Article(id=1314918298207215712, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918247384834796, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1740585600000, receivedDateStr=2025-02-27, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791430552292, onlineDateStr=2026-10-08, pubDate=1760889600000, pubDateStr=2025-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791430552292, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791430552292, creator=13701087609, updateTime=1791430552292, updator=13701087609, issue=Issue{id=1314918247384834796, tenantId=1146029695717560320, journalId=1234093305789726721, year='2025', volume='45', issue='10', pageStart='5329', pageEnd='5920', issueExtLink='null', onlineDate='null', pubDate='1760889600000', pubDateStr='2025-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791430540175, creator='13701087609', updateTime=1791431660009, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314922944367784036, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918247384834796, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314922944367784037, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1314918247384834796, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=5570, endPage=5584, ext={EN=ArticleExt(id=1314918299868160097, articleId=1314918298207215712, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=Research progress on selective leaching of lithium from spent lithium iron phosphate batteries, columnId=1240689598498656298, journalTitle=China Environmental Science, columnName=Solid Waste, runingTitle=null, highlight=null, articleAbstract=

With the rapid development of the renewable energy industry, the usage of lithium iron phosphate batteries has soared. Therefore, the recycling of spent batteries has become a social focus. The selective leaching method can effectively extract lithium, reduce impurities, and improve recycling efficiency. This paper systematically reviews various selective lithium leaching techniques, including chemical oxidation, acid-assisted leaching, electrochemistry, high-temperature roasting, mechanochemistry, and so on, which further compares their respective advantages and disadvantages from the aspects of technical economy and environmental benefits. The results indicate that the chemical oxidation method has advantages in cost control and operational flexibility, while the electrochemical method is more and environmentally friendly and green. For the selective recycling of spent lithium iron phosphate batteries, more efficient, environmentally friendly, and economical recycling solutions should be developed in the future. This will provide new ideas for exploring selective recycling strategies for lithium iron phosphate batteries, which can promote comprehensive and coordinated development of the economy, environment, and technology, and thereby build a virtuous cycle system of new quality productivity.

, authors=Ya-nan LI, Jia-jun AN, Lei WANG*, Xu-dong WANG, authorsList=Ya-nan LI, Jia-jun AN, Lei WANG, Xu-dong WANG, authorCompany=null, correspAuthors=Lei WANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314918300182732898, articleId=1314918298207215712, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=废旧磷酸铁锂电池中锂的选择性浸出研究进展, columnId=1240689598737731645, journalTitle=中国环境科学, columnName=固体废物, runingTitle=null, highlight=null, articleAbstract=

本文系统介绍了化学氧化法、酸辅助浸出法、电化学法、高温焙烧法和机械化学法等多种锂的选择性浸出方法,比较了各自的优势与不足,并从技术经济和环境效益两方面分析.结果显示,化学氧化法在成本控制和操作灵活性方面具有优势,而电化学法则更具绿色环保特性.针对废旧磷酸铁锂的选择性回收,未来应开发出更高效、环保和经济的回收处理方案.这将为探索磷酸铁锂电池的选择性回收策略提供新的思路,促进经济、环境和技术的全面协同发展,进而构建新质生产力的良性循环体系.

, authors=李亚楠, 安家君, 王磊*, 王旭东, authorsList=李亚楠, 安家君, 王磊, 王旭东, authorCompany=null, correspAuthors=王磊, authorNote=

李亚楠(2000-),女,山西大同人,西安建筑科技大学硕士研究生,主要从事废旧电池有价金属的回收与利用研究.发表论文1篇..

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李亚楠(2000-),女,山西大同人,西安建筑科技大学硕士研究生,主要从事废旧电池有价金属的回收与利用研究.发表论文1篇..

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李亚楠(2000-),女,山西大同人,西安建筑科技大学硕士研究生,主要从事废旧电池有价金属的回收与利用研究.发表论文1篇..

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废旧磷酸铁锂电池中锂的选择性浸出研究进展
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李亚楠 , 安家君 , 王磊 * , 王旭东
中国环境科学 | 固体废物 2025,45(10): 5570-5584
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中国环境科学 |固体废物 2025 , 45 (10) : 5570 -5584
废旧磷酸铁锂电池中锂的选择性浸出研究进展
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李亚楠(2000-),女,山西大同人,西安建筑科技大学硕士研究生,主要从事废旧电池有价金属的回收与利用研究.发表论文1篇..

