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Article(id=1314921963122950872, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314921940238828053, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1750867200000, receivedDateStr=2025-06-26, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791431426077, onlineDateStr=2026-10-08, pubDate=1768838400000, pubDateStr=2026-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791431426077, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791431426077, creator=13701087609, updateTime=1791431426077, updator=13701087609, issue=Issue{id=1314921940238828053, tenantId=1146029695717560320, journalId=1234093305789726721, year='2026', volume='46', issue='1', pageStart='1', pageEnd='592', issueExtLink='null', onlineDate='null', pubDate='1768838400000', pubDateStr='2026-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791431420621, creator='13701087609', updateTime=1791431552947, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314922495317210104, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314921940238828053, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314922495317210105, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314921940238828053, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=138, endPage=151, ext={EN=ArticleExt(id=1314921965043942106, articleId=1314921963122950872, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=Research progress on the coupled photocatalytic and microbial technology for enhanced nitrogen removal from wastewater, columnId=1234106386360103680, journalTitle=China Environmental Science, columnName=Water Pollution Control, runingTitle=null, highlight=null, articleAbstract=

Addressing the challenge of nitrogen-containing wastewater treatment, the photocatalytic-microbial coupled denitrification technology has emerged as a new research hotspot due to its advantages of high efficiency, cost-effectiveness, and environmental friendliness. After a comparative analysis of the advantages and disadvantages of different photocatalytic denitrification technologies, a detailed introduction to the current research status of domestic and international photocatalytic-microbial coupled denitrification processes is provided. The review emphasizes three major forms of the coupled system, including indirect sequential coupling of photocatalytic and microbial, direct coupling, as well as bioelectrochemical-photocatalytic coupling systems. The intrinsic interaction mechanisms within the coupled system are deeply explored, such as the physiological and ecological responses of microorganisms to photocatalysts, the optimization of microbial communities by the photocatalytic process, the migration and transformation mechanisms of photocatalysts within biofilms, and the electron transfer processes between photocatalysts and microorganisms. Finally, the article points out the existing bottlenecks in this technology, such as the development of visible-light materials, the safety of nanomaterials, the long-term stability of the system, and the scaling up for engineering applications. Suggestions are made for deepening the mechanism research, developing new coupled processes, optimizing materials, and promoting engineering applications, with the aim of providing a reference for the efficient and green treatment of nitrogen-containing wastewater.

, authors=Shu-lin KONG1, 2, 3, 4, Tong ZHANG1, 2, 3, 4, Jian-bo LIN5, Min-sheng HUANG1, 2, 3, 4, Yan HE1, 2, 3, 4, *, Li-hong WANG1, 2, 3, 4, authorsList=Shu-lin KONG, Tong ZHANG, Jian-bo LIN, Min-sheng HUANG, Yan HE, Li-hong WANG, authorCompany=null, correspAuthors=Yan HE, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314921966243513051, articleId=1314921963122950872, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=光催化与微生物耦合技术用于污水强化脱氮的研究进展, columnId=1234106386565624579, journalTitle=中国环境科学, columnName=水污染与控制, runingTitle=null, highlight=null, articleAbstract=

针对含氮废水处理难题，光催化-微生物耦合脱氮技术因其高效、经济、绿色的优势成为新兴的研究热点．在对比分析了不同光催化脱氮技术的优缺点后，对目前光催化-微生物耦合脱氮工艺的国内外研究现状进行了详细介绍．重点综述了耦合体系的三大形式，包括光催化-微生物间接顺序耦合、直接耦合以及生物电化学-光催化耦合系统．深入探讨了耦合体系的内在交互作用机制，如微生物对光催化剂的生理生态响应，光催化过程对微生物群落的优化，光催化剂在生物膜中的迁移转化机制以及光催化剂与微生物之间的电子传递过程．最后指出该技术在可见光材料开发、纳米材料安全性、系统长期稳定性以及工程化放大等方面存在的瓶颈问题．并针对深化机理研究、开发新型耦合工艺、优化材料以及推进工程化应用等方面提出了建议，以期为含氮废水的高效绿色处理提供参考．

, authors=孔书麟1, 2, 3, 4, 张彤1, 2, 3, 4, 林剑波5, 黄民生1, 2, 3, 4, 何岩1, 2, 3, 4, *, 王丽红1, 2, 3, 4, authorsList=孔书麟, 张彤, 林剑波, 黄民生, 何岩, 王丽红, authorCompany=null, correspAuthors=何岩, authorNote=

孔书麟（1995-），男，河南商丘人，华东师范大学博士研究生，主要从事水污染治理与修复研究．发表论文3篇．.

