Article(id=1314907691416387762, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907656704324517, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.01.012, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1756656000000, receivedDateStr=2025-09-01, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428023437, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428023437, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428023437, creator=13701087609, updateTime=1791428023437, updator=13701087609, issue=Issue{id=1314907656704324517, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='1', pageStart='1', pageEnd='206', issueExtLink='null', onlineDate='null', pubDate='1769875200000', pubDateStr='2026-02-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791428015160, creator='13701087609', updateTime=1791430491940, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314918045139690301, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907656704324517, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314918045139690302, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907656704324517, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=73, endPage=79, ext={EN=ArticleExt(id=1314907693916192947, articleId=1314907691416387762, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Enhancement Mechanisms of Acid and Alkaline Corrosion for Flotation Separation of Lepidolite and Feldspar: Influences of Surface Properties and Particle Size, columnId=1236276106932842717, journalTitle=Mining and Metallurgical Engineering, columnName=MINERAL PROCESSING, runingTitle=null, highlight=null, articleAbstract=

Based on investigation of the influence mechanisms of acid and alkaline corrosion for flotation separation of lepidolite and feldspar, efficient separation of lepidolite and feldspar in different particle size fractions was achieved by flotation with surface dissolution and collector interaction. It is found that in flotation process, alkaline corrosion can promote the separation of lepidolite and feldspar more effectively than acid corrosion. Under optimal conditions, lepidolite concentrates in size fraction of 38-74 μm and-38 μm are obtained with recoveries of Li2O at 92.54% and 83.20%, respectively. The effects of acid and alkaline corrosion on the wettability, morphology, reagent adsorption and electrical potential of the mineral surface were explored by contact angle measurements, high-speed camera observations, SEM, AFM, XPS, infrared spectroscopy and zeta potential analyses. Results show that alkaline corrosion, due to its distinct mechanisms at the surfaces of lepidolite and feldspar, can promote the separation between them; whereas acid corrosion has no selectivity for two minerals. Besides, both acid and alkaline corrosion are independent of particle size of minerals.

, authors=Zheyi ZHANG1, 2, Ying LUO1, 2, Qian WEI1, 2, Fen JIAO1, 2, authorsList=Zheyi ZHANG, Ying LUO, Qian WEI, Fen JIAO, authorCompany=null, correspAuthors=Fen JIAO, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314907695124152500, articleId=1314907691416387762, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=酸碱蚀对浮选分离锂云母和长石的增效机制:表面性质与颗粒尺寸的影响, columnId=1236276107125780707, journalTitle=矿冶工程杂志, columnName=选矿, runingTitle=null, highlight=null, articleAbstract=

研究了酸蚀和碱蚀作用对锂云母和长石浮选分离的影响机制,通过表面溶蚀和捕收剂作用实现了不同粒级锂云母与长石的高效浮选分离,结果显示,碱蚀作用比酸蚀作用更能促进锂云母和长石的浮选分离,在适宜条件下,38~74 μm粒级和-38 μm粒级锂云母精矿的Li2O回收率分别为92.54%和83.20%。通过接触角测试、高速摄影机观测以及SEM、AFM、XPS、红外光谱测试等研究了酸蚀和碱蚀对矿物表面润湿性、形貌、药剂吸附及电位的影响,结果表明,碱蚀作用对锂云母和长石表面不同的作用机制促进了两种矿物的浮选分离,而酸蚀作用对矿物表面的溶蚀没有选择性;两种溶蚀作用的效果均不受矿物粒级的影响。

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张喆怡(1997—)女,陕西西安人,博士研究生,主要研究方向为复杂难选微细粒矿物的回收技术。E-mail:

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焦芬(1983—),女,山西运城人,博士,教授,主要研究方向为复杂难处理矿产资源分离与综合利用基础理论与应用、再生资源高效清洁利用。E-mail:
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张喆怡(1997—)女,陕西西安人,博士研究生,主要研究方向为复杂难选微细粒矿物的回收技术。E-mail:

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张喆怡(1997—)女,陕西西安人,博士研究生,主要研究方向为复杂难选微细粒矿物的回收技术。E-mail:

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张喆怡 1, 2 , 罗颖 1, 2 , 魏茜 1, 2 , 焦芬 1, 2
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酸碱蚀对浮选分离锂云母和长石的增效机制:表面性质与颗粒尺寸的影响
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张喆怡(1997—)女,陕西西安人,博士研究生,主要研究方向为复杂难选微细粒矿物的回收技术。E-mail:

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张喆怡(1997—)女,陕西西安人,博士研究生,主要研究方向为复杂难选微细粒矿物的回收技术。E-mail:

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张喆怡1, 2 , 罗颖1, 2, 魏茜1, 2, 焦芬1, 2
作者信息
  • 1.中南大学矿物加工与生物工程学院,湖南 长沙 410083
  • 2.中南大学湖南省战略含钙矿物资源清洁高效利用重点实验室,湖南 长沙 410083
通讯作者:
焦芬(1983—),女,山西运城人,博士,教授,主要研究方向为复杂难处理矿产资源分离与综合利用基础理论与应用、再生资源高效清洁利用。E-mail:
作者简介:

张喆怡(1997—)女,陕西西安人,博士研究生,主要研究方向为复杂难选微细粒矿物的回收技术。E-mail:

Enhancement Mechanisms of Acid and Alkaline Corrosion for Flotation Separation of Lepidolite and Feldspar: Influences of Surface Properties and Particle Size
Zheyi ZHANG1, 2 , Ying LUO1, 2, Qian WEI1, 2, Fen JIAO1, 2
Affiliations
  • 1.School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, Hunan, China
  • 2.Key Laboratory of Hunan Province for Clean and Efficient Utilization of Strategic Calcium-Containing Mineral Resources, Central South University, Changsha 410083, Hunan, China
doi: 10.3969/j.issn.0253-6099.2026.01.012
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研究了酸蚀和碱蚀作用对锂云母和长石浮选分离的影响机制,通过表面溶蚀和捕收剂作用实现了不同粒级锂云母与长石的高效浮选分离,结果显示,碱蚀作用比酸蚀作用更能促进锂云母和长石的浮选分离,在适宜条件下,38~74 μm粒级和-38 μm粒级锂云母精矿的Li2O回收率分别为92.54%和83.20%。通过接触角测试、高速摄影机观测以及SEM、AFM、XPS、红外光谱测试等研究了酸蚀和碱蚀对矿物表面润湿性、形貌、药剂吸附及电位的影响,结果表明,碱蚀作用对锂云母和长石表面不同的作用机制促进了两种矿物的浮选分离,而酸蚀作用对矿物表面的溶蚀没有选择性;两种溶蚀作用的效果均不受矿物粒级的影响。

锂云母  /  长石  /  表面溶蚀  /  浮选分离  /  酸蚀  /  碱蚀

Based on investigation of the influence mechanisms of acid and alkaline corrosion for flotation separation of lepidolite and feldspar, efficient separation of lepidolite and feldspar in different particle size fractions was achieved by flotation with surface dissolution and collector interaction. It is found that in flotation process, alkaline corrosion can promote the separation of lepidolite and feldspar more effectively than acid corrosion. Under optimal conditions, lepidolite concentrates in size fraction of 38-74 μm and-38 μm are obtained with recoveries of Li2O at 92.54% and 83.20%, respectively. The effects of acid and alkaline corrosion on the wettability, morphology, reagent adsorption and electrical potential of the mineral surface were explored by contact angle measurements, high-speed camera observations, SEM, AFM, XPS, infrared spectroscopy and zeta potential analyses. Results show that alkaline corrosion, due to its distinct mechanisms at the surfaces of lepidolite and feldspar, can promote the separation between them; whereas acid corrosion has no selectivity for two minerals. Besides, both acid and alkaline corrosion are independent of particle size of minerals.

lepidolite  /  feldspar  /  surface corrosion  /  flotation separation  /  acid corrosion  /  alkaline corrosion
张喆怡, 罗颖, 魏茜, 焦芬. 酸碱蚀对浮选分离锂云母和长石的增效机制:表面性质与颗粒尺寸的影响. 矿冶工程杂志, 2026 , 46 (1) : 73 -79 . DOI: 10.3969/j.issn.0253-6099.2026.01.012
Zheyi ZHANG, Ying LUO, Qian WEI, Fen JIAO. Enhancement Mechanisms of Acid and Alkaline Corrosion for Flotation Separation of Lepidolite and Feldspar: Influences of Surface Properties and Particle Size[J]. Mining and Metallurgical Engineering, 2026 , 46 (1) : 73 -79 . DOI: 10.3969/j.issn.0253-6099.2026.01.012
  • 湖南省杰出青年科学基金项目(2023JJ10070)
  • 国家自然科学基金(52474317; 52304316)
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doi: 10.3969/j.issn.0253-6099.2026.01.012
  • 接收时间:2025-09-01
  • 首发时间:2026-10-08
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  • 收稿日期:2025-09-01
基金
湖南省杰出青年科学基金项目(2023JJ10070)
国家自然科学基金(52474317; 52304316)
作者信息
    1.中南大学矿物加工与生物工程学院,湖南 长沙 410083
    2.中南大学湖南省战略含钙矿物资源清洁高效利用重点实验室,湖南 长沙 410083

通讯作者:

焦芬(1983—),女,山西运城人,博士,教授,主要研究方向为复杂难处理矿产资源分离与综合利用基础理论与应用、再生资源高效清洁利用。E-mail:
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https://castjournals.cast.org.cn/joweb/kygczz/CN/10.3969/j.issn.0253-6099.2026.01.012
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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