Article(id=1314907722504569117, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907656704324517, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.01.018, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1756828800000, receivedDateStr=2025-09-03, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428030849, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428030849, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428030849, creator=13701087609, updateTime=1791428030849, updator=13701087609, issue=Issue{id=1314907656704324517, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='1', pageStart='1', pageEnd='206', issueExtLink='null', onlineDate='null', pubDate='1769875200000', pubDateStr='2026-02-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791428015160, creator='13701087609', updateTime=1791430491940, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314918045139690301, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907656704324517, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314918045139690302, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907656704324517, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=108, endPage=113, ext={EN=ArticleExt(id=1314907724270371102, articleId=1314907722504569117, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Synthesis of Iron Phosphate and Fe/P Carbon-Based Oxygen Reduction Catalyst for Efficient Recycling of Iron Phosphate Slag, columnId=1236276106727321817, journalTitle=Mining and Metallurgical Engineering, columnName=METALLURGY, runingTitle=null, highlight=null, articleAbstract=

With iron phosphate slag as raw material, Fe and P elements were extracted by acid leaching, which was then used to synthesize battery-grade iron phosphate. Meanwhile, activated carbon and carbon nanotubes were introduced to adsorb the residual Fe and P elements in the leachate, and then high-performance Fe/P oxygen reduction catalysts (FP-6) were prepared by calcination. The results show that the FP-6 catalyst exhibits a half-wave potential of-0.037 V (vs.Hg/HgO) in 0.1 mol/L KOH solution, demonstrating excellent oxygen reduction catalytic activity. With FP-6 as the cathode catalyst, the zinc-air batteries can deliver a specific capacity of 780 mAh/g and a power density of 121 mW/cm2, and stably cycle for 182 h at a high current density of 5 mA/cm2. This study provides a low-cost and sustainable approach for efficient recycling of iron phosphate slag and resource utilization.

, authors=Huijie WANG1, Yilan WU2, Zhongyue JIA3, Xiangqun ZHUGE1, Kun LUO1, authorsList=Huijie WANG, Yilan WU, Zhongyue JIA, Xiangqun ZHUGE, Kun LUO, authorCompany=null, correspAuthors=Kun LUO, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314907725528662304, articleId=1314907722504569117, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=磷铁渣高效回收制备磷酸铁和Fe/P碳基氧还原催化剂的研究, columnId=1236276107322913000, journalTitle=矿冶工程杂志, columnName=冶金, runingTitle=null, highlight=null, articleAbstract=

以磷铁渣为原料,采用酸浸法提取Fe、P元素合成电池级磷酸铁;同时引入活性炭和碳纳米管对浸出液中残留Fe、P元素进行吸附富集,经焙烧制备得高性能Fe/P氧还原催化剂(FP-6)。结果表明,FP-6催化剂在0.1 mol/L KOH溶液中半波电位达到-0.037 V(vs.Hg/HgO),具有优良的氧还原催化活性;用作锌空气电池正极催化剂时,电池比容量可达780 mAh/g,功率密度为121 mW/cm2,且在5 mA/cm2高电流密度下可稳定循环182 h。本研究为磷铁渣高效回收与资源化再利用提供了低成本、可持续开发的新思路。

, authors=王慧洁1, 吴一览2, 贾中悦3, 诸葛祥群1, 罗鲲1, authorsList=王慧洁, 吴一览, 贾中悦, 诸葛祥群, 罗鲲, authorCompany=null, correspAuthors=罗鲲, authorNote=

王慧洁(2000—),女,江苏盐城人,硕士,研究方向为磷铁矿回收。E-mail:

, correspAuthorsNote=
罗鲲(1966—),男,辽宁沈阳人,博士,教授,硕士研究生导师,主要从事电化学储能和电池材料回收研究。E-mail:
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王慧洁(2000—),女,江苏盐城人,硕士,研究方向为磷铁矿回收。E-mail:

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磷铁渣高效回收制备磷酸铁和Fe/P碳基氧还原催化剂的研究
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王慧洁 1 , 吴一览 2 , 贾中悦 3 , 诸葛祥群 1 , 罗鲲 1
矿冶工程杂志 | 冶金 2026,46(1): 108-113
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矿冶工程杂志 |冶金 2026 , 46 (1) : 108 -113
磷铁渣高效回收制备磷酸铁和Fe/P碳基氧还原催化剂的研究
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王慧洁1 , 吴一览2, 贾中悦3, 诸葛祥群1, 罗鲲1
作者信息
  • 1.常州大学材料科学与工程学院,江苏 常州 213164
  • 2.浙江大有实业有限公司,浙江 杭州 310000
  • 3.常州威斯顿机器人科技有限公司,江苏 常州 213125
通讯作者:
罗鲲(1966—),男,辽宁沈阳人,博士,教授,硕士研究生导师,主要从事电化学储能和电池材料回收研究。E-mail:
作者简介:

王慧洁(2000—),女,江苏盐城人,硕士,研究方向为磷铁矿回收。E-mail:

Synthesis of Iron Phosphate and Fe/P Carbon-Based Oxygen Reduction Catalyst for Efficient Recycling of Iron Phosphate Slag
Huijie WANG1 , Yilan WU2, Zhongyue JIA3, Xiangqun ZHUGE1, Kun LUO1
Affiliations
  • 1.School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China
  • 2.Zhejiang Dayou Industrial Co., Ltd., Hangzhou 310000, Zhejiang, China
  • 3.Changzhou Wisdom Robot Technology Co.Ltd., Changzhou 213125, Jiangsu, China
doi: 10.3969/j.issn.0253-6099.2026.01.018
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以磷铁渣为原料,采用酸浸法提取Fe、P元素合成电池级磷酸铁;同时引入活性炭和碳纳米管对浸出液中残留Fe、P元素进行吸附富集,经焙烧制备得高性能Fe/P氧还原催化剂(FP-6)。结果表明,FP-6催化剂在0.1 mol/L KOH溶液中半波电位达到-0.037 V(vs.Hg/HgO),具有优良的氧还原催化活性;用作锌空气电池正极催化剂时,电池比容量可达780 mAh/g,功率密度为121 mW/cm2,且在5 mA/cm2高电流密度下可稳定循环182 h。本研究为磷铁渣高效回收与资源化再利用提供了低成本、可持续开发的新思路。

磷铁渣  /  磷酸铁  /  Fe/P碳基催化剂  /  锌空气电池  /  酸浸

With iron phosphate slag as raw material, Fe and P elements were extracted by acid leaching, which was then used to synthesize battery-grade iron phosphate. Meanwhile, activated carbon and carbon nanotubes were introduced to adsorb the residual Fe and P elements in the leachate, and then high-performance Fe/P oxygen reduction catalysts (FP-6) were prepared by calcination. The results show that the FP-6 catalyst exhibits a half-wave potential of-0.037 V (vs.Hg/HgO) in 0.1 mol/L KOH solution, demonstrating excellent oxygen reduction catalytic activity. With FP-6 as the cathode catalyst, the zinc-air batteries can deliver a specific capacity of 780 mAh/g and a power density of 121 mW/cm2, and stably cycle for 182 h at a high current density of 5 mA/cm2. This study provides a low-cost and sustainable approach for efficient recycling of iron phosphate slag and resource utilization.

phosphorus iron slag  /  iron phosphate  /  Fe/P carbon-based catalyst  /  zinc-air battery  /  acid leaching
王慧洁, 吴一览, 贾中悦, 诸葛祥群, 罗鲲. 磷铁渣高效回收制备磷酸铁和Fe/P碳基氧还原催化剂的研究. 矿冶工程杂志, 2026 , 46 (1) : 108 -113 . DOI: 10.3969/j.issn.0253-6099.2026.01.018
Huijie WANG, Yilan WU, Zhongyue JIA, Xiangqun ZHUGE, Kun LUO. Synthesis of Iron Phosphate and Fe/P Carbon-Based Oxygen Reduction Catalyst for Efficient Recycling of Iron Phosphate Slag[J]. Mining and Metallurgical Engineering, 2026 , 46 (1) : 108 -113 . DOI: 10.3969/j.issn.0253-6099.2026.01.018
  • 国家自然科学基金(52474431)
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doi: 10.3969/j.issn.0253-6099.2026.01.018
  • 接收时间:2025-09-03
  • 首发时间:2026-10-08
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  • 收稿日期:2025-09-03
基金
国家自然科学基金(52474431)
作者信息
    1.常州大学材料科学与工程学院,江苏 常州 213164
    2.浙江大有实业有限公司,浙江 杭州 310000
    3.常州威斯顿机器人科技有限公司,江苏 常州 213125

通讯作者:

罗鲲(1966—),男,辽宁沈阳人,博士,教授,硕士研究生导师,主要从事电化学储能和电池材料回收研究。E-mail:
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https://castjournals.cast.org.cn/joweb/kygczz/CN/10.3969/j.issn.0253-6099.2026.01.018
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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