Article(id=1188423623153959827, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1188423621174244026, articleNumber=1009-5438(2024)03-0071-04, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1709568000000, receivedDateStr=2024-03-05, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1761271871602, onlineDateStr=2025-10-24, pubDate=1719244800000, pubDateStr=2024-06-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1761271871602, onlineIssueDateStr=2025-10-24, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1761271871602, creator=13701087609, updateTime=1761271871602, updator=13701087609, issue=Issue{id=1188423621174244026, tenantId=1146029695717560320, journalId=1185652524569653253, year='2024', volume='50', issue='3', pageStart='1', pageEnd='98', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=0, articleOrder=1, issueType=-1, specialIssue=null, createTime=1761271871131, creator=13701087609, updateTime=1761283363050, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1188471821818015773, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1188423621174244026, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1188471821818015774, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1188423621174244026, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=71, endPage=74, ext={EN=ArticleExt(id=1188423623376257941, articleId=1188423623153959827, tenantId=1146029695717560320, journalId=1185652524569653253, language=EN, title=Effects of Online Accelerated Cooling on Microstructure and Properties of Hot Rolled C-Mn Seamless Steel Pipe, columnId=1187095652984042303, journalTitle=Science & Technology of Baotou Steel, columnName=Variety Quality and Experimental Study, runingTitle=null, highlight=null, articleAbstract=

In this paper, it is introduced the online accelerated cooling process test of a type of hot rolled C-Mn seamless steel pipe in 460 production line of Baotou Steel Pipe Co., Ltd.. The test results showed that the effects of online accelerated cooling process on microstructure and properties of test steel were significant, generation of proeutectoid ferrite in two phase region could be restrained by online controlled cooling so that the matrix grains were refined as well as grain size was increased from level 6.5 under non controlled cooling conditions to level 8 and the banded structure of steel was improved. The mechanical properties and impact properties of steel pipe are significantly improved, the yield strength could reach 300~345 MPa, tensile strength could reach 485~545 MPa, average value of longitudinal impact energy at room temperature could reach 102 J, average value of longitudinal impact energy at 0 ℃ could reach 86 J and average value of longitudinal impact energy at -20 ℃ could reach 60 J.

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文章介绍了包钢钢管公司460生产线上一种C-Mn热轧无缝钢管在线加速冷却工艺试验。试验结果表明,在线加速冷却工艺对试验钢组织、性能影响显著,在线控冷能够抑制两相区先共析铁素体的产生,细化了基体晶粒,晶粒度从非控冷状态下的6.5级提高到了8级,改善了钢的带状组织。钢管力学性能及冲击性能有明显提高,屈服强度达到300~345 MPa,抗拉强度达到485~545 MPa,纵向室温冲击功平均值达到102 J,纵向0 ℃冲击功平均值达到86 J,纵向-20 ℃冲击功平均值达到60 J。

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邬占飞(1984-),男,内蒙古土默特右旗人,高级工程师,现从事无缝钢管产品研发工作。

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邬占飞(1984-),男,内蒙古土默特右旗人,高级工程师,现从事无缝钢管产品研发工作。

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邬占飞(1984-),男,内蒙古土默特右旗人,高级工程师,现从事无缝钢管产品研发工作。

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C Si Mn P S Cr、Mo、Nb、V、Ti
0.17~0.23 0.17~0.37 0.35~0.65 ≤0.030 ≤0.030 残余
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试验钢化学成分(质量分数) %

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C Si Mn P S Cr、Mo、Nb、V、Ti
0.17~0.23 0.17~0.37 0.35~0.65 ≤0.030 ≤0.030 残余
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试样编号 晶粒度/级 显微组织
内壁 外壁
0# 6.5 6.5 F+P F+P
1# 8 8.5 F+P+B F+P+B
10# 8 8.5 F+P+B F+P+B
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钢管显微组织、晶粒度对比

