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In this paper, the effects of rare earth on the quality, metallurgical performances and mineral composition of sinter are systematically studied with sinter cup as well as the occurrence states of rare earth in different minerals of sinter are analyzed with scanning electron microscope and energy spectrum. The results showed that the sinter product ratio, utilization coefficient and drum strength tended to be increased first and then decreased, reducibility and low-temperature reduction degradation index of sinter tended to be improved first and then deteriorated, melting range was widened as well as the amount of formation for calcium ferrite in the mineral composition of sinter tended to be decreased with the proportion of rare earth increased. During the sintering process, the rare earth is into hematite, calcium ferrite and glass phase as well as it exists as columnar rare earth mineral in glass phase.
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采用烧结杯系统研究了稀土对烧结矿质量、冶金性能以及矿物组成的影响,并结合扫描电镜和能谱分析了稀土在烧结矿不同矿物中的赋存状态。研究结果表明:随着稀土配比的增加,烧结成品率、利用系数以及转鼓强度呈先增加后降低的趋势,烧结矿还原性和低温还原粉化指数呈先改善后恶化的趋势,熔融区间变宽,烧结矿矿物组成中铁酸钙的生成量呈降低的趋势。在烧结过程中稀土进入赤铁矿、铁酸钙及玻璃相中,在玻璃相中以柱状稀土矿物状态存在。
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刘周利(1984-),男,陕西省宝鸡市人,高级工程师,现从事烧结工艺研究及管理工作。
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1 Technical Center of Inner Mongolia Baotou Steel Union Co., Ltd., Baotou 014010,Inner Mongolia Autonomous Region, China
2 Inner Mongolia Enterprise Key Laboratory of Rare Earth Steel Products Research & Development,Baotou 014010, Inner Mongolia Autonomous Region, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1198292634134475287, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, authorId=1198292633945731603, language=CN, stringName=刘周利, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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1 内蒙古包钢钢联股份有限公司技术中心,内蒙古 包头 014010
2 内蒙古自治区稀土钢产品研发企业重点实验室,内蒙古 包头 014010, bio={"content":"
刘周利(1984-),男,陕西省宝鸡市人,高级工程师,现从事烧结工艺研究及管理工作。
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刘周利(1984-),男,陕西省宝鸡市人,高级工程师,现从事烧结工艺研究及管理工作。
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2 内蒙古自治区稀土钢产品研发企业重点实验室,内蒙古 包头 014010)])]), Author(id=1198292634209972761, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1198292634298053150, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, authorId=1198292634209972761, language=EN, stringName=Min Wang, firstName=Min, middleName=null, lastName=Wang, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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1 内蒙古包钢钢联股份有限公司技术中心,内蒙古 包头 014010)])]), Author(id=1198292634444853797, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, orderNo=2, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1198292634524545578, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, authorId=1198292634444853797, language=EN, stringName=Hai-quan Liang, firstName=Hai-quan, middleName=null, lastName=Liang, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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3 Rare Earth Steel Iron-making Plant of Inner Mongolia Baotou Steel Union Co., Ltd., Baotou 014010,Inner Mongolia Autonomous Region, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1198292634608431660, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, authorId=1198292634444853797, language=CN, stringName=梁海全, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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3 内蒙古包钢钢联股份有限公司稀土钢炼铁厂,内蒙古 包头 014010, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1198292633723433484, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, xref=3, ext=[AuthorCompanyExt(id=1198292633731822093, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633723433484, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
3 Rare Earth Steel Iron-making Plant of Inner Mongolia Baotou Steel Union Co., Ltd., Baotou 014010,Inner Mongolia Autonomous Region, China), AuthorCompanyExt(id=1198292633736016398, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633723433484, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
3 内蒙古包钢钢联股份有限公司稀土钢炼铁厂,内蒙古 包头 014010)])]), Author(id=1198292634658763310, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, orderNo=3, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1198292634751038003, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, authorId=1198292634658763310, language=EN, stringName=Xiao-yi He, firstName=Xiao-yi, middleName=null, lastName=He, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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4 Manufacturing Dept. of Inner Mongolia Baotou Steel Union Co., Ltd., Baotou 014010,Inner Mongolia Autonomous Region, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1198292634864284213, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, authorId=1198292634658763310, language=CN, stringName=何晓义, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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4 内蒙古包钢钢联股份有限公司制造部,内蒙古 包头 014010, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1198292633849262607, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, xref=4, ext=[AuthorCompanyExt(id=1198292633857651216, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633849262607, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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32(2):22-26., articleTitle=包钢烧结矿的化学成分及显微结构对其冶金性能的影响, refAbstract=null), Reference(id=1198292639264109193, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, doi=null, pmid=null, pmcid=null, year=2007, volume=26, issue=2, pageStart=100, pageEnd=103, url=null, language=null, rfNumber=[4], rfOrder=3, authorNames=赵艳霞, 罗果萍, 孙国龙, journalName=内蒙古科技大学学报, refType=null, unstructuredReference=赵艳霞, 罗果萍, 孙国龙, 等. 包钢烧结优化配矿的基础研究[J].
