Article(id=1314918567708029949, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918450573701162, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1747065600000, receivedDateStr=2025-05-13, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791430616546, onlineDateStr=2026-10-08, pubDate=1766160000000, pubDateStr=2025-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791430616546, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791430616546, creator=13701087609, updateTime=1791430616546, updator=13701087609, issue=Issue{id=1314918450573701162, tenantId=1146029695717560320, journalId=1234093305789726721, year='2025', volume='45', issue='12', pageStart='6513', pageEnd='7104', issueExtLink='null', onlineDate='null', pubDate='1766160000000', pubDateStr='2025-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791430588620, creator='13701087609', updateTime=1791431575400, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314922589479333965, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918450573701162, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314922589479333966, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918450573701162, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=6737, endPage=6748, ext={EN=ArticleExt(id=1314918568148431870, articleId=1314918567708029949, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=Influences of fecal dissolved organic matter on the adsorption and transport of veterinary drugs in high organic matter soils, columnId=1234106389669409584, journalTitle=China Environmental Science, columnName=Soil Pollution Control, runingTitle=null, highlight=null, articleAbstract=

Surface and subsurface soils collected from a bamboo forest at the footslope of an upland were used to explore the effects of pig manure dissolved organic (PM DOM) and its hydrophilic (HI) and hydrophobic (HO) fractions on the adsorption, transport, and retention of doxycycline, enrofloxacin, florfenicol, and sulfamethazine. Total DOM was extracted from pig manure and further separated into HI and HO fractions using XAD-8resin column. According to the results of batch equilibrium experiments, the addition of PM DOM led to varying decreases in the adsorption of enrofloxacin, florfenicol, and sulfamethazine but marked increases in the adsorption of doxycycline; the addition of PM DOM's HIS fraction substantially weakened the adsorption of enrofloxacin and florfenicol by the soils; the addition of PM DOM's HO fraction significantly enhanced the adsorption of doxycycline but markedly reduced the adsorption of florfenicol by the soils. According to the results of saturated transport experiments in repacked soil columns, doxycycline and enrofloxacin could make a breakthrough; the HI fraction of PM DOM played a predominant role in reducing the recovery rate of sulfamethazine in the surface and subsurface soils (by 13.6% and 5.4%, respectively), while both the HI and HO fractions of PM DOM increased the recovery rate of florfenicol (only evidenced in the surface soil; by 30.7% and 20.1%, respectively). The addition of PM DOM could enhance the retention of sulfamethazine and florfenicol (by 14.9% and 7.8%, respectively, in the surface soil columns; by 3.1% and 10.6%, respectively, in the subsurface soil columns) while promote the redistribution of enrofloxacin and doxycycline to deeper soil layers. The humification degree and aromaticity of DOM in the aqueous phase of the soils, as well as the content and proportion of humic-like and protein-like components of DOM, might exert a crucial influence on the transport of veterinary drugs in the soils.

, authors=Hao YAN1, Hui-yun XIAO1, Zhuo CHEN1, Yu-juan LV2, Xiang-yu TANG1, *, Jin-sheng HU1, 3, Jian-hua CHENG1, authorsList=Hao YAN, Hui-yun XIAO, Zhuo CHEN, Yu-juan LV, Xiang-yu TANG, Jin-sheng HU, Jian-hua CHENG, authorCompany=null, correspAuthors=Xiang-yu TANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314918568534307839, articleId=1314918567708029949, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=粪源溶解性有机质对高有机质土壤中兽药吸附与迁移的影响, columnId=1234106394572550190, journalTitle=中国环境科学, columnName=土壤污染与控制, runingTitle=null, highlight=null, articleAbstract=

以坡脚旱地雷竹林表层和亚表层土壤为对象,研究猪粪DOM及其亲水和疏水组分对强力霉素、恩诺沙星、氟苯尼考和磺胺二甲基嘧啶吸附、迁移与滞留的影响.从猪粪中提取总DOM,并用XAD-8树脂柱将其进一步分离为亲水和疏水组分.批量平衡实验结果表明,加入猪粪总DOM会不同程度地降低土壤对恩诺沙星、氟苯尼考和磺胺二甲基嘧啶的吸附,但会大幅度提高对强力霉素的吸附;添加猪粪DOM的亲水组分会大幅减弱土壤对恩诺沙星和氟苯尼考的吸附,添加猪粪DOM的疏水组分则会大幅增强土壤对强力霉素的吸附,但会使对氟苯尼考的吸附明显减弱.饱和填装土柱实验结果表明,强力霉素和恩诺沙星未发生穿透;添加猪粪DOM 的亲水组分在降低磺胺二甲基嘧啶穿透率上起主要作用,在表层和亚表层土壤中的降幅分别为13.6%和5.4%;而猪粪DOM的亲水和疏水组分均在提高氟苯尼考穿透率上发挥作用(仅体现在表层土壤中,升幅分别为30.7%和20.1%).猪粪DOM的添加会提高磺胺二甲基嘧啶和氟苯尼考在土柱中的滞留(表层土壤中的增幅分别为14.9 %和7.8%,亚表层土壤中的增幅分别为3.1%和10.6%),而促进恩诺沙星和强力霉素向土壤更深处再分布.土壤水相DOM的腐殖化程度和芳香性及类腐殖质和类蛋白质组分的含量及占比可能对土壤中兽药的迁移产生重要影响.

