832038810534, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314917947500486819, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907832038810534, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=150, endPage=155, ext={EN=ArticleExt(id=1314907832701510567, articleId=1314907832525349798, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Surfactant-Assisted Ultrasonic Separation Process for Copper Foil and Graphite in Anode Sheets of Spent Lithium-Ion Batteries, columnId=1236276106727321817, journalTitle=Mining and Metallurgical Engineering, columnName=METALLURGY, runingTitle=null, highlight=null, articleAbstract=

Anode sheets of spent lithium-ion batteries were taken for research, and an L25(54) orthogonal test was employed to investigate the effects of ultrasonic temperature, ultrasonic time, ultrasonic frequency and solid-liquid ratio on the separation efficiency of graphite and copper foil in a system with an addition of 0.5% surfactant. A system without surfactant was taken as the control group. The results show that the graphite separation efficiency reaches 95.75% in a system with an addition of 0.5% surfactant, by ultrasonic separation at 90 ℃ for 15 min with a frequency of 100 kHz and solid-liquid ratio of 1∶9. The recovered graphite is basically consistent with those of standard graphite in terms of the XRD diffraction peaks and has a low proportion of disordered structure. The recovered copper foil exhibits favorable mechanical properties, with a tensile strength of 180-190 MPa, and its carrier mobility is 35.68 cm2/(V·s), indicating excellent electrical conductivity.

, authors=Zhiqiang ZHENG1, 2, Yisheng YANG1, 2, Zifang XU1, Lijie DING2, Maoqin QIU3, Wenming LI1, 2, authorsList=Zhiqiang ZHENG, Yisheng YANG, Zifang XU, Lijie DING, Maoqin QIU, Wenming LI, authorCompany=null, correspAuthors=Lijie DING, Maoqin QIU, Wenming LI, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314907833037054888, articleId=1314907832525349798, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=表面活性剂协同超声分离废旧锂离子电池负极片中石墨和铜箔工艺研究, columnId=1236276107322913000, journalTitle=矿冶工程杂志, columnName=冶金, runingTitle=null, highlight=null, articleAbstract=

以废旧锂离子电池负极片为研究对象,采用L25(54)正交试验,在添加0.5%表面活性剂的体系中,考察超声温度、超声时间、超声频率、固液比对石墨和铜箔分离率的影响,并设置无表面活性剂体系作为对照。结果表明,在表面活性剂添加量0.5%、超声温度90 ℃、超声时间15 min、超声频率100 kHz、固液比1∶9条件下,石墨分离率可达95.75%。回收石墨的XRD衍射峰与标准石墨基本一致,无序结构占比较低。回收铜箔抗拉强度为180~190 MPa,力学性能良好;载流子迁移率为35.68 cm2/(V·s),具备良好的导电性能。

, authors=郑志强1, 2, 杨义升1, 2, 徐子芳1, 丁李杰2, 邱茂琴3, 李文明1, 2, authorsList=郑志强, 杨义升, 徐子芳, 丁李杰, 邱茂琴, 李文明, authorCompany=null, correspAuthors=丁李杰, 邱茂琴, 李文明, authorNote=

郑志强(1998-),男,安徽合肥人,硕士研究生,主要研究方向为锂离子电池材料。E-mail:

, correspAuthorsNote=
李文明(1986-),男,安徽亳州人,博士,副研究员,主要从事新能源材料的高值化制备与回收产业化。E-mail:
丁李杰(1994-),男,安徽滁州人,硕士,主要从事电池回收再生资源化利用。E-mail:
邱茂琴(1986-),女,四川眉山人,博士,主要从事新能源材料的高值化制备与回收产业化。E-mail:
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表面活性剂协同超声分离废旧锂离子电池负极片中石墨和铜箔工艺研究
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郑志强 1, 2 , 杨义升 1, 2 , 徐子芳 1 , 丁李杰 2 , 邱茂琴 3 , 李文明 1, 2
矿冶工程杂志 | 冶金 2026,46(2): 150-155
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矿冶工程杂志 |冶金 2026 , 46 (2) : 150 -155
表面活性剂协同超声分离废旧锂离子电池负极片中石墨和铜箔工艺研究
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2.合肥综合性国家科学中心能源研究院(安徽省能源实验室),安徽 合肥 230051, bio={"content":"

郑志强(1998-),男,安徽合肥人,硕士研究生,主要研究方向为锂离子电池材料。E-mail:

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郑志强(1998-),男,安徽合肥人,硕士研究生,主要研究方向为锂离子电池材料。E-mail:

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郑志强1, 2 , 杨义升1, 2, 徐子芳1, 丁李杰2 , 邱茂琴3 , 李文明1, 2
作者信息
  • 1.安徽理工大学,安徽 淮南 232001
  • 2.合肥综合性国家科学中心能源研究院(安徽省能源实验室),安徽 合肥 230051
  • 3.合肥职业技术学院 安徽 合肥 230012
通讯作者:
李文明(1986-),男,安徽亳州人,博士,副研究员,主要从事新能源材料的高值化制备与回收产业化。E-mail:
丁李杰(1994-),男,安徽滁州人,硕士,主要从事电池回收再生资源化利用。E-mail:
邱茂琴(1986-),女,四川眉山人,博士,主要从事新能源材料的高值化制备与回收产业化。E-mail:
作者简介:

郑志强(1998-),男,安徽合肥人,硕士研究生,主要研究方向为锂离子电池材料。E-mail:

Surfactant-Assisted Ultrasonic Separation Process for Copper Foil and Graphite in Anode Sheets of Spent Lithium-Ion Batteries
Zhiqiang ZHENG1, 2 , Yisheng YANG1, 2, Zifang XU1, Lijie DING2 , Maoqin QIU3 , Wenming LI1, 2
Affiliations
  • 1.Anhui University of Science and Technology, Huainan 232001, Anhui, China
  • 2.Institute of Energy, Hefei Comprehensive National Science Center (Anhui Energy Laboratory), Hefei 230051, Anhui, China
  • 3.Hefei Technology College, Hefei 230012, Anhui, China
doi: 10.3969/j.issn.0253-6099.2026.02.024
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以废旧锂离子电池负极片为研究对象,采用L25(54)正交试验,在添加0.5%表面活性剂的体系中,考察超声温度、超声时间、超声频率、固液比对石墨和铜箔分离率的影响,并设置无表面活性剂体系作为对照。结果表明,在表面活性剂添加量0.5%、超声温度90 ℃、超声时间15 min、超声频率100 kHz、固液比1∶9条件下,石墨分离率可达95.75%。回收石墨的XRD衍射峰与标准石墨基本一致,无序结构占比较低。回收铜箔抗拉强度为180~190 MPa,力学性能良好;载流子迁移率为35.68 cm2/(V·s),具备良好的导电性能。

废旧锂离子电池  /  超声分离  /  表面活性剂  /  负极片  /  铜箔  /  石墨

Anode sheets of spent lithium-ion batteries were taken for research, and an L25(54) orthogonal test was employed to investigate the effects of ultrasonic temperature, ultrasonic time, ultrasonic frequency and solid-liquid ratio on the separation efficiency of graphite and copper foil in a system with an addition of 0.5% surfactant. A system without surfactant was taken as the control group. The results show that the graphite separation efficiency reaches 95.75% in a system with an addition of 0.5% surfactant, by ultrasonic separation at 90 ℃ for 15 min with a frequency of 100 kHz and solid-liquid ratio of 1∶9. The recovered graphite is basically consistent with those of standard graphite in terms of the XRD diffraction peaks and has a low proportion of disordered structure. The recovered copper foil exhibits favorable mechanical properties, with a tensile strength of 180-190 MPa, and its carrier mobility is 35.68 cm2/(V·s), indicating excellent electrical conductivity.

spent lithium-ion battery  /  ultrasonic separation  /  surfactant  /  anode sheet  /  copper foil  /  graphite
郑志强, 杨义升, 徐子芳, 丁李杰, 邱茂琴, 李文明. 表面活性剂协同超声分离废旧锂离子电池负极片中石墨和铜箔工艺研究. 矿冶工程杂志, 2026 , 46 (2) : 150 -155 . DOI: 10.3969/j.issn.0253-6099.2026.02.024
Zhiqiang ZHENG, Yisheng YANG, Zifang XU, Lijie DING, Maoqin QIU, Wenming LI. Surfactant-Assisted Ultrasonic Separation Process for Copper Foil and Graphite in Anode Sheets of Spent Lithium-Ion Batteries[J]. Mining and Metallurgical Engineering, 2026 , 46 (2) : 150 -155 . DOI: 10.3969/j.issn.0253-6099.2026.02.024
  • 安徽省教育厅高校科研重点项目(2025AHGXZK31123)
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doi: 10.3969/j.issn.0253-6099.2026.02.024
  • 接收时间:2026-01-13
  • 首发时间:2026-10-08
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  • 收稿日期:2026-01-13
基金
安徽省教育厅高校科研重点项目(2025AHGXZK31123)
作者信息
    1.安徽理工大学,安徽 淮南 232001
    2.合肥综合性国家科学中心能源研究院(安徽省能源实验室),安徽 合肥 230051
    3.合肥职业技术学院 安徽 合肥 230012

通讯作者:

李文明(1986-),男,安徽亳州人,博士,副研究员,主要从事新能源材料的高值化制备与回收产业化。E-mail:
丁李杰(1994-),男,安徽滁州人,硕士,主要从事电池回收再生资源化利用。E-mail:
邱茂琴(1986-),女,四川眉山人,博士,主要从事新能源材料的高值化制备与回收产业化。E-mail:
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https://castjournals.cast.org.cn/joweb/kygczz/CN/10.3969/j.issn.0253-6099.2026.02.024
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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