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* 责任作者，教授，
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2.崇明生态研究院，上海 202162
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孔书麟（1995-），男，河南商丘人，华东师范大学博士研究生，主要从事水污染治理与修复研究．发表论文3篇．.

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孔书麟（1995-），男，河南商丘人，华东师范大学博士研究生，主要从事水污染治理与修复研究．发表论文3篇．.

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3.水污染防治与利用山西省重点实验室，山西 太原 030009
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2.Institute of Eco-Chongming, Shanghai 202162, China
3.Shanxi Key Laboratory of Water Pollution Prevention and Utilization, Taiyuan 030009, China
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光催化与微生物耦合技术用于污水强化脱氮的研究进展
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孔书麟 1, 2, 3, 4 , 张彤 1, 2, 3, 4 , 林剑波 5 , 黄民生 1, 2, 3, 4 , 何岩 1, 2, 3, 4, * , 王丽红 1, 2, 3, 4
中国环境科学 | 水污染与控制 2026,46(1): 138-151
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中国环境科学 |水污染与控制 2026 , 46 (1) : 138 -151
光催化与微生物耦合技术用于污水强化脱氮的研究进展
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孔书麟（1995-），男，河南商丘人，华东师范大学博士研究生，主要从事水污染治理与修复研究．发表论文3篇．.

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孔书麟（1995-），男，河南商丘人，华东师范大学博士研究生，主要从事水污染治理与修复研究．发表论文3篇．.

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2.Institute of Eco-Chongming, Shanghai 202162, China
3.Shanxi Key Laboratory of Water Pollution Prevention and Utilization, Taiyuan 030009, China
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2.崇明生态研究院，上海 202162
3.水污染防治与利用山西省重点实验室，山西 太原 030009
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孔书麟1, 2, 3, 4 , 张彤1, 2, 3, 4, 林剑波5, 黄民生1, 2, 3, 4, 何岩1, 2, 3, 4, * , 王丽红1, 2, 3, 4
作者信息
  • 1.华东师范大学生态与环境科学学院，上海 200241
  • 2.崇明生态研究院，上海 202162
  • 3.水污染防治与利用山西省重点实验室，山西 太原 030009
  • 4.自然资源部大都市区国土空间生态修复工程技术创新中心，上海 200062
  • 5.生态环境部太湖流域东海海域生态环境监督管理局生态环境监测与科学研究中心，上海 200125
通讯作者:
* 责任作者，教授，
作者简介:

孔书麟（1995-），男，河南商丘人，华东师范大学博士研究生，主要从事水污染治理与修复研究．发表论文3篇．.

