Article(id=1188049104094511343, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1188049099627574244, articleNumber=1009-5438(2024)02-0036-06, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1705852800000, receivedDateStr=2024-01-22, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1761182579300, onlineDateStr=2025-10-23, pubDate=1713974400000, pubDateStr=2024-04-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1761182579300, onlineIssueDateStr=2025-10-23, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1761182579300, creator=13701087609, updateTime=1761182579300, updator=13701087609, issue=Issue{id=1188049099627574244, tenantId=1146029695717560320, journalId=1185652524569653253, year='2024', volume='50', issue='2', pageStart='1', pageEnd='98', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1761182578236, creator=13701087609, updateTime=1761291001661, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1188503860504052243, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1188049099627574244, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1188503860504052244, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1188049099627574244, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=36, endPage=41, ext={EN=ArticleExt(id=1188049104413278452, articleId=1188049104094511343, tenantId=1146029695717560320, journalId=1185652524569653253, language=EN, title=Research on Effects of Internal Quality of Casting Blank on DWTT (Drop Weight Tear Test) Properties of Heavy Gauge X80M Hot Rolled Steel Strip, columnId=1187095652984042303, journalTitle=Science & Technology of Baotou Steel, columnName=Variety Quality and Experimental Study, runingTitle=null, highlight=null, articleAbstract=

The drop weight tear test (DWTT) is used to test the toughness of materials, mainly for studying the low-temperature toughness of metal materials. In the paper, the microstructure and morphology of samples corresponding to different area proportions of brittle fracture are compared and analyzed with optical microscope aiming at the unqualified DWTT properties of products during trial production process of heavy gauge X80M hot rolled steel strip. The composition segregation in thickness direction of casting blank is tested. It is found that the severe segregation in thickness direction of steel strip is the main factor influencing the DWTT properties by analysis. The center segregation of casting blank and DWTT properties of product are improved effectively by adjusting the arc alignment precision of segment and optimizing the specific water amount of continuous casting machine so that the goal of stable production of hot rolled steel strip for heavy gauge X80M pipeline steel is realized.

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落锤撕裂试验(DWTT)是用来检测材料韧性,主要用于金属材料的低温韧性研究。文章针对厚规格X80M热轧钢带试制过程中出现的产品DWTT性能不合格问题,使用光学显微镜对比分析了不同脆性断口面积比例对应试样的组织、形貌。对铸坯厚度方向成分偏析进行检测,分析得出钢带厚度方向偏析严重是影响DWTT性能的主要因素,通过调整扇形段对弧精度,优化铸机二冷水比水量,改善了铸坯中心偏析程度,有效提高了产品的DWTT性能,实现稳定生产厚规格X80M管线钢热轧钢带的目的。

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薛志强(1984-),男,内蒙古包头市人,硕士,工程师,现从事销售技术服务工作。

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薛志强(1984-),男,内蒙古包头市人,硕士,工程师,现从事销售技术服务工作。

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薛志强(1984-),男,内蒙古包头市人,硕士,工程师,现从事销售技术服务工作。

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铸坯内部质量对厚规格X80M热轧钢带DWTT性能影响研究
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薛志强 1 , 张振宇 1 , 魏晓东 2
包钢科技 | 品种质量与试验研究 2024,50(2): 36-41
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包钢科技 | 品种质量与试验研究 2024, 50(2): 36-41
铸坯内部质量对厚规格X80M热轧钢带DWTT性能影响研究
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薛志强1, 张振宇1, 魏晓东2
作者信息
  • 1 内蒙古包钢钢联股份有限公司销售分公司,内蒙古 包头 014010
  • 2 内蒙古包钢钢联股份有限公司技术中心,内蒙古 包头 014010
  • 薛志强(1984-),男,内蒙古包头市人,硕士,工程师,现从事销售技术服务工作。

Research on Effects of Internal Quality of Casting Blank on DWTT (Drop Weight Tear Test) Properties of Heavy Gauge X80M Hot Rolled Steel Strip
Zhi-qiang Xue1, Zhen-yu Zhang1, Xiao-dong Wei2
Affiliations
  • 1 Sales Branch Co. of Inner Mongolia Baotou Steel Union Co., Ltd., Baotou 014010, Inner Mongolia Autonomous Region, China
  • 2 Technical Center of Inner Mongolia Baotou Steel Union Co., Ltd., Baotou 014010, Inner Mongolia Autonomous Region, China
出版时间: 2024-04-25
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落锤撕裂试验(DWTT)是用来检测材料韧性,主要用于金属材料的低温韧性研究。文章针对厚规格X80M热轧钢带试制过程中出现的产品DWTT性能不合格问题,使用光学显微镜对比分析了不同脆性断口面积比例对应试样的组织、形貌。对铸坯厚度方向成分偏析进行检测,分析得出钢带厚度方向偏析严重是影响DWTT性能的主要因素,通过调整扇形段对弧精度,优化铸机二冷水比水量,改善了铸坯中心偏析程度,有效提高了产品的DWTT性能,实现稳定生产厚规格X80M管线钢热轧钢带的目的。

