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This paper revealed the spatial and temporal distribution and source characteristics of dissolved organic nitrogen (DON) in the watershed through the joint analysis of water quality indicators, three-dimensional fluorescence spectroscopy (3DEEM) and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). The results showed that the proportion of DON concentration to total dissolved nitrogen concentration in all counties of the watershed in all seasons ranged from 15% to 20%. The overall DON level was low, while the DON/TN ratios in the main stream sections of the two downstream counties were significantly higher than those in the upstream. 3DEEM showed that DOM was dominated by humus of terrestrial origin, and the activity of the protein-like fractions was enhanced in summer and autumn. The fluorescence index indicated that agricultural input dominated the exogenous pollution. FT-ICR MS detected that nitrogenous organic matter was dominated by lignin-like substances. The input of Yellow Water (YH) elevated the percentage of condensed aromatics downstream by 11.4%. The lower amount of nitrogenous organic matter in the water body in summer compared with autumn at Gaojiaxie Village (G9) revealed the influence of land-source humus input. The transformation of dissolved organic nitrogen in the Fen River basin was synergistically driven by exogenous inputs, biodegradation and photolysis, which formed the characteristics of DON sources under the action of multiple mechanisms. The study suggested that priority should be given to the control of tributary inputs of difficult-to-degrade organics to enhance the effectiveness of management.

, authors=Hui SUN1, 2, Feng ZHANG1, 3, *, Xiao-yu YANG1, Yan WANG1, Chao-xu WANG1, 3, Hong-yan LI1, Xiao-bo CUI2, Li-bo MAO4, authorsList=Hui SUN, Feng ZHANG, Xiao-yu YANG, Yan WANG, Chao-xu WANG, Hong-yan LI, Xiao-bo CUI, Li-bo MAO, authorCompany=null, correspAuthors=Feng ZHANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314918466860179808, articleId=1314918465484448094, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=水体中含氮有机物的分布特征及来源解析——以汾河水库上游流域为例, columnId=1234106388268503686, journalTitle=中国环境科学, columnName=环境生态, runingTitle=null, highlight=null, articleAbstract=

通过水质指标、三维荧光光谱(3DEEM)与傅里叶变换离子回旋共振质谱(FT-ICR MS)联合分析,揭示了流域内溶解性有机氮(DON)的时空分布及来源特征.结果表明:流域各县四季DON浓度占总溶解态氮浓度的比例在15%~20%之间,整体DON水平较低,而下游两县干流断面的DON/TN比值明显高于上游.3DEEM显示溶解性有机物(DOM)以陆源腐殖质为主,夏秋季类蛋白组分活性增强,荧光指数表明农业输入主导外源污染.FT-ICR MS检测到含氮有机物以木质素类为主,引黄水(YH)输入使下游稠合芳香物占比提升 11.4%,高家舍村(G9)相比秋季,夏季水体含氮有机物数量较低,揭示了陆源腐殖质输入的影响.汾河流域溶解性有机氮的转化受外源输入、生物降解与光解协同驱动,形成多机制作用下的DON来源特征,研究建议优先管控支流难降解有机物输入以提升治理效能.

, authors=孙晖1, 2, 张峰1, 3, *, 杨晓宇1, 王岩1, 王朝旭1, 3, 李红艳1, 崔晓波2, 毛立波4, authorsList=孙晖, 张峰, 杨晓宇, 王岩, 王朝旭, 李红艳, 崔晓波, 毛立波, authorCompany=null, correspAuthors=张峰, authorNote=

孙晖(1993-),男,山西太原人,太原理工大学硕士研究生,主要从事饮用水风险监测.发表论文3篇..

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* 责任作者,副教授,
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孙晖(1993-),男,山西太原人,太原理工大学硕士研究生,主要从事饮用水风险监测.发表论文3篇..

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孙晖(1993-),男,山西太原人,太原理工大学硕士研究生,主要从事饮用水风险监测.发表论文3篇..

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水体中含氮有机物的分布特征及来源解析——以汾河水库上游流域为例
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孙晖 1, 2 , 张峰 1, 3, * , 杨晓宇 1 , 王岩 1 , 王朝旭 1, 3 , 李红艳 1 , 崔晓波 2 , 毛立波 4
中国环境科学 | 环境生态 2025,45(12): 6805-6816
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中国环境科学 |环境生态 2025 , 45 (12) : 6805 -6816
水体中含氮有机物的分布特征及来源解析——以汾河水库上游流域为例
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2.太原供水集团有限公司,山西 太原 030001, bio={"content":"

孙晖(1993-),男,山西太原人,太原理工大学硕士研究生,主要从事饮用水风险监测.发表论文3篇..

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孙晖(1993-),男,山西太原人,太原理工大学硕士研究生,主要从事饮用水风险监测.发表论文3篇..

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孙晖1, 2 , 张峰1, 3, * , 杨晓宇1, 王岩1, 王朝旭1, 3, 李红艳1, 崔晓波2, 毛立波4
作者信息
  • 1.太原理工大学环境与生态学院,山西 晋中 030600
  • 2.太原供水集团有限公司,山西 太原 030001
  • 3.山西省污水高效治理技术创新中心,山西 太原 030000
  • 4.山西大地环境投资控股有限公司,山西 太原 030032
通讯作者:
* 责任作者,副教授,
作者简介:

孙晖(1993-),男,山西太原人,太原理工大学硕士研究生,主要从事饮用水风险监测.发表论文3篇..

