Article(id=1314922086888469463, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314922077824578469, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1751385600000, receivedDateStr=2025-07-02, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791431455585, onlineDateStr=2026-10-08, pubDate=1771516800000, pubDateStr=2026-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791431455585, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791431455585, creator=13701087609, updateTime=1791431455585, updator=13701087609, issue=Issue{id=1314922077824578469, tenantId=1146029695717560320, journalId=1234093305789726721, year='2026', volume='46', issue='2', pageStart='593', pageEnd='1184', issueExtLink='null', onlineDate='null', pubDate='1771516800000', pubDateStr='2026-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791431453424, creator='13701087609', updateTime=1791431520751, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314922360277398376, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314922077824578469, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314922360277398377, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314922077824578469, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=888, endPage=897, ext={EN=ArticleExt(id=1314922087093990360, articleId=1314922086888469463, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=Large-volume solid phase extraction-based extraction and compositional characterization of natural freshwater dissolved organic matter, columnId=1234106388083954308, journalTitle=China Environmental Science, columnName=Environmental Ecology, runingTitle=null, highlight=null, articleAbstract=
Dissolved organic matter (DOM) is a key component of aquatic ecosystems and the global carbon cycle. However, the lack of reference samples for endogenous freshwater DOM has hindered a deeper understanding of its environmental behavior and biogeochemical cycling. This study aims to provide a gram-scale, high-purity endogenous freshwater DOM reference sample. By employing an amplified solid-phase extraction method using modified styrene-divinylbenzene polymer resin-packed columns, 8tons of water from the central line project of South-to-North Water Diversion were processed, successfully yielding 13.12g of DOM, named as NSBD-DOM. A comprehensive suite of analytical techniques—including elemental analysis, Fourier transform infrared spectroscopy, excitation-emission matrix spectra, nuclear magnetic resonance spectroscopy, and high-resolution mass spectrometry—was employed to systematically compare NSBD-DOM with Suwannee River Fulvic Acid (SRFA) from the International Humic Substances Society. The NSBD-DOM was predominantly composed of fulvic acid like components, exhibiting characteristic of carbohydrate anomeric carbon, alkenes/conjugated alkenes, and amino sugars. Compared to SRFA, NSBD-DOM exhibited lower molecular weight, condensation degree, and oxygen content, accompanied by lower levels of polyphenols and polycyclic aromatics. However, it showed a higher H/C ratio and higher nitrogen content, with elevated levels of unsaturated aliphatic compounds and highly unsaturated compounds. NSBD-DOM exhibits typical endogenous characteristics, it can serve as a unified reference for studies on DOM's environmental behavior, carbon cycling, and related research fields.
, authors=Hao-jie HU
1, Chen HE
1, *, Na PAN
2, Yang-rong WANG
1, Yi-da WANG
1, Gui-xue SONG
3, Xue-song BAI
2, Zhen-xin RUAN
2, Jia-xin WEN
2, Ya-qi WANG
2, Quan SHI
1, *, authorsList=Hao-jie HU, Chen HE, Na PAN, Yang-rong WANG, Yi-da WANG, Gui-xue SONG, Xue-song BAI, Zhen-xin RUAN, Jia-xin WEN, Ya-qi WANG, Quan SHI, authorCompany=null, correspAuthors=Chen HE, Quan SHI, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314922087358231513, articleId=1314922086888469463, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=基于大体积固相萃取的天然淡水溶解性有机质提取及组成表征, columnId=1234106388268503686, journalTitle=中国环境科学, columnName=环境生态, runingTitle=null, highlight=null, articleAbstract=
溶解性有机质(DOM)是水生生态系统和全球碳循环的关键组分,但淡水内源DOM参考样品的缺乏,制约了对其环境行为和生物地球化学循环的深入理解.本研究旨在提供一种克级高纯度淡水内源DOM参考样品.通过放大的改性苯乙烯-二乙烯基苯聚合物树脂填充柱固相萃取法,处理南水北调中线工程8t河水,成功制备了13.12g DOM,命名为NSBD-DOM.综合运用元素分析、傅立叶变换红外光谱、三维荧光光谱、核磁共振波谱和高分辨质谱等手段,系统表征了NSBD-DOM的化学组成,并与国际腐殖酸协会提供的苏万尼河富里酸(SRFA)进行对比.结果表明,NSBD-DOM主体为类富里酸组分,包含碳水化合物端基碳、烯烃/共轭烯烃以及氨基糖等特征.相较于SRFA,NSBD-DOM的分子量、缩合度、氧元素含量较低,其中多酚类和多环芳烃类化合物含量较低;然而,其氢碳比、氮含量、不饱和脂肪族化合物和高度不饱和化合物含量较高.NSBD-DOM具备典型内源特征,可为DOM的环境行为、碳循环等研究提供参考.
, authors=胡浩杰
1, 何晨
1, *, 潘娜
2, 王飏荣
1, 王一达
1, 宋桂雪
3, 白雪松
2, 阮振鑫
2, 温佳鑫
2, 王亚琦
2, 史权
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胡浩杰(1998-),男,山东东营人,中国石油大学(北京)博士研究生,主要从事溶解性有机质分子组成与结构研究.发表论文5篇.hhj_cup@163.com.
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胡浩杰(1998-),男,山东东营人,中国石油大学(北京)博士研究生,主要从事溶解性有机质分子组成与结构研究.发表论文5篇.hhj_cup@163.com.
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胡浩杰(1998-),男,山东东营人,中国石油大学(北京)博士研究生,主要从事溶解性有机质分子组成与结构研究.发表论文5篇.hhj_cup@163.com.
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2, address=
2.Beijing Branch, China South to North Water Diversion Group Mid Route Co. Ltd., Beijing 102408, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1314922088528442353, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314922086888469463, authorId=1314922088381641710, language=CN, stringName=潘娜, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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2.中国南水北调集团中线有限公司北京分公司,北京 102408, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1314922087672804317, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314922086888469463, xref=2., ext=[AuthorCompanyExt(id=1314922087681192926, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314922086888469463, companyId=1314922087672804317, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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1.State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1314922088733963254, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314922086888469463, authorId=1314922088599745523, language=CN, stringName=王飏荣, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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3.Institute of Marine Science and Technology, Shandong University, Qingdao 266237, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1314922089262444544, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314922086888469463, authorId=1314922089065313278, language=CN, stringName=宋桂雪, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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3.山东大学海洋研究院,山东 青岛 266237, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1314922087773467616, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314922086888469463, xref=3., ext=[AuthorCompanyExt(id=1314922087781856225, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314922086888469463, companyId=1314922087773467616, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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