Article(id=1314921994605392228, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314921940238828053, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1749398400000, receivedDateStr=2025-06-09, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791431433582, onlineDateStr=2026-10-08, pubDate=1768838400000, pubDateStr=2026-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791431433582, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791431433582, creator=13701087609, updateTime=1791431433582, updator=13701087609, issue=Issue{id=1314921940238828053, tenantId=1146029695717560320, journalId=1234093305789726721, year='2026', volume='46', issue='1', pageStart='1', pageEnd='592', issueExtLink='null', onlineDate='null', pubDate='1768838400000', pubDateStr='2026-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791431420621, creator='13701087609', updateTime=1791431552947, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314922495317210104, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314921940238828053, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314922495317210105, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314921940238828053, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=429, endPage=439, ext={EN=ArticleExt(id=1314921996627046757, articleId=1314921994605392228, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=Performance and mechanisms of enhanced retention of aged microplastics by magnetite-loaded biochar, columnId=1240689620866887794, journalTitle=China Environmental Science, columnName=Emerging Contaminants, runingTitle=null, highlight=null, articleAbstract=
To compare their capture efficiency, four types of iron (hydro)oxide-loaded biochar functionalized with ferrihydrite, goethite, hematite, or magnetite were synthesized via co-precipitation method at a consistent iron-to-biochar mass ratio. The modification significantly improved electrostatic attraction between the biochar and aged microplastics, thereby increasing retention capacity. Among these materials, magnetite-loaded biochar demonstrated the highest removal efficiency exceeding 90% and maximum adsorption capacity of 25.02mg/g, representing a 5.53-fold improvement over unmodified biochar. This superior performance is likely attributed to its highest iron oxide loading (4.15wt%). Adsorption data followed both the Langmuir monolayer model and pseudo-first order kinetics. Notably, magnetite-loaded biochar maintained over 95% retention under varying ionic strengths, cation valences, and pH conditions. It also preserved greater than 90% of microplastics in multi-bed volume tests and real-water samples. Moreover, after multiple alkaline washing regeneration cycles, the material remained stable adsorption performance, demonstrating its excellent reusability potential.
, authors=Yu-chen TANG, Cun XIONG, Chang-jian LUO, Yu-ping QIU
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本研究通过调控相同铁炭质量比,采用共沉淀法制备了四种铁(氢)氧化物负载型生物炭,对比了其对水体中老化微塑料的截留效率.研究发现,铁(氢)氧化物(水铁矿、针铁矿、赤铁矿和磁铁矿)负载强化了静电吸引作用,提升了生物炭截留微塑料的能力.其中,磁铁矿负载生物炭的吸附去除最优(>90%),最大吸附量为25.02mg/g,较原始生物炭提升5.53倍,这可能与其铁氧化物负载量最高(4.15wt%)有关.吸附过程遵循Langmuir单层吸附模型与准一级动力学规律.在不同离子强度、阳离子价态和pH值影响下,磁铁矿负载生物炭的截留率均大于95%,且在多床体积截留与实际水体测试中依然保持了90%以上的截留率.磁铁矿负载生物炭经碱洗再生循环后,截留能力依然维持稳定,表明其具有良好的重复利用性.
, authors=唐宇琛, 熊村, 罗长健, 邱宇平
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唐宇琛(1998-),男,山东烟台人,硕士,主要从事环境微塑料研究.2230531@tongji.edu.cn.
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唐宇琛(1998-),男,山东烟台人,硕士,主要从事环境微塑料研究.2230531@tongji.edu.cn.
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