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试样编号 晶粒度/级 显微组织
内壁 外壁
0# 6.5 6.5 F+P F+P
1# 8 8.5 F+P+B F+P+B
10# 8 8.5 F+P+B F+P+B
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在线加速冷却对热轧C-Mn无缝钢管组织及性能影响
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邬占飞 , 米永峰 , 贺景春 , 郭志文 , 姜海龙 , 孙文秀
包钢科技 | 品种质量与试验研究 2024,50(3): 71-74
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包钢科技 | 品种质量与试验研究 2024, 50(3): 71-74
在线加速冷却对热轧C-Mn无缝钢管组织及性能影响
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邬占飞, 米永峰, 贺景春, 郭志文, 姜海龙, 孙文秀
作者信息
  • 内蒙古包钢钢管有限公司, 内蒙古 包头 014010
  • 邬占飞(1984-),男,内蒙古土默特右旗人,高级工程师,现从事无缝钢管产品研发工作。

Effects of Online Accelerated Cooling on Microstructure and Properties of Hot Rolled C-Mn Seamless Steel Pipe
Zhan-fei Wu, Yong-feng Mi, Jing-chun He, Zhi-wen Guo, Hai-long Jiang, Wen-xiu Sun
Affiliations
  • Inner Mongolia Baotou Steel Pipe Co., Ltd., Baotou 014010, Inner Mongolia Autonomous Region, China
出版时间: 2024-06-25
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文章介绍了包钢钢管公司460生产线上一种C-Mn热轧无缝钢管在线加速冷却工艺试验。试验结果表明,在线加速冷却工艺对试验钢组织、性能影响显著,在线控冷能够抑制两相区先共析铁素体的产生,细化了基体晶粒,晶粒度从非控冷状态下的6.5级提高到了8级,改善了钢的带状组织。钢管力学性能及冲击性能有明显提高,屈服强度达到300~345 MPa,抗拉强度达到485~545 MPa,纵向室温冲击功平均值达到102 J,纵向0 ℃冲击功平均值达到86 J,纵向-20 ℃冲击功平均值达到60 J。

在线加速冷却  /  热轧C-Mn无缝钢管  /  带状组织  /  力学性能

In this paper, it is introduced the online accelerated cooling process test of a type of hot rolled C-Mn seamless steel pipe in 460 production line of Baotou Steel Pipe Co., Ltd.. The test results showed that the effects of online accelerated cooling process on microstructure and properties of test steel were significant, generation of proeutectoid ferrite in two phase region could be restrained by online controlled cooling so that the matrix grains were refined as well as grain size was increased from level 6.5 under non controlled cooling conditions to level 8 and the banded structure of steel was improved. The mechanical properties and impact properties of steel pipe are significantly improved, the yield strength could reach 300~345 MPa, tensile strength could reach 485~545 MPa, average value of longitudinal impact energy at room temperature could reach 102 J, average value of longitudinal impact energy at 0 ℃ could reach 86 J and average value of longitudinal impact energy at -20 ℃ could reach 60 J.