, authors=晏浩1, 肖慧芸1, 陈卓1, 吕玉娟2, 唐翔宇1, *, 胡锦昇1, 3, 程建华1, authorsList=晏浩, 肖慧芸, 陈卓, 吕玉娟, 唐翔宇, 胡锦昇, 程建华, authorCompany=null, correspAuthors=唐翔宇, authorNote=

晏浩(2000-),男,江苏苏州人,浙江农林大学硕士研究生,主要从事土壤有机污染物迁移行为研究.发表论文1篇..

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* 责任作者,教授,
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晏浩(2000-),男,江苏苏州人,浙江农林大学硕士研究生,主要从事土壤有机污染物迁移行为研究.发表论文1篇..

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晏浩(2000-),男,江苏苏州人,浙江农林大学硕士研究生,主要从事土壤有机污染物迁移行为研究.发表论文1篇..

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粪源溶解性有机质对高有机质土壤中兽药吸附与迁移的影响
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晏浩 1 , 肖慧芸 1 , 陈卓 1 , 吕玉娟 2 , 唐翔宇 1, * , 胡锦昇 1, 3 , 程建华 1
中国环境科学 | 土壤污染与控制 2025,45(12): 6737-6748
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中国环境科学 |土壤污染与控制 2025 , 45 (12) : 6737 -6748
粪源溶解性有机质对高有机质土壤中兽药吸附与迁移的影响
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晏浩(2000-),男,江苏苏州人,浙江农林大学硕士研究生,主要从事土壤有机污染物迁移行为研究.发表论文1篇..

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晏浩(2000-),男,江苏苏州人,浙江农林大学硕士研究生,主要从事土壤有机污染物迁移行为研究.发表论文1篇..

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晏浩1 , 肖慧芸1, 陈卓1, 吕玉娟2, 唐翔宇1, * , 胡锦昇1, 3, 程建华1
作者信息
  • 1.浙江农林大学林业与生物技术学院,森林食物资源挖掘与利用全国重点实验室,浙江 杭州 311300
  • 2.生态环境部南京环境科学研究所,江苏 南京 210042
  • 3.中国科学院、水利部成都山地灾害与环境研究所,四川 成都 610299
通讯作者:
* 责任作者,教授,
作者简介:

晏浩(2000-),男,江苏苏州人,浙江农林大学硕士研究生,主要从事土壤有机污染物迁移行为研究.发表论文1篇..

Influences of fecal dissolved organic matter on the adsorption and transport of veterinary drugs in high organic matter soils
Hao YAN1 , Hui-yun XIAO1, Zhuo CHEN1, Yu-juan LV2, Xiang-yu TANG1, * , Jin-sheng HU1, 3, Jian-hua CHENG1
Affiliations
  • 1.State Key Laboratory for Development and Utilization of Forest Food Resources, College of Forestry and Biotechnology, Zhejiang A&F University, Hangzhou 311300, China
  • 2.Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, China
  • 3.Institute of Mountain Hazards and Environment, Chinese Academy of Sciences, Chengdu 610299, China
出版时间: 2025-12-20
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以坡脚旱地雷竹林表层和亚表层土壤为对象,研究猪粪DOM及其亲水和疏水组分对强力霉素、恩诺沙星、氟苯尼考和磺胺二甲基嘧啶吸附、迁移与滞留的影响.从猪粪中提取总DOM,并用XAD-8树脂柱将其进一步分离为亲水和疏水组分.批量平衡实验结果表明,加入猪粪总DOM会不同程度地降低土壤对恩诺沙星、氟苯尼考和磺胺二甲基嘧啶的吸附,但会大幅度提高对强力霉素的吸附;添加猪粪DOM的亲水组分会大幅减弱土壤对恩诺沙星和氟苯尼考的吸附,添加猪粪DOM的疏水组分则会大幅增强土壤对强力霉素的吸附,但会使对氟苯尼考的吸附明显减弱.饱和填装土柱实验结果表明,强力霉素和恩诺沙星未发生穿透;添加猪粪DOM 的亲水组分在降低磺胺二甲基嘧啶穿透率上起主要作用,在表层和亚表层土壤中的降幅分别为13.6%和5.4%;而猪粪DOM的亲水和疏水组分均在提高氟苯尼考穿透率上发挥作用(仅体现在表层土壤中,升幅分别为30.7%和20.1%).猪粪DOM的添加会提高磺胺二甲基嘧啶和氟苯尼考在土柱中的滞留(表层土壤中的增幅分别为14.9 %和7.8%,亚表层土壤中的增幅分别为3.1%和10.6%),而促进恩诺沙星和强力霉素向土壤更深处再分布.土壤水相DOM的腐殖化程度和芳香性及类腐殖质和类蛋白质组分的含量及占比可能对土壤中兽药的迁移产生重要影响.

