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A carbonate-mineralizing bacterial strain C7-1was isolated from karst soil and identified as Serratia marcescens. Through single factor test combined with characterization technology, the cadmium (Cd) removal efficiency and underlyingmechanism of S. marcescens were analyzed, along with its ability toremove Cd, lead (Pb), zinc (Zn), and copper (Cu) from soil. The results indicated that the urea concentration was the main factor controlling Cd²⁺ removal.The maximum Cd2⁺ removal rate reached 74%, which was primarily via extracellular precipitation (42%) followed by surface adsorption (27%). Cd2⁺ may bind to CO₃^2- to form CdCO₃ based on scanning electron microscope-energy dispersive spectroscopy (SEM-EDS), fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The removal efficiencies of strain C7-1for Cd2⁺, Pb2⁺, Zn2⁺ and Cu2⁺ achieved 22.9%~65.9% in soil filtrates. The heavy metal ions were found to form amorphous mineral precipitates through co-precipitation and were adsorbed onthe bacterial surfaces via functional groups, including hydroxyl, carboxyl, carbonate, phosphoric acid, and sulfuric acid groups.

, authors=Qian YANG¹, Xiao-yi LI¹, Jun-yi CAO¹, Yun-feng PAN¹, Cheng-zhong HE², Chun-lin TU², Long-hua WU³, Xin-ran LIANG^{1, *}, Fang-dong ZHAN^{1, *}, authorsList=Qian YANG, Xiao-yi LI, Jun-yi CAO, Yun-feng PAN, Cheng-zhong HE, Chun-lin TU, Long-hua WU, Xin-ran LIANG, Fang-dong ZHAN, authorCompany=null, correspAuthors=Xin-ran LIANG, Fang-dong ZHAN, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314921957150253882, articleId=1314921953878696759, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=碳酸盐矿化菌对喀斯特地区土壤滤液重金属的矿化吸附机制, columnId=1314921943346802741, journalTitle=中国环境科学, columnName=岩溶关键带重金属污染成因, runingTitle=null, highlight=null, articleAbstract=

从喀斯特地区土壤中分离出一株碳酸盐矿化菌C7-1，鉴定为粘质沙雷氏菌（Serratia marcescens），通过单因素实验结合表征技术，解析其对镉（Cd）的去除机制，并探讨其对土壤滤液中Cd、铅（Pb）、锌（Zn）、铜（Cu）的去除方式．结果表明：尿素浓度是调控Cd²⁺去除的关键因素，去除率最高可达74%，其中胞外沉淀（42%）为主要途径，表面吸附（27%）次之；扫描电镜-能谱（SEM-EDS）、傅里叶红外光谱（FTIR）和X射线衍射（XRD）结果发现Cd²⁺可能与CO₃^2-结合形成CdCO₃．土壤滤液中，菌株C7-1对Cd²⁺、Pb²⁺、Zn²⁺和Cu²⁺的去除率在22.9%~65.9%之间．重金属离子以共沉淀的方式形成无定形颗粒状物质，并在羟基、羧基、碳酸根、磷酸和硫酸基团的作用下吸附在菌体表面．

, authors=杨茜¹, 李小艺¹, 曹俊毅¹, 潘云凤¹, 和成忠², 涂春霖², 吴龙华³, 梁新然^{1, *}, 湛方栋^{1, *}, authorsList=杨茜, 李小艺, 曹俊毅, 潘云凤, 和成忠, 涂春霖, 吴龙华, 梁新然, 湛方栋, authorCompany=null, correspAuthors=梁新然, 湛方栋, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=/BeZVK+DvSmgbfRSsZJdjQ==, magXml=JQSPlzt5dwJ60vZ0sIc5fA==, pdfUrl=null, pdf=pf1Kpli7AeekCXbu21mEag==, pdfFileSize=2165325, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=aL2k++vL95OdeD5ntDjOYw==, mapNumber=null, fund=null)}, authors=[Author(id=1314921960602166089, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314921953878696759, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=528904457@qq.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1314921961034179403, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314921953878696759, authorId=1314921960602166089, language=EN, stringName=Qian YANG, firstName=Qian, middleName=null, lastName=YANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1.Key Laboratory for Improving Quality and Productivity of Arable Land of Yunnan Province, College of Resources and Environment, Yunnan Agricultural University, Kunming 650201, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1314921961348752204, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1314921953878696759, authorId=1314921960602166089, language=CN, stringName=杨茜, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1.云南农业大学资源与环境学院，云南省耕地培育与产能提升重点实验室，云南 昆明 650201, bio={"content":"

杨茜（1999-），女，云南昆明人，云南农业大学博士研究生，主要从事重金属污染土壤修复研究．528904457@qq.com.

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杨茜（1999-），女，云南昆明人，云南农业大学博士研究生，主要从事重金属污染土壤修复研究．528904457@qq.com.

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