Article(id=1314918517770646072, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918450573701162, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1747238400000, receivedDateStr=2025-05-15, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791430604640, onlineDateStr=2026-10-08, pubDate=1766160000000, pubDateStr=2025-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791430604640, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791430604640, creator=13701087609, updateTime=1791430604640, updator=13701087609, issue=Issue{id=1314918450573701162, tenantId=1146029695717560320, journalId=1234093305789726721, year='2025', volume='45', issue='12', pageStart='6513', pageEnd='7104', issueExtLink='null', onlineDate='null', pubDate='1766160000000', pubDateStr='2025-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791430588620, creator='13701087609', updateTime=1791431575400, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314922589479333965, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918450573701162, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314922589479333966, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918450573701162, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=6584, endPage=6594, ext={EN=ArticleExt(id=1314918517997138489, articleId=1314918517770646072, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=Mechanism of membrane fouling reduction in electric field assisted membrane separation treatment of oily wastewater, columnId=1234106386360103680, journalTitle=China Environmental Science, columnName=Water Pollution Control, runingTitle=null, highlight=null, articleAbstract=

An integrated electrochemical-coupled membrane reactor system was constructed, where a conductive ceramic membrane (CCM) cathode fabricated by spray pyrolysis-in situ precipitation and a Ti/RuO2-IrO2 anode were employed to investigate the mitigation mechanism of membrane fouling during electric field-assisted oil-containing wastewater treatment. It was demonstrated that a stable Sb-SnO2 conductive coating was successfully deposited on the CCM electrode surface through the spray pyrolysis-in-situ precipitation method, exhibiting an average roughness of approximately 324nm, which represented a 32% reduction compared to the pre-modified state. Under an electrochemical potential of -1.0V, the CCM electrode was characterized by an impedance value of 38 Ω·cm2 and a corrosion potential of -0.36V, indicating excellent electrode stability and corrosion resistance. In oily wastewater treatment experiments, when the applied electric field intensity was varied between 0.6~9.8V/cm, the flux decline rate of the CCM membrane was observed to progressively decrease with increasing electric field intensity. The flux decay rate was found to stabilize when the electric field intensity reached 4.2V/cm. After five cycles of hydraulic backwashing, the CCM membrane flux was measured to be 15%~17% higher for both 0.1g/L and 0.5g/L oily wastewater concentrations compared to non-electrified conditions, demonstrating extended membrane service life. Membrane fouling characterization revealed that the modified CCM exhibited enhanced hydrophilicity and surface electronegativity, which generated strong repulsive forces against oil droplets (Zeta potential: -35.2 to~16.7mV) during electric field-assisted separation. Analysis of the membrane fouling mechanism indicated that the electric field application significantly improved the irreversibility of membrane fouling, with the fouling process being transformed from a standard clogging model to a complete clogging model. These findings further confirmed the critical role of electric fields in mitigating membrane fouling progression.

, authors=Jia-wei TANG1, *, Qiang GUQ1, Zhao-feng LIU1, Xiao-duan LI1, Zu-yu YAN2, Suo ZHANG2, Jing-feng LI1, Chun-hui ZHANG3, Xu-wen HE3, authorsList=Jia-wei TANG, Qiang GUQ, Zhao-feng LIU, Xiao-duan LI, Zu-yu YAN, Suo ZHANG, Jing-feng LI, Chun-hui ZHANG, Xu-wen HE, authorCompany=null, correspAuthors=Jia-wei TANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314918518269768250, articleId=1314918517770646072, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=电场辅助膜分离处理含油废水过程中膜污染减缓机理, columnId=1234106386565624579, journalTitle=中国环境科学, columnName=水污染与控制, runingTitle=null, highlight=null, articleAbstract=