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26(2):100-103., articleTitle=包钢烧结优化配矿的基础研究, refAbstract=null), Reference(id=1198292639352189579, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, doi=null, pmid=null, pmcid=null, year=2010, volume=31, issue=4, pageStart=88, pageEnd=91, url=null, language=null, rfNumber=[5], rfOrder=4, authorNames=韩淑霞, 刘铃声, journalName=稀土, refType=null, unstructuredReference=韩淑霞, 刘铃声. 稀土对烧结矿质量的影响研究[J].
稀土,
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31(4):88-91., articleTitle=稀土对烧结矿质量的影响研究, refAbstract=null)], funds=null, companyList=[AuthorCompany(id=1198292633513718275, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, xref=1, ext=[AuthorCompanyExt(id=1198292633522106884, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633513718275, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
1 Technical Center of Inner Mongolia Baotou Steel Union Co., Ltd., Baotou 014010,Inner Mongolia Autonomous Region, China), AuthorCompanyExt(id=1198292633530495493, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633513718275, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
1 内蒙古包钢钢联股份有限公司技术中心,内蒙古 包头 014010)]), AuthorCompany(id=1198292633589215751, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, xref=2, ext=[AuthorCompanyExt(id=1198292633614381577, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633589215751, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
2 Inner Mongolia Enterprise Key Laboratory of Rare Earth Steel Products Research & Development,Baotou 014010, Inner Mongolia Autonomous Region, China), AuthorCompanyExt(id=1198292633626964490, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633589215751, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
2 内蒙古自治区稀土钢产品研发企业重点实验室,内蒙古 包头 014010)]), AuthorCompany(id=1198292633723433484, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, xref=3, ext=[AuthorCompanyExt(id=1198292633731822093, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633723433484, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
3 Rare Earth Steel Iron-making Plant of Inner Mongolia Baotou Steel Union Co., Ltd., Baotou 014010,Inner Mongolia Autonomous Region, China), AuthorCompanyExt(id=1198292633736016398, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633723433484, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
3 内蒙古包钢钢联股份有限公司稀土钢炼铁厂,内蒙古 包头 014010)]), AuthorCompany(id=1198292633849262607, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, xref=4, ext=[AuthorCompanyExt(id=1198292633857651216, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633849262607, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
4 Manufacturing Dept. of Inner Mongolia Baotou Steel Union Co., Ltd., Baotou 014010,Inner Mongolia Autonomous Region, China), AuthorCompanyExt(id=1198292633861845521, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, companyId=1198292633849262607, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
4 内蒙古包钢钢联股份有限公司制造部,内蒙古 包头 014010)])], figs=[ArticleFig(id=1198292636097409623, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, language=EN, label=null, caption=null, figureFileSmall=uWEZC873NqWC6pel8fSyog==, figureFileBig=q/kcarigCgceHj9p3afn2w==, tableContent=null), ArticleFig(id=1198292636151935575, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, language=CN, label=图1, caption=
