Article(id=1314918373180400189, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918356222829028, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1744646400000, receivedDateStr=2025-04-15, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791430570168, onlineDateStr=2026-10-08, pubDate=1763568000000, pubDateStr=2025-11-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791430570168, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791430570168, creator=13701087609, updateTime=1791430570168, updator=13701087609, issue=Issue{id=1314918356222829028, tenantId=1146029695717560320, journalId=1234093305789726721, year='2025', volume='45', issue='11', pageStart='5921', pageEnd='6512', issueExtLink='null', onlineDate='null', pubDate='1763568000000', pubDateStr='2025-11-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791430566125, creator='13701087609', updateTime=1791431596967, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314922679942078535, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918356222829028, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314922679942078536, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918356222829028, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=6101, endPage=6111, ext={EN=ArticleExt(id=1314918373352366654, articleId=1314918373180400189, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=Mechanism of enhanced lead(Ⅱ) adsorption by silane coupling agent-modified ferrihydrite, columnId=1234106386360103680, journalTitle=China Environmental Science, columnName=Water Pollution Control, runingTitle=null, highlight=null, articleAbstract=
3-aminopropyltriethoxysilane (KH550) was used to modify Fh, yielding organosilane-modified ferrihydrite (KH-Fh). The Pb(Ⅱ) adsorption performance and underlying mechanisms of KH-Fh were systematically explored.Results demonstrate that the modification successfully introduced Si-OH and -NH2 functional groups onto the Fh surface, enhancing the maximum adsorption capacity from 50.51mg/g of the unmodified Fh to 102.85mg/g of KH-Fh, representing a 103.6% increase. Adsorption kinetics and isotherm studies indicate that the adsorption processes of both Fh and KH-Fh for Pb(Ⅱ) conform to the pseudo-second-order kinetic model and the Langmuir isotherm model, suggesting that chemisorption is the dominant mechanism. The positive value of the thermodynamic parameter ΔH indicates that elevated temperatures promote the adsorption reaction. Compared with unmodified Fh, KH-Fh maintains higher and more stable adsorption efficiency across a wide pH range (3.0~7.0) and is less affected by ionic strength and common coexisting ions (Na+, K+, Ca2+). X-ray photoelectron spectroscopy (XPS) analysis confirms that Pb(Ⅱ) is immobilized through coordination with Si-OH, Fe-OH, and -NH2 functional groups on the surface of KH-Fh, significantly enhancing the adsorption stability. These results offer novel theoretical insights and practical guidance for the functional modification of iron oxides and the remediation of Pb(Ⅱ)-contaminated environments.
, authors=Lin CAI
1, Cheng-feng JIANG
2, Xin-yu YAN
1, Shuang-lian XIONG
1, Shu-xin TU
1, *, authorsList=Lin CAI, Cheng-feng JIANG, Xin-yu YAN, Shuang-lian XIONG, Shu-xin TU, authorCompany=null, correspAuthors=Shu-xin TU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314918373562081855, articleId=1314918373180400189, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=硅烷偶联剂改性水铁矿对Pb(Ⅱ)的吸附增效机制, columnId=1234106386565624579, journalTitle=中国环境科学, columnName=水污染与控制, runingTitle=null, highlight=null, articleAbstract=
以3-氨基丙基三乙氧基硅烷(KH550)改性水铁矿,制备有机硅烷改性水铁矿(KH-Fh),并系统探究其对Pb(Ⅱ)的吸附性能与机制.结果表明,改性后Si-OH和-NH2官能团成功引入,使材料最大吸附容量从50.51mg/g跃升至102.85mg/g,增幅达103.6%.吸附动力学与等温线研究显示,Fh和KH-Fh对Pb(Ⅱ)的吸附符合伪二级动力学和Langmuir模型,以化学吸附为主;热力学参数ΔH>0,表明升温促进反应.相较于原矿,KH-Fh在pH值3.0~7.0范围吸附效率更高且稳定,受离子强度与常见共存离子影响小.XPS分析证实,Pb(Ⅱ)通过与Si-OH、Fe-OH及-NH2配位实现固定.研究结果为铁氧化物功能化改性及铅污染修复提供了新的理论见解和实践指导.
, authors=蔡琳
1, 江承风
2, 严心雨
1, 熊双莲
1, 涂书新
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蔡琳(2001-),女,江苏南通人,华中农业大学硕士研究生,主要从事重金属污染修复研究.发表论文2篇.13485173729@163.com.
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蔡琳(2001-),女,江苏南通人,华中农业大学硕士研究生,主要从事重金属污染修复研究.发表论文2篇.13485173729@163.com.
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