Article(id=1314922173014303086, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314922077824578469, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1720022400000, receivedDateStr=2024-07-04, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791431476119, onlineDateStr=2026-10-08, pubDate=1771516800000, pubDateStr=2026-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791431476119, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791431476118, creator=13701087609, updateTime=1791431476118, updator=13701087609, issue=Issue{id=1314922077824578469, tenantId=1146029695717560320, journalId=1234093305789726721, year='2026', volume='46', issue='2', pageStart='593', pageEnd='1184', issueExtLink='null', onlineDate='null', pubDate='1771516800000', pubDateStr='2026-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791431453424, creator='13701087609', updateTime=1791431520751, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314922360277398376, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314922077824578469, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314922360277398377, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314922077824578469, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=657, endPage=665, ext={EN=ArticleExt(id=1314922173291127151, articleId=1314922173014303086, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=Impacts of firework emissions on PM2.5 composition and reactive nitrogen species in Zhengzhou, columnId=1234106386020365051, journalTitle=China Environmental Science, columnName=Air Pollution Control, runingTitle=null, highlight=null, articleAbstract=

A comparative analysis of air quality in Zhengzhou before and after the Spring Festival from 2020 to 2023 was conducted, and high time-resolution observational data on PM2.5 chemical components and reactive nitrogen gases were utilized to systematically evaluate the impact of fireworks during the 2023 Spring Festival on PM2.5 concentrations, its chemical composition, NH3, and HONO. The results indicate that PM2.5 concentrations in Zhengzhou around the Spring Festival decreased by 67% from 2020 to 2022. However, following the relaxation of fireworks restrictions in 2023, PM2.5 concentrations increased by 123% year-on-year, with concentrations during the peak fireworks-burning period surging to 8.7 times those of previous periods. Fireworks contributed to 49.6% of PM2.5 concentrations during the 7-day Spring Festival holiday, with the most significant increases observed in the concentrations of K+, SO42-, and Cl-. Simultaneously, concentrations of toxic and hazardous heavy metal elements, including Al, V, Cr, Cu, Zn, Ba, and Pb, increased significantly during the fireworks-burning period. Furthermore, NH3 concentrations reached (18.4 ± 8.9)μg/m3 during this period, 1.7 times higher than during non-festival periods, a change that promoted an increase in aerosol pH values. Additionally, HONO concentrations rose to (1.26 ± 0.83)×10-9 during fireworks burning, representing an increase of 72.6%. This is likely because fireworks led to elevated atmospheric concentrations of NO, NO2, particulate matter, and nitrates, which in turn promoted the heterogeneous conversion of NO2, nitrate photolysis, and homogeneous reactions, thereby facilitating HONO formation.

, authors=Jie TAO1, Xin-hao SHANG2, 3, Ming-kai WANG4, Xin-yuan ZHANG4, Shen-bo WANG2, *, Rui-qin ZHANG2, authorsList=Jie TAO, Xin-hao SHANG, Ming-kai WANG, Xin-yuan ZHANG, Shen-bo WANG, Rui-qin ZHANG, authorCompany=null, correspAuthors=Shen-bo WANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314922173702168944, articleId=1314922173014303086, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=烟花爆竹燃放对郑州市PM2.5化学组分及活性氮物种的影响, columnId=1234106388364981004, journalTitle=中国环境科学, columnName=大气污染与控制, runingTitle=null, highlight=null, articleAbstract=