粪源溶解性有机质  /  亲/疏水组分  /  兽药  /  吸附  /  迁移

Surface and subsurface soils collected from a bamboo forest at the footslope of an upland were used to explore the effects of pig manure dissolved organic (PM DOM) and its hydrophilic (HI) and hydrophobic (HO) fractions on the adsorption, transport, and retention of doxycycline, enrofloxacin, florfenicol, and sulfamethazine. Total DOM was extracted from pig manure and further separated into HI and HO fractions using XAD-8resin column. According to the results of batch equilibrium experiments, the addition of PM DOM led to varying decreases in the adsorption of enrofloxacin, florfenicol, and sulfamethazine but marked increases in the adsorption of doxycycline; the addition of PM DOM's HIS fraction substantially weakened the adsorption of enrofloxacin and florfenicol by the soils; the addition of PM DOM's HO fraction significantly enhanced the adsorption of doxycycline but markedly reduced the adsorption of florfenicol by the soils. According to the results of saturated transport experiments in repacked soil columns, doxycycline and enrofloxacin could make a breakthrough; the HI fraction of PM DOM played a predominant role in reducing the recovery rate of sulfamethazine in the surface and subsurface soils (by 13.6% and 5.4%, respectively), while both the HI and HO fractions of PM DOM increased the recovery rate of florfenicol (only evidenced in the surface soil; by 30.7% and 20.1%, respectively). The addition of PM DOM could enhance the retention of sulfamethazine and florfenicol (by 14.9% and 7.8%, respectively, in the surface soil columns; by 3.1% and 10.6%, respectively, in the subsurface soil columns) while promote the redistribution of enrofloxacin and doxycycline to deeper soil layers. The humification degree and aromaticity of DOM in the aqueous phase of the soils, as well as the content and proportion of humic-like and protein-like components of DOM, might exert a crucial influence on the transport of veterinary drugs in the soils.

fecal dissolved organic matter  /  hydrophilic/hydrophobic component  /  veterinary drugs  /  adsorption  /  transport
晏浩, 肖慧芸, 陈卓, 吕玉娟, 唐翔宇, 胡锦昇, 程建华. 粪源溶解性有机质对高有机质土壤中兽药吸附与迁移的影响. 中国环境科学, 2025 , 45 (12) : 6737 -6748 .
Hao YAN, Hui-yun XIAO, Zhuo CHEN, Yu-juan LV, Xiang-yu TANG, Jin-sheng HU, Jian-hua CHENG. Influences of fecal dissolved organic matter on the adsorption and transport of veterinary drugs in high organic matter soils[J]. China Environmental Science, 2025 , 45 (12) : 6737 -6748 .
  • 国家自然科学基金资助项目(42177379; 42377374)
  • 浙江省自然科学基金资助项目(LD21D010001)
  • 浙江农林大学科研发展基金资助项目(2020FR040)
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2025年第45卷第12期
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  • 接收时间:2025-05-13
  • 首发时间:2026-10-08
  • 出版时间:2025-12-20
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  • 收稿日期:2025-05-13
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国家自然科学基金资助项目(42177379; 42377374)
浙江省自然科学基金资助项目(LD21D010001)
浙江农林大学科研发展基金资助项目(2020FR040)
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    1.浙江农林大学林业与生物技术学院,森林食物资源挖掘与利用全国重点实验室,浙江 杭州 311300
    2.生态环境部南京环境科学研究所,江苏 南京 210042
    3.中国科学院、水利部成都山地灾害与环境研究所,四川 成都 610299

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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
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