构建了导电陶瓷膜(CCM)为阴极、钛钌铱电极为阳极的一体化电化学耦合膜反应系统,开展了电场辅助膜分离处理含油废水实验及膜污染减缓机制研究.结果表明,以喷雾热解-原位沉淀法制备的CCM电极表面稳定附着了Sb-SnO2导电涂层,膜表面平均粗糙度约为324nm,比改性前降低了32%.在-1.0V电化学条件下,CCM电极阻抗值约38Ω·cm2,腐蚀电位为-0.36V,具备良好的电极稳定性和抗腐蚀性.在处理含油废水实验中,当施加电场强度为0.6~9.8V/cm时,CCM膜通量衰减幅度均表现出随电场强度增加膜通量衰减幅度逐步减缓的趋势.当电场强度达到4.2V/cm时,膜通量衰减速率逐步稳定,以水力反冲洗方式循环处理0.1g/L和0.5g/L的含油废水5次后,CCM膜通量较无电场条件可提高15%~17%,具备更长的膜应用周期.膜污染分析表征显示,CCM 电极相比改性前具备更好的亲水性和表面电负性,在电场辅助膜分离过程中,与油滴(Zeta电位为-35.2~-16.7mV)会发生明显的斥力作用.膜污染堵塞模型揭示电场作用显著改善了膜污染的不可逆情况,可将膜污染过程由标准堵塞模型转化为完全堵塞模型,进一步证实了电场作用对减缓膜污染的支撑作用.

, authors=唐佳伟1, *, 郭强1, 刘兆峰1, 李小端1, 闫祖喻2, 张锁2, 李井峰1, 张春晖3, 何绪文3, authorsList=唐佳伟, 郭强, 刘兆峰, 李小端, 闫祖喻, 张锁, 李井峰, 张春晖, 何绪文, authorCompany=null, correspAuthors=唐佳伟, authorNote=

唐佳伟(1992-),男,北京人,高级工程师,博士,主要从事工业废水处理方面的研究.发表论文30余篇..

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唐佳伟(1992-),男,北京人,高级工程师,博士,主要从事工业废水处理方面的研究.发表论文30余篇..

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唐佳伟(1992-),男,北京人,高级工程师,博士,主要从事工业废水处理方面的研究.发表论文30余篇..

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电场辅助膜分离处理含油废水过程中膜污染减缓机理
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唐佳伟 1, * , 郭强 1 , 刘兆峰 1 , 李小端 1 , 闫祖喻 2 , 张锁 2 , 李井峰 1 , 张春晖 3 , 何绪文 3
中国环境科学 | 水污染与控制 2025,45(12): 6584-6594
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中国环境科学 |水污染与控制 2025 , 45 (12) : 6584 -6594
电场辅助膜分离处理含油废水过程中膜污染减缓机理
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唐佳伟(1992-),男,北京人,高级工程师,博士,主要从事工业废水处理方面的研究.发表论文30余篇..

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唐佳伟(1992-),男,北京人,高级工程师,博士,主要从事工业废水处理方面的研究.发表论文30余篇..

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唐佳伟1, * , 郭强1, 刘兆峰1, 李小端1, 闫祖喻2, 张锁2, 李井峰1, 张春晖3, 何绪文3
作者信息
  • 1.北京低碳清洁能源研究院,煤炭开采水资源保护与利用全国重点实验室,北京 102211
  • 2.神华新街能源有限责任公司,内蒙古 鄂尔多斯 017200
  • 3.中国矿业大学(北京)化学与环境工程学院,北京 100083
通讯作者:
* 责任作者,高级工程师,
作者简介:

唐佳伟(1992-),男,北京人,高级工程师,博士,主要从事工业废水处理方面的研究.发表论文30余篇..

Mechanism of membrane fouling reduction in electric field assisted membrane separation treatment of oily wastewater
Jia-wei TANG1, * , Qiang GUQ1, Zhao-feng LIU1, Xiao-duan LI1, Zu-yu YAN2, Suo ZHANG2, Jing-feng LI1, Chun-hui ZHANG3, Xu-wen HE3
Affiliations
  • 1.National Institute of Low Carbon and Clean Energy, Beijing, State Key Laboratory of Water Resource Protection and Utilization in Coal Mining, Beijing 102211, China
  • 2.Shenhua Group Xinjie Energy Co., Ltd, Ordos 017200, China
  • 3.China University of Mining and Technology (Beijing), Beijing 100083, China
出版时间: 2025-12-20
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构建了导电陶瓷膜(CCM)为阴极、钛钌铱电极为阳极的一体化电化学耦合膜反应系统,开展了电场辅助膜分离处理含油废水实验及膜污染减缓机制研究.结果表明,以喷雾热解-原位沉淀法制备的CCM电极表面稳定附着了Sb-SnO2导电涂层,膜表面平均粗糙度约为324nm,比改性前降低了32%.在-1.0V电化学条件下,CCM电极阻抗值约38Ω·cm2,腐蚀电位为-0.36V,具备良好的电极稳定性和抗腐蚀性.在处理含油废水实验中,当施加电场强度为0.6~9.8V/cm时,CCM膜通量衰减幅度均表现出随电场强度增加膜通量衰减幅度逐步减缓的趋势.当电场强度达到4.2V/cm时,膜通量衰减速率逐步稳定,以水力反冲洗方式循环处理0.1g/L和0.5g/L的含油废水5次后,CCM膜通量较无电场条件可提高15%~17%,具备更长的膜应用周期.膜污染分析表征显示,CCM 电极相比改性前具备更好的亲水性和表面电负性,在电场辅助膜分离过程中,与油滴(Zeta电位为-35.2~-16.7mV)会发生明显的斥力作用.膜污染堵塞模型揭示电场作用显著改善了膜污染的不可逆情况,可将膜污染过程由标准堵塞模型转化为完全堵塞模型,进一步证实了电场作用对减缓膜污染的支撑作用.