Distribution characteristics and source apportionment of nitrogen-containing organic compounds in water bodies: A case study of the upper reaches of the Fenhe Reservoir basin
Hui SUN1, 2 , Feng ZHANG1, 3, * , Xiao-yu YANG1, Yan WANG1, Chao-xu WANG1, 3, Hong-yan LI1, Xiao-bo CUI2, Li-bo MAO4
Affiliations
  • 1.College of Environmental Science and Engineering, Taiyuan University of Technology, Jinzhong 030600, China
  • 2.Taiyuan Water Supply Group Limited Company, Taiyuan 030001, China
  • 3.Innovation Center for Advanced Wastewater Treatment Technologies, Taiyuan 030000, China
  • 4.Shanxi Dadi Environment Investment Holdings Limited Company, Taiyuan 030032, China
出版时间: 2025-12-20
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通过水质指标、三维荧光光谱(3DEEM)与傅里叶变换离子回旋共振质谱(FT-ICR MS)联合分析,揭示了流域内溶解性有机氮(DON)的时空分布及来源特征.结果表明:流域各县四季DON浓度占总溶解态氮浓度的比例在15%~20%之间,整体DON水平较低,而下游两县干流断面的DON/TN比值明显高于上游.3DEEM显示溶解性有机物(DOM)以陆源腐殖质为主,夏秋季类蛋白组分活性增强,荧光指数表明农业输入主导外源污染.FT-ICR MS检测到含氮有机物以木质素类为主,引黄水(YH)输入使下游稠合芳香物占比提升 11.4%,高家舍村(G9)相比秋季,夏季水体含氮有机物数量较低,揭示了陆源腐殖质输入的影响.汾河流域溶解性有机氮的转化受外源输入、生物降解与光解协同驱动,形成多机制作用下的DON来源特征,研究建议优先管控支流难降解有机物输入以提升治理效能.

溶解态有机氮  /  汾河水库上游流域  /  光学性质  /  分子特征  /  FT-ICR MS

This paper revealed the spatial and temporal distribution and source characteristics of dissolved organic nitrogen (DON) in the watershed through the joint analysis of water quality indicators, three-dimensional fluorescence spectroscopy (3DEEM) and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). The results showed that the proportion of DON concentration to total dissolved nitrogen concentration in all counties of the watershed in all seasons ranged from 15% to 20%. The overall DON level was low, while the DON/TN ratios in the main stream sections of the two downstream counties were significantly higher than those in the upstream. 3DEEM showed that DOM was dominated by humus of terrestrial origin, and the activity of the protein-like fractions was enhanced in summer and autumn. The fluorescence index indicated that agricultural input dominated the exogenous pollution. FT-ICR MS detected that nitrogenous organic matter was dominated by lignin-like substances. The input of Yellow Water (YH) elevated the percentage of condensed aromatics downstream by 11.4%. The lower amount of nitrogenous organic matter in the water body in summer compared with autumn at Gaojiaxie Village (G9) revealed the influence of land-source humus input. The transformation of dissolved organic nitrogen in the Fen River basin was synergistically driven by exogenous inputs, biodegradation and photolysis, which formed the characteristics of DON sources under the action of multiple mechanisms. The study suggested that priority should be given to the control of tributary inputs of difficult-to-degrade organics to enhance the effectiveness of management.

dissolved organic nitrogen  /  upper Fenhe Reservoir watershed  /  optical properties  /  molecular characterization  /  FT-ICR MS
孙晖, 张峰, 杨晓宇, 王岩, 王朝旭, 李红艳, 崔晓波, 毛立波. 水体中含氮有机物的分布特征及来源解析——以汾河水库上游流域为例. 中国环境科学, 2025 , 45 (12) : 6805 -6816 .
Hui SUN, Feng ZHANG, Xiao-yu YANG, Yan WANG, Chao-xu WANG, Hong-yan LI, Xiao-bo CUI, Li-bo MAO. Distribution characteristics and source apportionment of nitrogen-containing organic compounds in water bodies: A case study of the upper reaches of the Fenhe Reservoir basin[J]. China Environmental Science, 2025 , 45 (12) : 6805 -6816 .
  • 山西省研究生教育创新项目(2023KY256)
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  • 接收时间:2025-05-19
  • 首发时间:2026-10-08
  • 出版时间:2025-12-20
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  • 收稿日期:2025-05-19
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山西省研究生教育创新项目(2023KY256)
作者信息
    1.太原理工大学环境与生态学院,山西 晋中 030600
    2.太原供水集团有限公司,山西 太原 030001
    3.山西省污水高效治理技术创新中心,山西 太原 030000
    4.山西大地环境投资控股有限公司,山西 太原 030032

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* 责任作者,副教授,
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2种不同金属材料的力学参数
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属数
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种数
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属
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Number of
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Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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