Research progress on the coupled photocatalytic and microbial technology for enhanced nitrogen removal from wastewater
Shu-lin KONG1, 2, 3, 4 , Tong ZHANG1, 2, 3, 4, Jian-bo LIN5, Min-sheng HUANG1, 2, 3, 4, Yan HE1, 2, 3, 4, * , Li-hong WANG1, 2, 3, 4
Affiliations
  • 1.School of Ecological and Environmental Sciences, East China Normal University, Shanghai 200241, China
  • 2.Institute of Eco-Chongming, Shanghai 202162, China
  • 3.Shanxi Key Laboratory of Water Pollution Prevention and Utilization, Taiyuan 030009, China
  • 4.Technology Innvation Center for Land Spatial Eco-Restoration in Metropolitan Area (Ministry of Natural Resources), Shanghai 200062, China
  • 5.Ecological Environment Monitoring and Scientific Research Center, Taihu Basin & East China Sea Ecological Environment Supervision and Administration Bureau, Ministry of Ecology and Environment, Shanghai 200125, China
出版时间: 2026-01-20
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针对含氮废水处理难题，光催化-微生物耦合脱氮技术因其高效、经济、绿色的优势成为新兴的研究热点．在对比分析了不同光催化脱氮技术的优缺点后，对目前光催化-微生物耦合脱氮工艺的国内外研究现状进行了详细介绍．重点综述了耦合体系的三大形式，包括光催化-微生物间接顺序耦合、直接耦合以及生物电化学-光催化耦合系统．深入探讨了耦合体系的内在交互作用机制，如微生物对光催化剂的生理生态响应，光催化过程对微生物群落的优化，光催化剂在生物膜中的迁移转化机制以及光催化剂与微生物之间的电子传递过程．最后指出该技术在可见光材料开发、纳米材料安全性、系统长期稳定性以及工程化放大等方面存在的瓶颈问题．并针对深化机理研究、开发新型耦合工艺、优化材料以及推进工程化应用等方面提出了建议，以期为含氮废水的高效绿色处理提供参考．

光催化技术  /  微生物  /  耦合  /  脱氮  /  去除机制  /  交互作用

Addressing the challenge of nitrogen-containing wastewater treatment, the photocatalytic-microbial coupled denitrification technology has emerged as a new research hotspot due to its advantages of high efficiency, cost-effectiveness, and environmental friendliness. After a comparative analysis of the advantages and disadvantages of different photocatalytic denitrification technologies, a detailed introduction to the current research status of domestic and international photocatalytic-microbial coupled denitrification processes is provided. The review emphasizes three major forms of the coupled system, including indirect sequential coupling of photocatalytic and microbial, direct coupling, as well as bioelectrochemical-photocatalytic coupling systems. The intrinsic interaction mechanisms within the coupled system are deeply explored, such as the physiological and ecological responses of microorganisms to photocatalysts, the optimization of microbial communities by the photocatalytic process, the migration and transformation mechanisms of photocatalysts within biofilms, and the electron transfer processes between photocatalysts and microorganisms. Finally, the article points out the existing bottlenecks in this technology, such as the development of visible-light materials, the safety of nanomaterials, the long-term stability of the system, and the scaling up for engineering applications. Suggestions are made for deepening the mechanism research, developing new coupled processes, optimizing materials, and promoting engineering applications, with the aim of providing a reference for the efficient and green treatment of nitrogen-containing wastewater.

photocatalytic technology  /  microorganisms  /  coupling  /  denitrification  /  removal mechanism  /  interaction
孔书麟, 张彤, 林剑波, 黄民生, 何岩, 王丽红. 光催化与微生物耦合技术用于污水强化脱氮的研究进展. 中国环境科学, 2026 , 46 (1) : 138 -151 .
Shu-lin KONG, Tong ZHANG, Jian-bo LIN, Min-sheng HUANG, Yan HE, Li-hong WANG. Research progress on the coupled photocatalytic and microbial technology for enhanced nitrogen removal from wastewater[J]. China Environmental Science, 2026 , 46 (1) : 138 -151 .
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  • 国家自然科学基金资助项目(42377405; 41877477)
  • 山西省创新生态服务支撑专项-创新平台基地建设专项(SWRFZYLY202501)
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  • 接收时间：2025-06-26
  • 首发时间：2026-10-08
  • 出版时间：2026-01-20
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  • 收稿日期：2025-06-26
基金
国家自然科学基金资助项目(42377405; 41877477)
山西省创新生态服务支撑专项-创新平台基地建设专项(SWRFZYLY202501)
作者信息
    1.华东师范大学生态与环境科学学院，上海 200241
    2.崇明生态研究院，上海 202162
    3.水污染防治与利用山西省重点实验室，山西 太原 030009
    4.自然资源部大都市区国土空间生态修复工程技术创新中心，上海 200062
    5.生态环境部太湖流域东海海域生态环境监督管理局生态环境监测与科学研究中心，上海 200125

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* 责任作者，教授，
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2种不同金属材料的力学参数
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Number of
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Percentage of
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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