X80M  /  DWTT  /  中心偏析

The drop weight tear test (DWTT) is used to test the toughness of materials, mainly for studying the low-temperature toughness of metal materials. In the paper, the microstructure and morphology of samples corresponding to different area proportions of brittle fracture are compared and analyzed with optical microscope aiming at the unqualified DWTT properties of products during trial production process of heavy gauge X80M hot rolled steel strip. The composition segregation in thickness direction of casting blank is tested. It is found that the severe segregation in thickness direction of steel strip is the main factor influencing the DWTT properties by analysis. The center segregation of casting blank and DWTT properties of product are improved effectively by adjusting the arc alignment precision of segment and optimizing the specific water amount of continuous casting machine so that the goal of stable production of hot rolled steel strip for heavy gauge X80M pipeline steel is realized.

X80M  /  DWTT  /  center segregation
薛志强, 张振宇, 魏晓东. 铸坯内部质量对厚规格X80M热轧钢带DWTT性能影响研究. 包钢科技, 2024 , 50 (2) : 36 -41 .
Zhi-qiang Xue, Zhen-yu Zhang, Xiao-dong Wei. Research on Effects of Internal Quality of Casting Blank on DWTT (Drop Weight Tear Test) Properties of Heavy Gauge X80M Hot Rolled Steel Strip[J]. Science & Technology of Baotou Steel, 2024 , 50 (2) : 36 -41 .
随着我国钢铁冶金技术及管道制造技术的进步,我国管线钢的品质和使用寿命得到显著提高。在高钢级、大直径以及大壁厚的优质钢管领域,钢铁及焊管企业取得了大量的宝贵经验[1]
国内大多数研究机构和钢铁企业选择X80M管线钢热轧卷板的特定厚度作为研发和技术储备的焦点[2]。而生产特定厚度的X80M管线钢热轧卷板的主要困难在于满足落锤撕裂试验(DWTT)的性能指标[3]。落锤撕裂试验是一个衡量材料韧脆性特性的试验项目[4],主要用于金属材料低温韧性的研究。石油管线的技术协议和执行标准要求22 mm厚规格的X80M管线钢的落锤撕裂韧性断口面积比例超过85%。厚规格板卷断裂韧性控制是制约大口径厚壁高钢级管线钢开发的技术瓶颈[5],同时,焊接工艺和焊材的匹配程度也限制了管线钢合金元素的添加量[6],因此,单纯增加合金含量提高韧性的方法难以实现,通过优化生产过程中的关键工序来满足板卷的独特性能要求。
本文主要就厚规格X80M热轧管线钢在生产试制过程中出现DWTT性能不达标的问题,通过对不同脆性断口面积比例试样的组织形貌与铸坯原料厚度方向成分偏析程度采用电镜进行系统检测分析,得出影响DWTT性能的主要因素是钢带厚度方向存在严重的带状偏析,通过优化铸机设备精度和二冷比水量,改善了铸坯中心偏析,有效提高了卷板的DWTT性能,解决了厚规格高钢级管线钢在研发和试制过程中DWTT性能精准控制的难题,实现了22 mm厚规格X80M大口径长距离运输管线用钢的技术开发和稳定生产。
某厂在X80M管线钢的开发和试制初期,试制厚度规格为22 mm的产品出现了大量的DWTT性能不合格问题。图1为对试样组落锤撕裂性能检测得出的韧性断口面积比例统计,由图1可以见,初验样(a)和复验样(b)试样组的韧性断口面积比例大量低于85%的标准要求,这直接导致板卷生产的合格率下降,对整个生产过程产生了很大的影响。