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烧结矿(SXT2.0)赤铁矿能谱分析, figureFileSmall=JoUjEdgw4ziRKA5yZBYOVg==, figureFileBig=Cql8mRD++biAr+J6KJXeVA==, tableContent=null), ArticleFig(id=1198292636382622302, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, language=EN, label=null, caption=null, figureFileSmall=fbwwARqAHvedwz56628xeA==, figureFileBig=QgRf1pz/zjeNSVZvubwztQ==, tableContent=null), ArticleFig(id=1198292636453925472, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, language=CN, label=图3, caption=
烧结矿(SXT2.0)磁铁矿能谱分析, figureFileSmall=fbwwARqAHvedwz56628xeA==, figureFileBig=QgRf1pz/zjeNSVZvubwztQ==, tableContent=null), ArticleFig(id=1198292636525228641, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, language=EN, label=null, caption=null, figureFileSmall=yukAzYHgNuXL3fCQiCu96g==, figureFileBig=vt5fK+Jy141MrLbJN4kOvw==, tableContent=null), ArticleFig(id=1198292636600726115, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, language=CN, label=图4, caption=
烧结矿(SXT2.0)铁酸钙能谱分析, figureFileSmall=yukAzYHgNuXL3fCQiCu96g==, figureFileBig=vt5fK+Jy141MrLbJN4kOvw==, tableContent=null), ArticleFig(id=1198292636672029284, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, language=EN, label=null, caption=null, figureFileSmall=+dUe24ii2kzHIUhJXIiU1A==, figureFileBig=K0vhej6UaI6nrerXD3rjiA==, tableContent=null), ArticleFig(id=1198292636747526757, tenantId=1146029695717560320, journalId=1185652524569653253, articleId=1198277726265242027, language=CN, label=图5, caption=
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| 原料名称 | TFe | FeO | CaO | SiO2 | MgO | Al2O3 | K2O | Na2O | F | REO | Ig |
| 自产精矿 | 66.46 | 28.83 | 0.92 | 2.50 | 0.83 | 0.12 | 0.13 | 0.12 | 0.38 | | 1.74 |
| 稀土精矿 | 3.75 | | | | | | | | 8.42 | 54.05 | |
| 蛇纹石 | | | 1.00 | 38.00 | 35.00 | | | | | | 10.00 |
| 石灰石 | | | 51.05 | 2.84 | 1.86 | | | | | | 39.91 |
| 生石灰 | | | 87.67 | 3.63 | 4.07 | | | | | | 2.31 |
| 白云石 | | | 31.09 | 2.36 | 19.86 | | | | | | 45.87 |
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试验原料化学成分及烧损(质量分数)%
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| 原料名称 | TFe | FeO | CaO | SiO2 | MgO | Al2O3 | K2O | Na2O | F | REO | Ig |
| 自产精矿 | 66.46 | 28.83 | 0.92 | 2.50 | 0.83 | 0.12 | 0.13 | 0.12 | 0.38 | | 1.74 |
| 稀土精矿 | 3.75 | | | | | | | | 8.42 | 54.05 | |
| 蛇纹石 | | | 1.00 | 38.00 | 35.00 | | | | | | 10.00 |
| 石灰石 | | | 51.05 | 2.84 | 1.86 | | | | | | 39.91 |
| 生石灰 | | | 87.67 | 3.63 | 4.07 | | | | | | 2.31 |
| 白云石 | | | 31.09 | 2.36 | 19.86 | | | | | | 45.87 |
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| 名称 | Fcad | Ad | Vdaf | St,d | Mt |
| 焦粉 | 82.0 | 16.0 | 2.1 | 0.9 | 2.4 |
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燃料工业分析(质量分数)%
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| 名称 | Fcad | Ad | Vdaf | St,d | Mt |
| 焦粉 | 82.0 | 16.0 | 2.1 | 0.9 | 2.4 |
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| 编号 | 烧结矿化学成分(质量分数)/% | R |
| TFe | FeO | CaO | SiO2 | MgO | F | REO |
| SJ | 58.50 | 10.44 | 9.88 | 4.84 | 2.08 | 0.07 | 0.20 | 2.04 |
| SXT0.5 | 58.22 | 10.72 | 9.48 | 4.78 | 1.96 | 0.37 | 0.50 | 1.98 |
| SXT1.0 | 57.54 | 10.60 | 9.50 | 4.81 | 2.01 | 0.52 | 0.95 | 1.98 |
| SXT1.5 | 56.83 | 10.22 | 9.63 | 4.86 | 1.95 | 0.58 | 1.44 | 1.98 |
| SXT2.0 | 55.01 | 10.31 | 9.72 | 4.80 | 2.03 | 0.62 | 2.11 | 2.03 |
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烧结矿化学成分及碱度
