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2.5 composition and reactive nitrogen species in Zhengzhou, columnId=1234106386020365051, journalTitle=China Environmental Science, columnName=Air Pollution Control, runingTitle=null, highlight=null, articleAbstract=
A comparative analysis of air quality in Zhengzhou before and after the Spring Festival from 2020 to 2023 was conducted, and high time-resolution observational data on PM2.5 chemical components and reactive nitrogen gases were utilized to systematically evaluate the impact of fireworks during the 2023 Spring Festival on PM2.5 concentrations, its chemical composition, NH3, and HONO. The results indicate that PM2.5 concentrations in Zhengzhou around the Spring Festival decreased by 67% from 2020 to 2022. However, following the relaxation of fireworks restrictions in 2023, PM2.5 concentrations increased by 123% year-on-year, with concentrations during the peak fireworks-burning period surging to 8.7 times those of previous periods. Fireworks contributed to 49.6% of PM2.5 concentrations during the 7-day Spring Festival holiday, with the most significant increases observed in the concentrations of K+, SO42-, and Cl-. Simultaneously, concentrations of toxic and hazardous heavy metal elements, including Al, V, Cr, Cu, Zn, Ba, and Pb, increased significantly during the fireworks-burning period. Furthermore, NH3 concentrations reached (18.4 ± 8.9)μg/m3 during this period, 1.7 times higher than during non-festival periods, a change that promoted an increase in aerosol pH values. Additionally, HONO concentrations rose to (1.26 ± 0.83)×10-9 during fireworks burning, representing an increase of 72.6%. This is likely because fireworks led to elevated atmospheric concentrations of NO, NO2, particulate matter, and nitrates, which in turn promoted the heterogeneous conversion of NO2, nitrate photolysis, and homogeneous reactions, thereby facilitating HONO formation.
, authors=Jie TAO
1, Xin-hao SHANG
2, 3, Ming-kai WANG
4, Xin-yuan ZHANG
4, Shen-bo WANG
2, *, Rui-qin ZHANG
2, authorsList=Jie TAO, Xin-hao SHANG, Ming-kai WANG, Xin-yuan ZHANG, Shen-bo WANG, Rui-qin ZHANG, authorCompany=null, correspAuthors=Shen-bo WANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314922173702168944, articleId=1314922173014303086, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=烟花爆竹燃放对郑州市PM
2.5化学组分及活性氮物种的影响, columnId=1234106388364981004, journalTitle=中国环境科学, columnName=大气污染与控制, runingTitle=null, highlight=null, articleAbstract=
对比分析了郑州市2020~2023年春节前后空气质量,利用高时间分辨率的PM2.5化学组分及活性氮气体观测数据,系统评估了2023年春节期间烟花燃放对PM2.5浓度及其化学组分,NH3与HONO的影响.结果表明,2020~2022年郑州市春节前后PM2.5浓度下降了67%,而2023年燃放政策放宽后PM2.5浓度同比上升了123%,烟花集中燃放时段的PM2.5浓度显著上升至以往时段的8.7倍.春节7d假期内烟花燃放贡献了49.6%的PM2.5浓度,其中K+、SO42-和Cl-浓度的增幅最高.同时,烟花燃放时段有毒有害重金属元素Al、V、Cr、Cu、Zn、Ba和Pb的浓度显著增加.另一方面,烟花燃放时段NH3浓度达到(18.4±8.9)μg/m3,较非春节时段高出1.7倍,该变化促进了气溶胶pH值上升.此外,烟花燃放期间HONO浓度升至(1.26±0.83)×10-9,增幅达72.6%;其原因可能是烟花燃放导致大气中NO、NO2、颗粒物及硝酸盐浓度升高,进而促进了NO2的非均相转化,硝酸盐光解及均相反应,有利于HONO的生成.
, authors=陶杰
1, 尚鑫豪
2, 3, 王铭凯
4, 张馨元
4, 王申博
2, *, 张瑞芹
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1.河南省郑州生态环境监测中心,河南 郑州 450046, bio={"content":"
陶杰(1976-),男,河南新野人,高级工程师,学士,主要研究方向为大气污染研究与控制.发表论文5篇.363428151@qq.com.
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陶杰(1976-),男,河南新野人,高级工程师,学士,主要研究方向为大气污染研究与控制.发表论文5篇.363428151@qq.com.
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