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The aim of this study was to investigate the performance of calcination-modified Drinking Water Treatment Residual (DWTR) in removing typical pollutants in stormwater. The results showed that the aluminium contents of DWTR were as high as 14g/kg, which were significantly higher than that of general soil, and the XRD pattern showed higher alumina peaks, and the calcination modification could further improve the specific surface area and surface characteristics of the sludge; the isothermal adsorption characteristics of DWTR for the typical stormwater pollutants of phosphate, ammonia, nitrogen, and lead ions were better fitted to both Langmuir and Freundlich model, and the results of kinetic experiments showed that the adsorption process was more in line with the quasi-secondary kinetic model, indicating that the adsorption process was dominated by chemical adsorption and accompanied by physical adsorption, and the adsorption performance of calcined modified sludge was generally better than that of air-dried and screened sludge only, and the morphology analysis showed that more adsorbed lead could exist in the relatively stable carbonate-bound state of lead; The adsorption performance of soil columns based on the substrate of sludge from a water purification plant for typical The soil columns based on the water purification plant sludge matrix could remove 100%, 98%, 86.94% and 85% of the typical rainwater pollutants (orthophosphate, lead ion, ammonia nitrogen, COD), and 59% to 78% of the natural rainfall and rooftop rainfall in Beijing with a COD of 65~85mg/L, and the effluent could meet the environmental quality standard of 30mg/L for surface water IV, which indicated that both air-dried sieved and calcined modified sludge have the potential to be used for the treatment of water purification plant sludge. This indicates that both air-dried and calcined water purification plant sludge have the potential to be used as urban artificial wetland substrate for soil replacement and rainwater purification.

, authors=Dong-hai CAO1, Xiao-ting SUN2, Yuan-hao ZHU1, Si-jia MA1, Si-yi ZHANG1, Li-ming DONG1, *, authorsList=Dong-hai CAO, Xiao-ting SUN, Yuan-hao ZHU, Si-jia MA, Si-yi ZHANG, Li-ming DONG, authorCompany=null, correspAuthors=Li-ming DONG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314922078856377255, articleId=1314922078294340517, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=煅烧改性净水厂污泥去除雨水中典型污染物性能研究, columnId=1234106386565624579, journalTitle=中国环境科学, columnName=水污染与控制, runingTitle=null, highlight=null, articleAbstract=

探讨煅烧改性净水厂污泥(DWTR)在去除雨水中典型污染物方面的性能.结果表明,DWTR中的铝含量高达14g/kg,显著高于一般土壤,且XRD图谱分析显示出较高的氧化铝峰,煅烧改性可进一步提高污泥的比表面积和表面特征;DWTR对典型雨水污染物磷酸盐、氨氮和Pb离子的等温吸附特性均较好拟合Langmuir和Freundlich模型,动力学实验结果表明吸附过程更符合准二级动力学模型,说明吸附过程以化学吸附为主,同时伴随物理吸附,煅烧改性污泥的吸附性能普遍优于仅风干筛分污泥,且形态分析表明更多的吸附Pb能以相对稳定的碳酸盐结合态Pb存在;基于净水厂污泥基质的土壤柱对典型雨水污染物(正磷酸盐、Pb离子、氨氮、COD)的去除率分别可达100%、98%、86.94%和85%,对北京地区COD为65~85mg/L的自然降雨和屋顶雨水的去除率可达59%~78%,出水能满足30mg/L的地表水Ⅳ类水环境质量标准,表明风干筛分和煅烧改性后的净水厂污泥均具备用于城市人工湿地基质进行土壤替代和雨水净化的应用潜力.

, authors=曹东海1, 孙小婷2, 朱元浩1, 马思佳1, 张丝艺1, 董黎明1, *, authorsList=曹东海, 孙小婷, 朱元浩, 马思佳, 张丝艺, 董黎明, authorCompany=null, correspAuthors=董黎明, authorNote=

曹东海(2000-),男,辽宁朝阳人,北京工商大学硕士研究生,研究方向为清洁生产与资源化利用..

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曹东海(2000-),男,辽宁朝阳人,北京工商大学硕士研究生,研究方向为清洁生产与资源化利用..

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曹东海(2000-),男,辽宁朝阳人,北京工商大学硕士研究生,研究方向为清洁生产与资源化利用..

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煅烧改性净水厂污泥去除雨水中典型污染物性能研究
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曹东海 1 , 孙小婷 2 , 朱元浩 1 , 马思佳 1 , 张丝艺 1 , 董黎明 1, *
中国环境科学 | 水污染与控制 2026,46(2): 769-775
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中国环境科学 |水污染与控制 2026 , 46 (2) : 769 -775
煅烧改性净水厂污泥去除雨水中典型污染物性能研究
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曹东海(2000-),男,辽宁朝阳人,北京工商大学硕士研究生,研究方向为清洁生产与资源化利用..

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曹东海(2000-),男,辽宁朝阳人,北京工商大学硕士研究生,研究方向为清洁生产与资源化利用..

