Article(id=1314907219745923707, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907112854089785, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2025.06.022, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1756396800000, receivedDateStr=2025-08-29, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791427910981, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791427910981, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791427910981, creator=13701087609, updateTime=1791427910981, updator=13701087609, issue=Issue{id=1314907112854089785, tenantId=1146029695717560320, journalId=1235980550691926019, year='2025', volume='45', issue='6', pageStart='1', pageEnd='228', issueExtLink='null', onlineDate='null', pubDate='1764518400000', pubDateStr='2025-12-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791427885497, creator='13701087609', updateTime=1791430521754, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314918170201252492, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907112854089785, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314918170201252493, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907112854089785, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=124, endPage=129, ext={EN=ArticleExt(id=1314907220257628796, articleId=1314907219745923707, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Occurrence State of Tin and Indium in Tin Smelting Dust and Corresponding Separation Method, columnId=1236276106727321817, journalTitle=Mining and Metallurgical Engineering, columnName=METALLURGY, runingTitle=null, highlight=null, articleAbstract=

With the dust from a tin smelter as raw material, the occurrence state of tin (Sn) and indium (In) therein was firstly studied. Then, a combined processing technique consisting of water leaching and oxidative acid leaching was adopted to separate and recover the key elements of Sn, In, Zn and Cd from the tin smelting dust, and effects of factors including suluric acid concentration, liquid-solid ratio, reaction temperature and reaction time on the leaching process were explored. The results show that Sn and In in the tin smelting dust mainly exist in the forms of SnO2, In2S3 and Zn2SnO4. After water leaching treatment, the dust was leached with sulfuric acid at a concentration of 200 g/L by adding potassium permanganate at a dosage of 1.5%, with liquid-solid ratio of 5.0, at a temperature of 65 ℃ for 120 min, resulting in the leaching rates of In, Zn and Cd at 82.00%, 95.60% and 94.30% respectively, while the leaching rate of Sn at 0.84%. After such treatment, the Sn content in the dust increased from 42.44% to 60.87% with an enrichment ratio of 1.43. The particles of the acid leaching residue were porous on the surface, showing that the dust with dense structure changed to the residue with loose one. This tin-rich acid leaching residue with low impurity content can be back to tin smelting process, and indium can go to the subsequent process for extraction and recovery. By this way, efficient recovery and utilization of valuable metals from tin smelting dust can be actualized.

, authors=Lishi CHEN1, 2, Pengcheng LI3, Meizhen WU1, Ruichun SU1, Tongwen FAN3, Zhang ZHANG3, Qingdong LIU2, 3, authorsList=Lishi CHEN, Pengcheng LI, Meizhen WU, Ruichun SU, Tongwen FAN, Zhang ZHANG, Qingdong LIU, authorCompany=null, correspAuthors=Qingdong LIU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314907220635116158, articleId=1314907219745923707, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=锡冶炼烟尘中锡、铟赋存形态及分离富集研究, columnId=1236276107322913000, journalTitle=矿冶工程杂志, columnName=冶金, runingTitle=null, highlight=null, articleAbstract=

以锡冶炼厂烟尘为原料,对其中Sn、In的赋存形态及分布特性进行研究,采用水浸-氧化酸浸联合工艺分离回收锡冶炼烟尘中的Sn、In、Zn、Cd关键元素,考察了硫酸质量浓度、液固比、浸出温度、浸出时间等因素对浸出效果的影响。结果表明,锡冶炼烟尘中Sn、In主要以SnO2、In2S3和Zn2SnO4形式存在。经水浸处理后,在硫酸质量浓度200 g/L、浸出温度65 ℃、浸出时间120 min、浸出液固比5.0、高锰酸钾添加量1.5%条件下氧化酸浸,In、Zn、Cd浸出率分别为82.00%、95.60%、94.30%,Sn浸出率为0.84%;经水浸-氧化酸浸工艺处理后,Sn含量从42.44%提高至60.87%,富集比为1.43。沉淀物酸浸渣颗粒表面呈多孔结构,由烟尘的致密状转变为蓬松状结构,该低杂质含量富锡酸浸渣可返回锡熔炼工序,铟进入萃取回收工序,实现锡冶炼烟尘中有价金属高效回收利用。

, authors=陈丽诗1, 2, 李鹏程3, 伍美珍1, 苏瑞春1, 范桐文3, 张璋3, 刘庆东2, 3, authorsList=陈丽诗, 李鹏程, 伍美珍, 苏瑞春, 范桐文, 张璋, 刘庆东, authorCompany=null, correspAuthors=刘庆东, authorNote=

陈丽诗(1992—),女,云南文山人,硕士,工程师,主要从事稀有金属材料研究。E-mail:

, correspAuthorsNote=
刘庆东(1981—),男,湖南澧县人,硕士,高级工程师,主要从事稀有金属材料研究。E-mail:
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锡冶炼烟尘中锡、铟赋存形态及分离富集研究
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陈丽诗 1, 2 , 李鹏程 3 , 伍美珍 1 , 苏瑞春 1 , 范桐文 3 , 张璋 3 , 刘庆东 2, 3
矿冶工程杂志 | 冶金 2025,45(6): 124-129
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矿冶工程杂志 |冶金 2025 , 45 (6) : 124 -129
锡冶炼烟尘中锡、铟赋存形态及分离富集研究
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陈丽诗1, 2 , 李鹏程3, 伍美珍1, 苏瑞春1, 范桐文3, 张璋3, 刘庆东2, 3
作者信息
  • 1.云南锡铟实验室有限公司,云南 昆明 650106
  • 2.昆明理工大学冶金与能源工程学院,云南 昆明 650093
  • 3.云南锡业股份有限公司锡业分公司,云南 个旧 661017
通讯作者:
刘庆东(1981—),男,湖南澧县人,硕士,高级工程师,主要从事稀有金属材料研究。E-mail:
作者简介:

陈丽诗(1992—),女,云南文山人,硕士,工程师,主要从事稀有金属材料研究。E-mail:

Occurrence State of Tin and Indium in Tin Smelting Dust and Corresponding Separation Method
Lishi CHEN1, 2 , Pengcheng LI3, Meizhen WU1, Ruichun SU1, Tongwen FAN3, Zhang ZHANG3, Qingdong LIU2, 3
Affiliations
  • 1.Yunnan Tin-Indium Laboratory Co., Ltd., Kunming 650106, Yunnan, China
  • 2.Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
  • 3.Tin Branch Company of Yunnan Tin Co., Ltd., Gejiu 661017, Yunnan, China
doi: 10.3969/j.issn.0253-6099.2025.06.022
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以锡冶炼厂烟尘为原料,对其中Sn、In的赋存形态及分布特性进行研究,采用水浸-氧化酸浸联合工艺分离回收锡冶炼烟尘中的Sn、In、Zn、Cd关键元素,考察了硫酸质量浓度、液固比、浸出温度、浸出时间等因素对浸出效果的影响。结果表明,锡冶炼烟尘中Sn、In主要以SnO2、In2S3和Zn2SnO4形式存在。经水浸处理后,在硫酸质量浓度200 g/L、浸出温度65 ℃、浸出时间120 min、浸出液固比5.0、高锰酸钾添加量1.5%条件下氧化酸浸,In、Zn、Cd浸出率分别为82.00%、95.60%、94.30%,Sn浸出率为0.84%;经水浸-氧化酸浸工艺处理后,Sn含量从42.44%提高至60.87%,富集比为1.43。沉淀物酸浸渣颗粒表面呈多孔结构,由烟尘的致密状转变为蓬松状结构,该低杂质含量富锡酸浸渣可返回锡熔炼工序,铟进入萃取回收工序,实现锡冶炼烟尘中有价金属高效回收利用。

水浸  /  氧化酸浸  /  锡冶炼烟尘  /  有价金属  /  回收  /  锡  /  铟  /  分离

With the dust from a tin smelter as raw material, the occurrence state of tin (Sn) and indium (In) therein was firstly studied. Then, a combined processing technique consisting of water leaching and oxidative acid leaching was adopted to separate and recover the key elements of Sn, In, Zn and Cd from the tin smelting dust, and effects of factors including suluric acid concentration, liquid-solid ratio, reaction temperature and reaction time on the leaching process were explored. The results show that Sn and In in the tin smelting dust mainly exist in the forms of SnO2, In2S3 and Zn2SnO4. After water leaching treatment, the dust was leached with sulfuric acid at a concentration of 200 g/L by adding potassium permanganate at a dosage of 1.5%, with liquid-solid ratio of 5.0, at a temperature of 65 ℃ for 120 min, resulting in the leaching rates of In, Zn and Cd at 82.00%, 95.60% and 94.30% respectively, while the leaching rate of Sn at 0.84%. After such treatment, the Sn content in the dust increased from 42.44% to 60.87% with an enrichment ratio of 1.43. The particles of the acid leaching residue were porous on the surface, showing that the dust with dense structure changed to the residue with loose one. This tin-rich acid leaching residue with low impurity content can be back to tin smelting process, and indium can go to the subsequent process for extraction and recovery. By this way, efficient recovery and utilization of valuable metals from tin smelting dust can be actualized.

water leaching  /  oxidative acid leaching  /  tin smelting dust  /  valuable metal  /  recovery  /  tin  /  indium  /  separation
陈丽诗, 李鹏程, 伍美珍, 苏瑞春, 范桐文, 张璋, 刘庆东. 锡冶炼烟尘中锡、铟赋存形态及分离富集研究. 矿冶工程杂志, 2025 , 45 (6) : 124 -129 . DOI: 10.3969/j.issn.0253-6099.2025.06.022
Lishi CHEN, Pengcheng LI, Meizhen WU, Ruichun SU, Tongwen FAN, Zhang ZHANG, Qingdong LIU. Occurrence State of Tin and Indium in Tin Smelting Dust and Corresponding Separation Method[J]. Mining and Metallurgical Engineering, 2025 , 45 (6) : 124 -129 . DOI: 10.3969/j.issn.0253-6099.2025.06.022
  • 云南省科技厅重大科技专项计划(202302AB080014)
  • 云南锡铟实验室专项项目(202405AR340002)
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2025年第45卷第6期
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doi: 10.3969/j.issn.0253-6099.2025.06.022
  • 接收时间:2025-08-29
  • 首发时间:2026-10-08
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  • 收稿日期:2025-08-29
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云南省科技厅重大科技专项计划(202302AB080014)
云南锡铟实验室专项项目(202405AR340002)
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    1.云南锡铟实验室有限公司,云南 昆明 650106
    2.昆明理工大学冶金与能源工程学院,云南 昆明 650093
    3.云南锡业股份有限公司锡业分公司,云南 个旧 661017

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刘庆东(1981—),男,湖南澧县人,硕士,高级工程师,主要从事稀有金属材料研究。E-mail:
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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