对比分析了郑州市2020~2023年春节前后空气质量,利用高时间分辨率的PM2.5化学组分及活性氮气体观测数据,系统评估了2023年春节期间烟花燃放对PM2.5浓度及其化学组分,NH3与HONO的影响.结果表明,2020~2022年郑州市春节前后PM2.5浓度下降了67%,而2023年燃放政策放宽后PM2.5浓度同比上升了123%,烟花集中燃放时段的PM2.5浓度显著上升至以往时段的8.7倍.春节7d假期内烟花燃放贡献了49.6%的PM2.5浓度,其中K+、SO42-和Cl-浓度的增幅最高.同时,烟花燃放时段有毒有害重金属元素Al、V、Cr、Cu、Zn、Ba和Pb的浓度显著增加.另一方面,烟花燃放时段NH3浓度达到(18.4±8.9)μg/m3,较非春节时段高出1.7倍,该变化促进了气溶胶pH值上升.此外,烟花燃放期间HONO浓度升至(1.26±0.83)×10-9,增幅达72.6%;其原因可能是烟花燃放导致大气中NO、NO2、颗粒物及硝酸盐浓度升高,进而促进了NO2的非均相转化,硝酸盐光解及均相反应,有利于HONO的生成.

, authors=陶杰1, 尚鑫豪2, 3, 王铭凯4, 张馨元4, 王申博2, *, 张瑞芹2, authorsList=陶杰, 尚鑫豪, 王铭凯, 张馨元, 王申博, 张瑞芹, authorCompany=null, correspAuthors=王申博, authorNote=

陶杰(1976-),男,河南新野人,高级工程师,学士,主要研究方向为大气污染研究与控制.发表论文5篇..

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* 责任作者,讲师,
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陶杰(1976-),男,河南新野人,高级工程师,学士,主要研究方向为大气污染研究与控制.发表论文5篇..

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陶杰(1976-),男,河南新野人,高级工程师,学士,主要研究方向为大气污染研究与控制.发表论文5篇..

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烟花爆竹燃放对郑州市PM2.5化学组分及活性氮物种的影响
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陶杰 1 , 尚鑫豪 2, 3 , 王铭凯 4 , 张馨元 4 , 王申博 2, * , 张瑞芹 2
中国环境科学 | 大气污染与控制 2026,46(2): 657-665
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中国环境科学 |大气污染与控制 2026 , 46 (2) : 657 -665
烟花爆竹燃放对郑州市PM2.5化学组分及活性氮物种的影响
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陶杰(1976-),男,河南新野人,高级工程师,学士,主要研究方向为大气污染研究与控制.发表论文5篇..

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陶杰(1976-),男,河南新野人,高级工程师,学士,主要研究方向为大气污染研究与控制.发表论文5篇..

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陶杰1 , 尚鑫豪2, 3, 王铭凯4, 张馨元4, 王申博2, * , 张瑞芹2
作者信息
  • 1.河南省郑州生态环境监测中心,河南 郑州 450046
  • 2.郑州大学生态与环境学院,河南 郑州 450001
  • 3.郑州弗迪电池有限公司,河南 郑州 451162
  • 4.郑州大学化学学院,河南 郑州 450001
通讯作者:
* 责任作者,讲师,
作者简介:

陶杰(1976-),男,河南新野人,高级工程师,学士,主要研究方向为大气污染研究与控制.发表论文5篇..

Impacts of firework emissions on PM2.5 composition and reactive nitrogen species in Zhengzhou
Jie TAO1 , Xin-hao SHANG2, 3, Ming-kai WANG4, Xin-yuan ZHANG4, Shen-bo WANG2, * , Rui-qin ZHANG2
Affiliations
  • 1.Zhengzhou Ecology and Environmental Monitoring Center of Henan Province, Zhengzhou 450046, China
  • 2.School of Ecology and Environment, Zhengzhou University, Zhengzhou 450001, China
  • 3.Zhengzhou Fodi Battery Co., Ltd., Zhengzhou 451162, China
  • 4.School of Chemistry, Zhengzhou University, Zhengzhou 450001, China
出版时间: 2026-02-20
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对比分析了郑州市2020~2023年春节前后空气质量,利用高时间分辨率的PM2.5化学组分及活性氮气体观测数据,系统评估了2023年春节期间烟花燃放对PM2.5浓度及其化学组分,NH3与HONO的影响.结果表明,2020~2022年郑州市春节前后PM2.5浓度下降了67%,而2023年燃放政策放宽后PM2.5浓度同比上升了123%,烟花集中燃放时段的PM2.5浓度显著上升至以往时段的8.7倍.春节7d假期内烟花燃放贡献了49.6%的PM2.5浓度,其中K+、SO42-和Cl-浓度的增幅最高.同时,烟花燃放时段有毒有害重金属元素Al、V、Cr、Cu、Zn、Ba和Pb的浓度显著增加.另一方面,烟花燃放时段NH3浓度达到(18.4±8.9)μg/m3,较非春节时段高出1.7倍,该变化促进了气溶胶pH值上升.此外,烟花燃放期间HONO浓度升至(1.26±0.83)×10-9,增幅达72.6%;其原因可能是烟花燃放导致大气中NO、NO2、颗粒物及硝酸盐浓度升高,进而促进了NO2的非均相转化,硝酸盐光解及均相反应,有利于HONO的生成.