导电陶瓷膜  /  含油废水  /  电化学  /  膜污染

An integrated electrochemical-coupled membrane reactor system was constructed, where a conductive ceramic membrane (CCM) cathode fabricated by spray pyrolysis-in situ precipitation and a Ti/RuO2-IrO2 anode were employed to investigate the mitigation mechanism of membrane fouling during electric field-assisted oil-containing wastewater treatment. It was demonstrated that a stable Sb-SnO2 conductive coating was successfully deposited on the CCM electrode surface through the spray pyrolysis-in-situ precipitation method, exhibiting an average roughness of approximately 324nm, which represented a 32% reduction compared to the pre-modified state. Under an electrochemical potential of -1.0V, the CCM electrode was characterized by an impedance value of 38 Ω·cm2 and a corrosion potential of -0.36V, indicating excellent electrode stability and corrosion resistance. In oily wastewater treatment experiments, when the applied electric field intensity was varied between 0.6~9.8V/cm, the flux decline rate of the CCM membrane was observed to progressively decrease with increasing electric field intensity. The flux decay rate was found to stabilize when the electric field intensity reached 4.2V/cm. After five cycles of hydraulic backwashing, the CCM membrane flux was measured to be 15%~17% higher for both 0.1g/L and 0.5g/L oily wastewater concentrations compared to non-electrified conditions, demonstrating extended membrane service life. Membrane fouling characterization revealed that the modified CCM exhibited enhanced hydrophilicity and surface electronegativity, which generated strong repulsive forces against oil droplets (Zeta potential: -35.2 to~16.7mV) during electric field-assisted separation. Analysis of the membrane fouling mechanism indicated that the electric field application significantly improved the irreversibility of membrane fouling, with the fouling process being transformed from a standard clogging model to a complete clogging model. These findings further confirmed the critical role of electric fields in mitigating membrane fouling progression.

conductive ceramic membrane  /  oily wastewater  /  electrochemistry  /  membrane fouling
唐佳伟, 郭强, 刘兆峰, 李小端, 闫祖喻, 张锁, 李井峰, 张春晖, 何绪文. 电场辅助膜分离处理含油废水过程中膜污染减缓机理. 中国环境科学, 2025 , 45 (12) : 6584 -6594 .
Jia-wei TANG, Qiang GUQ, Zhao-feng LIU, Xiao-duan LI, Zu-yu YAN, Suo ZHANG, Jing-feng LI, Chun-hui ZHANG, Xu-wen HE. Mechanism of membrane fouling reduction in electric field assisted membrane separation treatment of oily wastewater[J]. China Environmental Science, 2025 , 45 (12) : 6584 -6594 .
  • 国家能源集团科技项目(GJNY-21-129)
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2025年第45卷第12期
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  • 接收时间:2025-05-15
  • 首发时间:2026-10-08
  • 出版时间:2025-12-20
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  • 收稿日期:2025-05-15
基金
国家能源集团科技项目(GJNY-21-129)
作者信息
    1.北京低碳清洁能源研究院,煤炭开采水资源保护与利用全国重点实验室,北京 102211
    2.神华新街能源有限责任公司,内蒙古 鄂尔多斯 017200
    3.中国矿业大学(北京)化学与环境工程学院,北京 100083

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* 责任作者,高级工程师,
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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