online accelerated cooling  /  hot rolled C-Mn seamless steel pipe  /  banded structure  /  mechanical property
邬占飞, 米永峰, 贺景春, 郭志文, 姜海龙, 孙文秀. 在线加速冷却对热轧C-Mn无缝钢管组织及性能影响. 包钢科技, 2024 , 50 (3) : 71 -74 .
Zhan-fei Wu, Yong-feng Mi, Jing-chun He, Zhi-wen Guo, Hai-long Jiang, Wen-xiu Sun. Effects of Online Accelerated Cooling on Microstructure and Properties of Hot Rolled C-Mn Seamless Steel Pipe[J]. Science & Technology of Baotou Steel, 2024 , 50 (3) : 71 -74 .
无缝钢管被广泛应用于油气的开采及输送,因其服役环境的特殊性,不仅对其耐腐蚀性有严格的要求,力学性能的稳定性也是产品安全服役的一项重要指标。近年来,随着产品竞争的日益激烈,钢铁企业面临重重压力。上游原材料尤其是合金的价格不断攀升,下游用户对产品的性能要求逐渐严格,对于钢铁企业,如何降本增效是一个必须思考的问题。包钢钢管公司试验将钢中Mn含量由原来的1.55%降低至0.40%~0.65%,达到降低生产成本的目的。事实上,伴随着Mn含量的降低,产品的力学性能也呈现出不同程度的下降,主要表现为钢中带状组织严重,造成钢管屈服强度偏低,且各项力学性能不稳定。究其原因是钢在凝固时溶质元素偏聚,轧制过程中溶质元素偏聚区被变形延伸成带状分布,轧后冷却时低锰区的局部相变温度Ar3较高,首先形成铁素体并导致碳和锰进一步富集到偏聚区,最后形成铁素体/珠光体带状组织。
热机械控轧控冷(TMCP)技术是通过控制轧制和控制冷却技术相结合,也就是采用低温轧制和在线热处理的综合处理手段,通过在线连续对热轧组织和轧后组织进行调控,获得理想的实物性能,该技术多用于板材的生产[1],如将控轧控冷技术用于无缝钢管生产,特别是轧后采用控制冷却技术,可在降低合金的基础上使钢管的强度和韧性同步提高,实现节约型绿色化生产。但因无缝钢管形状、工艺流程的特殊性和复杂性,导致热轧过程工艺窗口窄,不易实现控制轧制生产,而在线控冷技术是热轧无缝钢管领域长期以来的重点发展方向[2],结合包钢自身无缝机组的特点,开发轧后在线控制冷却设备和工艺,实现高品质热轧无缝钢管的生产[3]
试验钢的原料为钢管公司Φ460 mm作业区采用Φ390 mm坯型轧制规格为Φ377 mm×9 mm的热轧无缝管料,其制造工艺为铁水预处理→顶底复吹转炉冶炼→LF炉精炼→圆坯连铸→管坯加热→穿孔→连轧→定径机(→在线控冷)→冷床冷却。本试验用材料仅采用C-Mn钢生产,不添加其他合金元素,化学成分如表1所示。
选定同一炉圆钢坯,在1 290 ℃温度下加热,菌式穿孔机穿孔,PQF连轧机轧管,定径后分别以不同的冷却方式进行冷却,定径后温度为908 ℃。方案一,出定径机后正常进入冷床空冷,过10支钢管,辊道速度设定为2.1 m/s,运行时间为15 s,入口温度为832 ℃,出口温度为773 ℃,冷却速度为3.9 ℃/s;方案二,出定径机后进入在线控冷系统,开启8组冷却器,试制10支钢管,辊道速度设定为1.5 m/s,运行时间21 s,控冷入口温度为807~825 ℃,控冷出口温度为571~647 ℃,冷却速度为10.7~12.9 ℃/s;经冷床冷却后,按照GB/T 2975—2018规定取样方法,在头尾纵向距离管端500 mm处取拉伸试样,试样宽度20 mm。按照GB/T 228.1—2021中规定的试验方法,在KN600-J4A型拉力试验机上进行拉伸试验。按照GB/T 2975—2018中规定的取样方法,在钢管端部纵向上,每组取3个冲击试样,试样尺寸7.5 mm×10 mm×55 mm,缺口深度为2 mm。按照GB/T 229—2022中规定的试验方法,在RKP450GE型冲击试验机上进行冲击试验。在每个测试样取金相试样,用4%硝酸酒精溶液腐蚀,采用蔡司金相显微镜和图像分析仪拍摄显微组织照片。选择过控冷系统第1支及第10支钢管分别进行头尾四象限拉伸、冲击、组织、晶粒度检验,同时和轧态钢管(未进行在线冷却)进行性能对比,
