Article(id=1198266571018826196, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1198266568997175650, articleNumber=1009-5438(2023)02-0001-04, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1677600000000, receivedDateStr=2023-03-01, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1763618613246, onlineDateStr=2025-11-20, pubDate=1682352000000, pubDateStr=2023-04-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1763618613246, onlineIssueDateStr=2025-11-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1763618613246, creator=13701087609, updateTime=1763618613246, updator=13701087609, issue=Issue{id=1198266568997175650, tenantId=1146029695717560320, journalId=1185652524569653253, year='2023', volume='49', issue='2', pageStart='1', pageEnd='98', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1763618612765, creator=13701087609, updateTime=1763619383107, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1198269800108618470, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1198266568997175650, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1198269800108618471, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1198266568997175650, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=1, endPage=4, ext={EN=ArticleExt(id=1198266571274678742, articleId=1198266571018826196, tenantId=1146029695717560320, journalId=1185652524569653253, language=EN, title=Experimental Study on Corrosion Resistance of Black Spots on Surface of Zn-Al-Mg Coating, columnId=1187100783049851249, journalTitle=Science & Technology of Baotou Steel, columnName=Expert Forum, runingTitle=null, highlight=null, articleAbstract=

The comparison tests for corrosion resistances of samples with and without black spots on the surface of Zn-Al-Mg coating as well as the pure Zn coating are carried out with the neutral salt spray tests. There was not red rust for the samples with and without black spots on the surface of Zn-Al-Mg coating with the neutral salt spray tests of 2 000 h and 4 000 h, while there was obvious red rust for the sample with pure Zn coating with the test of 2 000 h and it was increased obviously with the test of 4 000 h. The positions with and without black spots of Zn-Al-Mg coating are analyzed with the scanning electron microscope and energy disperse spectroscopy. The results showed that many fine magnesium-rich eutectic structures were enriched at the position with black spots. There were differences for reflection of light between them and stripy eutectic structure at the position without black spots as well as the magnesium-rich eutectic structures were easily to be oxidized by the oxygen in the air so as to form black oxide so that the visual differences appear black spots. The salt spray test results showed that the corrosion resistance at the position with black spots didn’t deteriorate as well as the corrosion resistances of samples with and without black spots on the surface of Zn-Al-Mg coating were the same good.

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采用中性盐雾试验对锌铝镁镀层表面黑点样品、锌铝镁镀层表面正常样品以及纯锌镀层样品的耐蚀性进行了对比测试,锌铝镁镀层表面黑点样品和锌铝镁镀层表面正常样品经2 000 h及4 000 h的中性盐雾腐蚀试验后在镀层表面均未出现红锈,而纯锌样品在2 000 h已经出现明显红锈,到4 000 h红锈量明显增多。使用扫描电镜及能谱仪对锌铝镁镀层的黑点部位和正常部位进行了分析,结果表明黑点部位富集了大量细小、富镁的共晶组织,由于这些细小的共晶组织与正常部位的条片状共晶组织对光的反射存在差异,同时富镁的共晶组织容易被空气中的氧气氧化形成黑色的氧化物,由此导致其目视差异呈黑点。盐雾试验结果表明,黑点部位的耐蚀性能并无恶化,锌铝镁镀层的黑点样品与正常样品同样具有较好的耐蚀性能。

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李智丽(1971-),女,辽宁省盘锦市人,硕士,正高级工程师,现从事金属材料热处理及物理检测工作。

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李智丽(1971-),女,辽宁省盘锦市人,硕士,正高级工程师,现从事金属材料热处理及物理检测工作。

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