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| 编号 | 烧结矿化学成分(质量分数)/% | R |
| TFe | FeO | CaO | SiO2 | MgO | F | REO |
| SJ | 58.50 | 10.44 | 9.88 | 4.84 | 2.08 | 0.07 | 0.20 | 2.04 |
| SXT0.5 | 58.22 | 10.72 | 9.48 | 4.78 | 1.96 | 0.37 | 0.50 | 1.98 |
| SXT1.0 | 57.54 | 10.60 | 9.50 | 4.81 | 2.01 | 0.52 | 0.95 | 1.98 |
| SXT1.5 | 56.83 | 10.22 | 9.63 | 4.86 | 1.95 | 0.58 | 1.44 | 1.98 |
| SXT2.0 | 55.01 | 10.31 | 9.72 | 4.80 | 2.03 | 0.62 | 2.11 | 2.03 |
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| 编号 | 成品率 /% | 利用系数 /(t·m-2·h-1) | 垂速 /(mm·min-1) | 燃耗 /(kg·t-1) | 转鼓(+6.3 mm) /% |
| SJ | 70.31 | 1.42 | 20.00 | 65.88 | 64.40 |
| SXT0.5 | 71.81 | 1.41 | 21.20 | 65.71 | 64.50 |
| SXT1.0 | 74.54 | 1.44 | 20.60 | 63.39 | 65.80 |
| SXT1.5 | 75.60 | 1.45 | 20.50 | 62.90 | 66.50 |
| SXT2.0 | 74.40 | 1.41 | 19.40 | 63.29 | 65.90 |
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烧结工艺指标
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| 编号 | 成品率 /% | 利用系数 /(t·m-2·h-1) | 垂速 /(mm·min-1) | 燃耗 /(kg·t-1) | 转鼓(+6.3 mm) /% |
| SJ | 70.31 | 1.42 | 20.00 | 65.88 | 64.40 |
| SXT0.5 | 71.81 | 1.41 | 21.20 | 65.71 | 64.50 |
| SXT1.0 | 74.54 | 1.44 | 20.60 | 63.39 | 65.80 |
| SXT1.5 | 75.60 | 1.45 | 20.50 | 62.90 | 66.50 |
| SXT2.0 | 74.40 | 1.41 | 19.40 | 63.29 | 65.90 |
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| 编号 | RI /% | RDI+3.15 mm /% | 软融性能/℃ | △Pmax/Pa |
| T4 | T10 | T40 | T40-T10 | TS | TD | TD-TS |
| SJ | 76.50 | 77.60 | 1 104 | 1 122 | 1 256 | 134 | 1 246 | 1 505 | 259 | 14 910 |
| SXT0.5 | 77.60 | 78.60 | 1 111 | 1 142 | 1 254 | 112 | 1 245 | 1 504 | 259 | 15 018 |
| SXT1.0 | 78.80 | 79.40 | 1 127 | 1 151 | 1 258 | 107 | 1 247 | 1 515 | 268 | 15 854 |
| SXT1.5 | 79.20 | 80.50 | 1 120 | 1 150 | 1 256 | 106 | 1 246 | 1 517 | 271 | 16 005 |
| SXT2.0 | 78.00 | 79.60 | 1 114 | 1 151 | 1 246 | 94 | 1 235 | 1 515 | 280 | 16 539 |
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烧结矿冶金性能
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| 编号 | RI /% | RDI+3.15 mm /% | 软融性能/℃ | △Pmax/Pa |
| T4 | T10 | T40 | T40-T10 | TS | TD | TD-TS |
| SJ | 76.50 | 77.60 | 1 104 | 1 122 | 1 256 | 134 | 1 246 | 1 505 | 259 | 14 910 |
| SXT0.5 | 77.60 | 78.60 | 1 111 | 1 142 | 1 254 | 112 | 1 245 | 1 504 | 259 | 15 018 |
| SXT1.0 | 78.80 | 79.40 | 1 127 | 1 151 | 1 258 | 107 | 1 247 | 1 515 | 268 | 15 854 |
| SXT1.5 | 79.20 | 80.50 | 1 120 | 1 150 | 1 256 | 106 | 1 246 | 1 517 | 271 | 16 005 |
| SXT2.0 | 78.00 | 79.60 | 1 114 | 1 151 | 1 246 | 94 | 1 235 | 1 515 | 280 | 16 539 |
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| 编号 | 磁铁矿 | 赤铁矿 | 铁酸钙 | 硅酸二钙 | 玻璃相 | 铈钙硅石 | 橄榄石 | 含稀土铁矿物 | 枪晶石 |
| SJ | 50 | 12 | 23 | 3 | 11 | | 1 | | |
| SXT0.5 | 49 | 15 | 15 | 1 | 10 | <1 | | 9 | <1 |
| SXT1.0 | 46 | 13 | 14 | 1 | 12 | 1 | | 12 | 1 |
| SXT1.5 | 45 | 14 | 13 | 1 | 11 | 1 | | 14 | 1 |
| SXT2.0 | 45 | 13 | 13 | 1 | 7 | 2 | | 17 | 2 |
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烧结矿矿物组成(体积分数)%
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| 编号 | 磁铁矿 | 赤铁矿 | 铁酸钙 | 硅酸二钙 | 玻璃相 | 铈钙硅石 | 橄榄石 | 含稀土铁矿物 | 枪晶石 |
| SJ | 50 | 12 | 23 | 3 | 11 | | 1 | | |
| SXT0.5 | 49 | 15 | 15 | 1 | 10 | <1 | | 9 | <1 |
| SXT1.0 | 46 | 13 | 14 | 1 | 12 | 1 | | 12 | 1 |
| SXT1.5 | 45 | 14 | 13 | 1 | 11 | 1 | | 14 | 1 |
| SXT2.0 | 45 | 13 | 13 | 1 | 7 | 2 | | 17 | 2 |
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