烟花爆竹  /  PM2.5  /  化学组分  /  重金属  /  活性氮化合物

A comparative analysis of air quality in Zhengzhou before and after the Spring Festival from 2020 to 2023 was conducted, and high time-resolution observational data on PM2.5 chemical components and reactive nitrogen gases were utilized to systematically evaluate the impact of fireworks during the 2023 Spring Festival on PM2.5 concentrations, its chemical composition, NH3, and HONO. The results indicate that PM2.5 concentrations in Zhengzhou around the Spring Festival decreased by 67% from 2020 to 2022. However, following the relaxation of fireworks restrictions in 2023, PM2.5 concentrations increased by 123% year-on-year, with concentrations during the peak fireworks-burning period surging to 8.7 times those of previous periods. Fireworks contributed to 49.6% of PM2.5 concentrations during the 7-day Spring Festival holiday, with the most significant increases observed in the concentrations of K+, SO42-, and Cl-. Simultaneously, concentrations of toxic and hazardous heavy metal elements, including Al, V, Cr, Cu, Zn, Ba, and Pb, increased significantly during the fireworks-burning period. Furthermore, NH3 concentrations reached (18.4 ± 8.9)μg/m3 during this period, 1.7 times higher than during non-festival periods, a change that promoted an increase in aerosol pH values. Additionally, HONO concentrations rose to (1.26 ± 0.83)×10-9 during fireworks burning, representing an increase of 72.6%. This is likely because fireworks led to elevated atmospheric concentrations of NO, NO2, particulate matter, and nitrates, which in turn promoted the heterogeneous conversion of NO2, nitrate photolysis, and homogeneous reactions, thereby facilitating HONO formation.

fireworks  /  PM2.5  /  chemical components  /  heavy metals  /  reactive nitrogen compounds
陶杰, 尚鑫豪, 王铭凯, 张馨元, 王申博, 张瑞芹. 烟花爆竹燃放对郑州市PM2.5化学组分及活性氮物种的影响. 中国环境科学, 2026 , 46 (2) : 657 -665 .
Jie TAO, Xin-hao SHANG, Ming-kai WANG, Xin-yuan ZHANG, Shen-bo WANG, Rui-qin ZHANG. Impacts of firework emissions on PM2.5 composition and reactive nitrogen species in Zhengzhou[J]. China Environmental Science, 2026 , 46 (2) : 657 -665 .
  • 国家重点研发计划项目(2024YFC3713700)
  • 郑州市PM2.5与O3协同控制监测项目(20220347A)
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2026年第46卷第2期
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  • 接收时间:2024-07-04
  • 首发时间:2026-10-08
  • 出版时间:2026-02-20
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  • 收稿日期:2024-07-04
基金
国家重点研发计划项目(2024YFC3713700)
郑州市PM2.5与O3协同控制监测项目(20220347A)
作者信息
    1.河南省郑州生态环境监测中心,河南 郑州 450046
    2.郑州大学生态与环境学院,河南 郑州 450001
    3.郑州弗迪电池有限公司,河南 郑州 451162
    4.郑州大学化学学院,河南 郑州 450001

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2种不同金属材料的力学参数
科
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属数
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genus
种数
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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