Article(id=1314918356680008164, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918356222829028, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1741881600000, receivedDateStr=2025-03-14, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791430566233, onlineDateStr=2026-10-08, pubDate=1763568000000, pubDateStr=2025-11-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791430566233, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791430566233, creator=13701087609, updateTime=1791430566233, updator=13701087609, issue=Issue{id=1314918356222829028, tenantId=1146029695717560320, journalId=1234093305789726721, year='2025', volume='45', issue='11', pageStart='5921', pageEnd='6512', issueExtLink='null', onlineDate='null', pubDate='1763568000000', pubDateStr='2025-11-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791430566125, creator='13701087609', updateTime=1791431596967, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314922679942078535, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918356222829028, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314922679942078536, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918356222829028, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=6079, endPage=6090, ext={EN=ArticleExt(id=1314918358357729765, articleId=1314918356680008164, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=The preparation of semi-coke activated carbon supported CuCo-MOF-74 and degradation of BPA in water via peroxymonosulfate activation, columnId=1234106386360103680, journalTitle=China Environmental Science, columnName=Water Pollution Control, runingTitle=null, highlight=null, articleAbstract=
In this study, a catalyst with bimetallic CuCo-MOF-74 dispersed on semi-coke (SC) (CuCo-MOF-74x/SC) was successfully prepared by one-pot hydrothermal synthesis, and the degradation behavior and mechanism for aqueous bisphenol A (BPA) via persulfate (PMS) activation was systemically studied. The characterization results showed that CuCo-MOF-74 was uniformly dispersed onto the surface of semi-coke activated carbon, and the specific surface area of CuCo-MOF-742/SC was 582.04m2/g. For BPA degradation, under the optimum conditions (0.2g/L PMS, 0.1g/L catalyst), the CuCo-MOF-742/SC/PMS system achieved a degradation efficiency of 95.01% for 20mg/L BPA in 30min and the mineralization rate of 54.7%, which was significantly higher than that of the CuCo-MOF-74/PMS system, and the reaction rate constant of CuCo-MOF-742/SC (0.1113min-1) was 3.4 times of CuCo-MOF-74 (0.0324min-1). After 5 cycles, the degradation efficiency of CuCo-MOF-742/SC decreased from 94.83% to 72.56%, which was remarkably higher than that of CuCo-MOF-74 (from 76.95% to 21.49%). In the CuCo-MOF-742/SC/PMS system, both free radicals (·OH,
and
) and non-radicals (1O2 and electron transfer) were involved in the degradation of BPA, and free radicals oxidation played a major role. The loading of CuCo-MOF-74 on SC significantly enhances the stability and improves specific surface area of CuCo-MOF-74, thereby elevating the degradation efficiency for BPA in water. This study provides the important guiding significance for the development of MOF-based catalysts.
, authors=Tian-jiao LU, Jia-hong WANG
*, authorsList=Tian-jiao LU, Jia-hong WANG, authorCompany=null, correspAuthors=Jia-hong WANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314918360136114670, articleId=1314918356680008164, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=半焦活性炭负载CuCo-MOF-74的制备及其活化过硫酸盐降解水中双酚A的研究, columnId=1234106386565624579, journalTitle=中国环境科学, columnName=水污染与控制, runingTitle=null, highlight=null, articleAbstract=
采用一锅水热合成法,成功制备了半焦活性炭(SC)负载CuCo-MOF-74的双金属催化剂(CuCo-MOF-74x/SC),研究了其活化过一硫酸盐(PMS)氧化降解水中双酚A(BPA)的行为和机制.表征结果表明,CuCo-MOF-74成功均匀负载到半焦活性炭表面,比表面积为582.04m2/g.BPA降解实验表明,在最佳条件下(0.2g/L PMS、0.1g/L 催化剂),CuCo-MOF-742/SC/PMS在30min内对20mg/L BPA的降解效率达到95.01%,矿化率为54.7%,显著优于CuCo-MOF-74/PMS体系,且CuCo-MOF-742/SC(0.1113min-1)的反应速率常数是CuCo-MOF-74(0.0324min-1)的3.4倍.5次循环后,CuCo-MOF-742/SC的降解效率由94.83%降至72.56%,显著高于CuCo-MOF-74(由76.95%降至21.49%).在CuCo-MOF-742/SC/PMS系统中,自由基(·OH、
和
)和非自由基(1O2和电子转移)都参与了BPA的降解,其中自由基起主要作用.将CuCo-MOF-74负载到半焦活性碳上,有效提高了CuCo-MOF-74的稳定性和比表面积,强化了其对水中BPA的降解效果,该研究对MOF基催化剂的开发具有重要指导意义.
, authors=芦天姣, 王家宏
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芦天姣(2000-),山西运城人,陕西科技大学硕士研究生,主要研究方向为水处理高级氧化.发表论文1篇.1017630474@qq.com.
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芦天姣(2000-),山西运城人,陕西科技大学硕士研究生,主要研究方向为水处理高级氧化.发表论文1篇.1017630474@qq.com.
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