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曹东海1 , 孙小婷2, 朱元浩1, 马思佳1, 张丝艺1, 董黎明1, *
作者信息
  • 1.北京工商大学,中国轻工业清洁生产和资源综合利用重点实验室,国家环境保护食品链污染防治重点实验室,北京 100048
  • 2.北京城市排水集团有限责任公司,北京 100044
通讯作者:
* 责任作者,教授,
作者简介:

曹东海(2000-),男,辽宁朝阳人,北京工商大学硕士研究生,研究方向为清洁生产与资源化利用..

Study on the performance of calcined modified water treatment plant sludge in removing typical pollutants from rainwater
Dong-hai CAO1 , Xiao-ting SUN2, Yuan-hao ZHU1, Si-jia MA1, Si-yi ZHANG1, Li-ming DONG1, *
Affiliations
  • 1.Key Laboratory of Cleaner Production and Integrated Resource Utilization of China National Light Industry, State Environmental Protection Key Lab of Food Chain Pollution Control, Beijing Technology and Business University, Beijing 100048, China
  • 2.Beijing Urban Drainage Group Co, Beijing 100044, China
出版时间: 2026-02-20
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探讨煅烧改性净水厂污泥(DWTR)在去除雨水中典型污染物方面的性能.结果表明,DWTR中的铝含量高达14g/kg,显著高于一般土壤,且XRD图谱分析显示出较高的氧化铝峰,煅烧改性可进一步提高污泥的比表面积和表面特征;DWTR对典型雨水污染物磷酸盐、氨氮和Pb离子的等温吸附特性均较好拟合Langmuir和Freundlich模型,动力学实验结果表明吸附过程更符合准二级动力学模型,说明吸附过程以化学吸附为主,同时伴随物理吸附,煅烧改性污泥的吸附性能普遍优于仅风干筛分污泥,且形态分析表明更多的吸附Pb能以相对稳定的碳酸盐结合态Pb存在;基于净水厂污泥基质的土壤柱对典型雨水污染物(正磷酸盐、Pb离子、氨氮、COD)的去除率分别可达100%、98%、86.94%和85%,对北京地区COD为65~85mg/L的自然降雨和屋顶雨水的去除率可达59%~78%,出水能满足30mg/L的地表水Ⅳ类水环境质量标准,表明风干筛分和煅烧改性后的净水厂污泥均具备用于城市人工湿地基质进行土壤替代和雨水净化的应用潜力.

净水厂污泥  /  煅烧改性  /  雨水净化  /  磷  /  COD

The aim of this study was to investigate the performance of calcination-modified Drinking Water Treatment Residual (DWTR) in removing typical pollutants in stormwater. The results showed that the aluminium contents of DWTR were as high as 14g/kg, which were significantly higher than that of general soil, and the XRD pattern showed higher alumina peaks, and the calcination modification could further improve the specific surface area and surface characteristics of the sludge; the isothermal adsorption characteristics of DWTR for the typical stormwater pollutants of phosphate, ammonia, nitrogen, and lead ions were better fitted to both Langmuir and Freundlich model, and the results of kinetic experiments showed that the adsorption process was more in line with the quasi-secondary kinetic model, indicating that the adsorption process was dominated by chemical adsorption and accompanied by physical adsorption, and the adsorption performance of calcined modified sludge was generally better than that of air-dried and screened sludge only, and the morphology analysis showed that more adsorbed lead could exist in the relatively stable carbonate-bound state of lead; The adsorption performance of soil columns based on the substrate of sludge from a water purification plant for typical The soil columns based on the water purification plant sludge matrix could remove 100%, 98%, 86.94% and 85% of the typical rainwater pollutants (orthophosphate, lead ion, ammonia nitrogen, COD), and 59% to 78% of the natural rainfall and rooftop rainfall in Beijing with a COD of 65~85mg/L, and the effluent could meet the environmental quality standard of 30mg/L for surface water IV, which indicated that both air-dried sieved and calcined modified sludge have the potential to be used for the treatment of water purification plant sludge. This indicates that both air-dried and calcined water purification plant sludge have the potential to be used as urban artificial wetland substrate for soil replacement and rainwater purification.

drinking water treatment residual  /  calcined modified  /  stormwater purification  /  phosphorus  /  COD
曹东海, 孙小婷, 朱元浩, 马思佳, 张丝艺, 董黎明. 煅烧改性净水厂污泥去除雨水中典型污染物性能研究. 中国环境科学, 2026 , 46 (2) : 769 -775 .
Dong-hai CAO, Xiao-ting SUN, Yuan-hao ZHU, Si-jia MA, Si-yi ZHANG, Li-ming DONG. Study on the performance of calcined modified water treatment plant sludge in removing typical pollutants from rainwater[J]. China Environmental Science, 2026 , 46 (2) : 769 -775 .

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  • 接收时间:2025-07-16
  • 首发时间:2026-10-08
  • 出版时间:2026-02-20
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  • 收稿日期:2025-07-16
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    1.北京工商大学,中国轻工业清洁生产和资源综合利用重点实验室,国家环境保护食品链污染防治重点实验室,北京 100048
    2.北京城市排水集团有限责任公司,北京 100044

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2种不同金属材料的力学参数
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属
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species
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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