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Chromatographic separation was accomplished on a BEH C18 column（2.1 mm×100 mm,1.7 μm chromatographic column） . The mass spectrometer conducted real-time detection through the positive ion multiple reaction monitoring（MRM）mode and completed quantitative analysis by external standard method combined with the matrix-matched standard curve.[Result] Within the concentration range of 1~80 ng/mL,the four nitroimidazole drugs had a good linearity,with correlation coefficients（r）were all greater than 0.998.The average recovery rate was 83.2%~106.8% at three spiked levels（1.0 μg/kg,2.0 μg/kg and 10.0 μg/kg）,the relative standard deviation（RSD）was 1.8%~20.1%.The detection limit of the method 1 μg/kg.[Conclusion] This method is simple to operate,sensitive and accurate,and is suitable for the detection of nitroimidazole drugs（metronidazole,tinidazole,dimedinidazole,ronidazole） residues in goat milk., authors=YI Hongbo, YANG Jian^*, ZHANG Lijun, LU Gang, DONG Liya, YANG Ying, LI Zhenxia, authorsList=YI Hongbo, YANG Jian, ZHANG Lijun, LU Gang, DONG Liya, YANG Ying, LI Zhenxia, authorCompany=Inner Mongolia Mengniu Dairy Industrial Co.,Ltd.,Hohhot Inner Mongolia 011500, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1321421076110889454, articleId=1321421074332504556, tenantId=1146029695717560320, journalId=1296801528146919473, language=CN, title=超高效液相色谱-串联质谱法检测羊奶中硝基咪唑类药物残留量研究, columnId=1297134032135938673, journalTitle=中国乳业, columnName=质量安全, runingTitle=null, highlight=null, articleAbstract=[目的]研发一项采用超高效液相色谱-串联质谱（UHPLC-MS/MS）技术精确检测羊奶中硝基咪唑类药物（包含甲硝唑、地美硝唑、洛硝哒唑及替硝唑等）残留量的方法。[方法]采用乙腈与柠檬酸缓冲液提取羊奶样品,随后用MCX阳离子交换固相萃取柱和PEP-2聚合物固相萃取柱净化处理。氮吹洗脱液至近干后,用含0.1%甲酸的水甲醇溶液定容至1 mL,用流相0.1%甲酸水溶液和乙腈渐变洗脱,色谱分离采用BEH C18柱（2.1 mm×100 mm,1.7 μm）。质谱仪通过正离子多反应监测（MRM）模式实时检测,并运用外标法结合基质匹配标准曲线完成定量分析。[结果]在1~80 ng/mL浓度范围内,4 种硝基咪唑类药物残留量具有较好的线性关系,相关系数（r）均大于0.998;平均回收率在3 个加标水平下（1 μg/kg、2 μg/kg和10 μg/kg）为83.2%~106.8%,相对标准偏差为1.8%~20.1%,方法检出限为1 μg/kg。[结论]该方法操作简单、灵敏、准确,适用于羊奶中硝基咪唑类药物残留量的检测。, authors=仪虹伯, 杨戬^*, 张利俊, 逯刚, 董立雅, 杨颖, 李振侠, authorsList=仪虹伯, 杨戬, 张利俊, 逯刚, 董立雅, 杨颖, 李振侠, authorCompany=内蒙古蒙牛乳业集团股份有限公司,内蒙古呼和浩特 011500, correspAuthors=^*杨戬（1992-）,男,内蒙古呼和浩特人,本科,工程师,研究方向为乳品快速检测技术开发及应用。, authorNote=仪虹伯（1988-）,女,内蒙古呼和浩特人,蒙古族,硕士,工程师,研究方向为乳品检验技术;张利俊（1985-）,男,内蒙古呼和浩特人,本科,工程师,研究方向为乳品检验技术;逯刚（1978-）,男,内蒙古呼和浩特人,硕士,高级工程师,研究方向为食品质量安全研究;董立雅（1987-）,女,北京人,硕士,工程师,研究方向为食品质量安全研究;杨颖（1986-）,女,内蒙古扎兰屯人,本科,中级工程师,研究方向为食品安全和追溯系统;李振侠（1997-）,女,内蒙古包头人,本科,助理工程师,研究方向为乳品检测。, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=S/uBMPPCR3AATi+mjgQKUQ==, pdfFileSize=2130801, pdfExtLink=null, richHtmlUrl=null, 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