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李亚楠(2000-),女,山西大同人,西安建筑科技大学硕士研究生,主要从事废旧电池有价金属的回收与利用研究.发表论文1篇..

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李亚楠 , 安家君, 王磊* , 王旭东
作者信息
  • 西安建筑科技大学环境与市政工程学院,陕西省膜分离技术研究院,陕西省膜分离重点实验室,陕西省环境工程重点实验室,陕西 西安 710055
通讯作者:
* 责任作者,教授,
作者简介:

李亚楠(2000-),女,山西大同人,西安建筑科技大学硕士研究生,主要从事废旧电池有价金属的回收与利用研究.发表论文1篇..

Research progress on selective leaching of lithium from spent lithium iron phosphate batteries
Ya-nan LI , Jia-jun AN, Lei WANG* , Xu-dong WANG
Affiliations
  • Shaanxi Key Laboratory of Environmental Engineering, Key Laboratory of Membrane Separation of Shaanxi Province, Research Institute of Membrane Separation Technology of Shaanxi Province, School of Environmental &Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
出版时间: 2025-10-20
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本文系统介绍了化学氧化法、酸辅助浸出法、电化学法、高温焙烧法和机械化学法等多种锂的选择性浸出方法,比较了各自的优势与不足,并从技术经济和环境效益两方面分析.结果显示,化学氧化法在成本控制和操作灵活性方面具有优势,而电化学法则更具绿色环保特性.针对废旧磷酸铁锂的选择性回收,未来应开发出更高效、环保和经济的回收处理方案.这将为探索磷酸铁锂电池的选择性回收策略提供新的思路,促进经济、环境和技术的全面协同发展,进而构建新质生产力的良性循环体系.

废旧磷酸铁锂  /  选择性浸出  /  化学氧化法  /  酸辅助浸出法  /  电化学法

With the rapid development of the renewable energy industry, the usage of lithium iron phosphate batteries has soared. Therefore, the recycling of spent batteries has become a social focus. The selective leaching method can effectively extract lithium, reduce impurities, and improve recycling efficiency. This paper systematically reviews various selective lithium leaching techniques, including chemical oxidation, acid-assisted leaching, electrochemistry, high-temperature roasting, mechanochemistry, and so on, which further compares their respective advantages and disadvantages from the aspects of technical economy and environmental benefits. The results indicate that the chemical oxidation method has advantages in cost control and operational flexibility, while the electrochemical method is more and environmentally friendly and green. For the selective recycling of spent lithium iron phosphate batteries, more efficient, environmentally friendly, and economical recycling solutions should be developed in the future. This will provide new ideas for exploring selective recycling strategies for lithium iron phosphate batteries, which can promote comprehensive and coordinated development of the economy, environment, and technology, and thereby build a virtuous cycle system of new quality productivity.

spent lithium iron phosphate  /  selective leaching  /  chemical oxidation method  /  auxiliary acid leaching method  /  electrochemical method
李亚楠, 安家君, 王磊, 王旭东. 废旧磷酸铁锂电池中锂的选择性浸出研究进展. 中国环境科学, 2025 , 45 (10) : 5570 -5584 .
Ya-nan LI, Jia-jun AN, Lei WANG, Xu-dong WANG. Research progress on selective leaching of lithium from spent lithium iron phosphate batteries[J]. China Environmental Science, 2025 , 45 (10) : 5570 -5584 .
  • 国家重点研发计划项目(2022YFC2904300)
  • 陕西省重点科技创新团队计划项目(2024RS-CXTD-51)
  • 陕西省重点研发计划三项改革综合试点项目(2023GXLH-060)
  • 陕西省秦创原“科学家+工程师”队伍建设项目(2022KXJ-172)
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  • 接收时间:2025-02-27
  • 首发时间:2026-10-08
  • 出版时间:2025-10-20
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  • 收稿日期:2025-02-27
基金
国家重点研发计划项目(2022YFC2904300)
陕西省重点科技创新团队计划项目(2024RS-CXTD-51)
陕西省重点研发计划三项改革综合试点项目(2023GXLH-060)
陕西省秦创原“科学家+工程师”队伍建设项目(2022KXJ-172)
作者信息
    西安建筑科技大学环境与市政工程学院,陕西省膜分离技术研究院,陕西省膜分离重点实验室,陕西省环境工程重点实验室,陕西 西安 710055

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2种不同金属材料的力学参数
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小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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