按照设定的在线快冷参数,对在线快冷后钢管进行力学性能检测,在其中0#表示轧态钢管,1#、10#为过在线快冷处理后的第1支和第10支钢管,1、2、3、4表示四象限拉伸性能检测结果,如图1所示。
图1为试验钢轧态和过快冷后拉伸性能对比,其中0#未过在线快冷轧态钢管头端四象限屈服强度为267~289 MPa,尾端为271~282 MPa,平均屈服强度为277 MPa,抗拉强度满足标准GB/T 8163—2018要求[4];1#、10#过在线快冷后2支钢管头尾四象限屈服强度在300~345 MPa区间,最大值已满足标准要求,头尾四象限屈服强度差约为45 MPa,说明钢管在轴向和周向上拉伸性能较为均匀,也表明在线快冷整体控制良好,在线快冷后平均屈服强度为321 MPa,较未过在线快冷轧态钢管的屈服强度提高44 MPa,屈服强度的提高率为15.9%。未过在线快冷钢管抗拉强度平均值为479 MPa,过在线快冷钢管的抗拉强度平均值为513 MPa,均能满足标准要求,抗拉强度提高34 MPa,提高率为7.1%。过在线快冷钢管屈服强度较抗拉强度提高的幅度要大。另外未过在线快冷钢管的延伸率平均值为31%,过在线快冷钢管的延伸率平均值为28%,两者相比过在线快冷的钢管整体延伸率有所降低,但满足标准要求且富余量较大。
对3支钢管的头尾进行四象限冲击性能检测,试验温度分别为室温、0 ℃、-20 ℃、-40 ℃,如图2所示。
图2为试验钢在不同试验温度下轧态冲击韧性和过在线快冷后冲击韧性对比,其中0#代表未过在线快冷轧态钢管头尾端四象限冲击功,1#、10#代表过在线快冷后两支钢管头尾四象限冲击功。过在线快冷钢管较未过在线快冷钢管的冲击功明显提高,满足标准GB/T 8163—2018中Q345B、Q345C、Q345D钢级要求,且随着试验温度降低,未过在线快冷的钢管和过在线快冷的钢管,冲击功呈下降趋势。
对3支钢管采用蔡司显微镜对晶粒度、显微组织进行了检测,结果如图3表2所示。
从钢管显微组织来看,未过在线快冷管线钢管0#内壁及外壁组织为铁素体(F)+珠光体(P),晶粒度为6.5级;过在线快冷钢管1#、10#内壁及外壁组织为针状铁素体(F)+珠光体(P)+粒状贝氏体(B),晶粒度为8~8.5级。通过在线快冷,钢管晶粒发生细化,内外表面的带状组织得到明显改善[5]。过在线快冷后钢管显微组织中的珠光体(P)含量明显比未过在线快冷显微组织中的珠光体(P)含量要多,使得材料的强度和韧性同时得到提高。
在线加速冷却过程改变了C-Mn钢奥氏体相变产物,最终形成了针状铁素体、粒状贝氏体和珠光体,此外,加速冷却还可促进铁素体晶粒中碳氮化物析出,提高钢的强度。目前采用Mn含量为0.35%~0.65%钢种,屈服强度单值已经满足标准GB/T 8163—2018中Q345B、Q345C、Q345D钢级要求,因此对在线快冷冷却水的大小、钢管的前进速度、终冷温度和性能的匹配有必要进一步研究,从而降低现有钢种合金含量。
(1)试验钢通过在线加速冷却,可一定程度上细化晶粒,增加珠光体含量,提高钢的强度,改善C-Mn钢的带状组织。
(2)试验钢管通过在线加速冷却,奥氏体相变产物为针状铁素体、粒状贝氏体和珠光体。
(3)试验钢通过在线加速冷却,可提高钢管的强度及冲击韧性,使得Q345B/C系列产品采用最为经济的C-Mn钢生产,无需添加合金元素,即可保证材料的力学性能满足标准要求,无需后续离线热处理,可进一步降低生产成本。
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袁国, 康健, 李振垒, 等. 热轧无缝钢管在线热处理工艺组织性能调控研发技术进展[J]. 钢管, 2018, 47(1):30-34.
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2024年第50卷第3期
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  • 接收时间:2024-03-05
  • 首发时间:2025-10-24
  • 出版时间:2024-06-25
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    内蒙古包钢钢管有限公司, 内蒙古 包头 014010
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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