该批次板卷落锤检测不合格试样的断口类型主要是分层断口,图2为韧性断口面积比例低于85%的试样断口形貌。由图2可见,撕裂断口处有明显的二次裂纹,裂纹垂直于断口平面,平行于钢板平面。
针对落锤不合格试样检测厚度方向偏析程度,对试样表面进行了抛光及热酸腐蚀处理,由图3低倍检测结果可明显看出试样脆性断口区域对应的中心偏析程度较韧性断口区域严重。
为进一步检验铸坯的成分偏析程度,对同炉低倍试样进行全厚度(230 mm)方向成分检验,取样位置为铸坯宽度方向1/4处,试样规格为20 mm×10 mm×230 mm,将试样分成五块进行抛光,成分检测打点位置详见图4
图5为元素C、Mn、P、Nb在铸坯厚度方向的含量分布,C含量的分布范围是0.044%~0.064%,偏析程度为0.02%,偏析指数为1.28;Mn含量的分布范围是1.70%~1.80%,偏析程度为0.10%,偏析指数为1.04;P含量的分布范围是0.012%~0.016%,偏析程度为0.004%,偏析指数为1.2;Nb含量的分布范围是0.066%~0.084%,偏析程度为0.018%,偏析指数为1.19。检测结果表明该批次的X80M铸坯中心成分偏析非常严重。
通过对不同韧性断口剪切面积的DWTT检测试样进行显微组织观察发现,剪切面积越小,样本在厚度方向上的偏析越明显,见图6。该批次板卷对应的铸坯低倍检测结果均为B类2.0,而且在铸坯的厚度中心处,偏析物呈现了明显的集中趋势。
铸坯凝固末端附近的钢液流动的动力来源于坯壳的鼓肚,以及钢液凝固时的体积收缩。轻压下技术是在收缩辊缝技术的基础上发展而来,它通过对连铸坯液芯末端附近施加适度的压力,形成必要的压下量,以补偿铸坯在凝固过程中形成的收缩量。
铸机扇形段设备的对弧精度对铸坯的轻压下效果影响显著,经对铸机扇形段弧度检测,对存在问题的扇形段进行了精确的调整修复,以保证生产过程中扇形段轻压下对铸坯中心偏析的改善效果。
辊缝仪测量结果显示,检修后铸机扇形段对弧精度得到了改善,调整后各扇形段之间弧度偏差均小于0.5 mm,铸机设备整体状况良好,有效提高了铸坯中心偏析的控制水平。
分析了56炉次样本的二冷比水量对铸坯中心C偏析的影响,在相同拉速和过热度条件下,铸坯中心C偏析受二冷比水量的影响见图7。由图7可见,比水量达到0.8 L/kg时,C偏析指数降至最低点。此外,低倍检测结果也验证了在该比水量下,铸坯的等轴晶比例达到最大。在二冷比水量调整到0.8 L/kg时,铸坯液相穴末段与轻压下扇形段能够精确匹配,铸坯中心偏析问题得到极大的改善。
对采取优化措施后生产的铸坯进行热酸低倍检验,检测结果表明中心偏析为C类2.0,中心疏松评级0.5以下占比在92%以上,铸坯质量良好,调整后铸坯低倍宏观照片见图8。通过调整铸机扇形段香蕉梁的基准弧度,保证了扇形段弧度的精度,有效提高了铸坯内部质量,中心偏析评级为C类的占比从调整前的70%增到了92%以上,热轧钢带的DWTT性能得到了进一步提高。
管线钢的DWTT性能与厚度方向的氧化物和硫化物夹杂的聚集程度密切相关[5],若这些偏析物聚集在管线钢的中心,会大幅削弱其韧性,并导致落锤分层现象。因此,要保证管线钢的DWTT性能,必须提高对铸坯中心偏析的控制水平,以降低偏析程度对DWTT性能的负面影响[3]
铸坯质量提高后,X80M管线钢热轧卷板的DWTT性能有了显著的提高。当板卷在-15 ℃下进行落锤撕裂测试时,所有单取样样本的剪切面积的百分比都超过了85%,双取样样本的平均剪切面积百分比超过90%的情况达到100%,均满足标准需求,见图9
图10显示了X80M管线钢热轧卷板系列温度落锤撕裂试验结果,其中板卷30°方向、横向、纵向韧脆转变温度分别为-33 ℃、-13 ℃、-40 ℃。这充分表明了铸坯质量的提高,有效提高了板卷的DWTT性能的控制水平。
(1)铸机在线扇形段之间对弧偏差小于0.5 mm,二冷水比水量在0.8 L/kg,可实现铸坯液相穴末端与轻压下位置的精确匹配,铸坯中心偏析得到有效改善。
(2)钢板厚度方向偏析程度与管线钢的落锤撕裂性能具有较强的对应性,当偏析物聚集于钢板中部时,会导致管线钢的韧性明显恶化,引起落锤撕裂现象,严重影响管线钢的使用性能,因此,必须对铸坯中心偏析进行精准控制,以保证管线钢具备优良的DWTT性能。
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  • 接收时间:2024-01-22
  • 首发时间:2025-10-23
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    1 内蒙古包钢钢联股份有限公司销售分公司,内蒙古 包头 014010
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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