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The action and mechanism of copolymer of maleic acid and acrylic acid (PMAA) in flotation separation of barite and fluorite in the presence of collector of sodium oleate were studied. A single mineral flotation test shows that sodium oleate has a good collecting for barite and fluorite, and PMAA has an obvious selective depressing effect on fluorite. A flotation test of artificially mixed minerals confirms that PMAA can achieve the separation of barite from fluorite in the presence of sodium oleate. A Zeta potential test shows that PMAA can hinder the adsorption of sodium oleate on the surface of fluorite, but cannot hinder its adsorption on barite surface. An XPS analysis shows that PMAA isn't effectively adsorbed on the surface of barite, but is chemically adsorbed on the surface of fluorite through the interaction between carboxyl groups of PMAA and calcium ions of fluorite, thus achieving the selective depression of fluorite during the flotation of barite with sodium oleate.

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研究了油酸钠体系下抑制剂马来酸-丙烯酸共聚物（PMAA）在浮选分离重晶石与萤石中的作用与机理。单矿物浮选试验结果表明，油酸钠对重晶石与萤石均具有很好的捕收性能，PMAA对萤石具有显著的选择性抑制作用；人工混合矿浮选结果证实了油酸钠体系下PMAA能实现重晶石与萤石的分离。Zeta电位测试结果表明，PMAA能阻碍油酸钠在萤石表面吸附，但不能阻碍油酸钠在重晶石表面吸附；XPS分析结果表明，PMAA在重晶石表面没有发生有效吸附，但PMAA能通过其分子中的羧基与萤石表面钙离子作用，在萤石表面发生化学吸附，从而实现油酸钠浮选重晶石过程中对萤石的选择性抑制。

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刘诚（1986—），男，江西九江人，博士，研究员，博士研究生导师，主要研究方向为矿物浮选理论与工艺。

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刘诚（1986—），男，江西九江人，博士，研究员，博士研究生导师，主要研究方向为矿物浮选理论与工艺。

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