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Co-doped ZnO gas-sensitive materials were synthesized via a hydrothermal method, and the influence of varying Co doping concentrations on their gas-sensing properties was systematically investigated. Furthermore, focusing on the emission characteristics of acetone within the multi-component VOCs generated during rubber vulcanization, the feasibility of real-time acetone detection using these materials was explored, aiming to enable cost-effective operation of adsorption systems under compliance conditions. The results indicated that the Co-ZnO-2% sensor achieved a high response value of 1146.8 to 260mg/m³ acetone at 240℃, with rapid response and recovery times of 16s and 8s, respectively. Additionally, it exhibited excellent selectivity, reproducibility, and long-term stability toward acetone. In a simulated VOC adsorption purification experiment, the Co-ZnO-2% sensor was applied, and its response values were demonstrated to effectively indicate both the breakthrough and saturation states of the adsorbent. Under multi-component adsorption conditions, with acetone as a representative indicator, a warning threshold and a concentration prediction model, X_acetone=(Y-16.89)/4.47, were established to estimate VOC concentrations. This approach successfully realized online monitoring of the adsorption process and evaluation of the emission status.

, authors=Jia-li YANG^{1, 2}, Xiao-qing DANG^{1, *}, He WANG^{1, 2}, authorsList=Jia-li YANG, Xiao-qing DANG, He WANG, authorCompany=null, correspAuthors=Xiao-qing DANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314923017768100233, articleId=1314923015805165959, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=Co-ZnO气敏材料对丙酮的响应特性及废气检测, columnId=1234106388364981004, journalTitle=中国环境科学, columnName=大气污染与控制, runingTitle=null, highlight=null, articleAbstract=

采用水热法制备了Co掺杂的ZnO气敏材料，研究了不同Co掺杂浓度对其气敏性能的影响，并围绕橡胶硫化过程多组分VOCs中丙酮的排放特征，探讨气敏材料对其的实时检测以实现吸附系统达标条件下的低成本运行．结果表明，Co-ZnO-2%在240°C下对260mg/m³丙酮的响应值达1146.8，响应/恢复时间分别为16s和8s，且对丙酮具有良好的选择性、重复性及长期稳定性．将Co-ZnO-2%应用于吸附净化VOCs模拟实验，实验验证其响应值可有效反映吸附剂的穿透与饱和状态．在多组分吸附条件下，将丙酮作为代表性指标，通过引入预警阈值及浓度预测模型X_丙酮=（Y -16.89）/4.47进行VOCs浓度推断，实现了吸附过程的在线检测与排放状态评估．

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杨佳丽（2001-），女，四川眉山人，西安建筑科技大学硕士研究生，主要从事大气污染控制的研究．18828359573@163.com.

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杨佳丽（2001-），女，四川眉山人，西安建筑科技大学硕士研究生，主要从事大气污染控制的研究．18828359573@163.com.

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