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Multi-metal catalysts Mn-Cu-Co-Ce/TiO2, Mn-Ce-Co/TiO2, and Mn-Ce-Cu/TiO2 were synthesized via the impregnation method. Among them, Mn-Cu-Co-Ce/TiO2 was characterized before and after the reaction using BET, XPS, O2-TPD, FT-IR, SEM-EDS, and XRD techniques. The catalytic performance of the catalysts for isopropanol degradation in a non-thermal plasma (NTP) synergistic system was investigated. The effects of initial concentration, gas flow rate, oxygen content, and catalyst water content on degradation efficiency were systematically analyzed. Organic byproducts generated during the degradation process were detected using gas chromatography-mass spectrometry (GC-MS), and the degradation mechanism under NTP conditions was explored. The results indicated that the NTP-assisted multi-metal catalyst system exhibited over 54% improvement in degradation efficiency compared to NTP alone, achieving a removal rate of 90.22%. CO2 selectivity also increased by approximately 34%, reaching 63.97%. In the synergistic system, degradation efficiency was negatively correlated with initial concentration, gas flow rate, and catalyst water content, while it was positively correlated with voltage. Moreover, the formation of byproducts such as O3was effectively suppressed. The degradation path of isopropyl alcohol may involve multiple aspects, including direct oxidation mineralization under the guidance of NTP, intermediate oxidation process, and deep redox reactions.
, authors=Bei-jia XIE, Ji-wu LI
*, Xiu-juan TANG
**, authorsList=Bei-jia XIE, Ji-wu LI, Xiu-juan TANG, authorCompany=null, correspAuthors=Ji-wu LI, Xiu-juan TANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314917716075574021, articleId=1314917713881953026, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=低温等离子体场中多元金属催化剂降解异丙醇的特性与机理, columnId=1234106386565624579, journalTitle=中国环境科学, columnName=水污染与控制, runingTitle=null, highlight=null, articleAbstract=
采用浸渍法制备Mn-Cu-Co-Ce/TiO2、Mn-Ce-Co/TiO2和Mn-Ce-Cu/TiO2为多元金属催化剂,通过BET、XPS、O2-TPD、FT-IR、SEM-EDS和XRD对反应前后的Mn-Cu-Co-Ce/TiO2进行表征,研究其在低温放电等离子体(NTP)场中催化剂体对异丙醇的催化降解性能,并分析初始浓度、气量、氧气含量及催化剂含水量等条件对降解效率的影响.应用气相色谱-质谱(GC-MS)对降解过程中产生的有机副产物进行检测,探讨NTP场中协同催化降解机理.结果表明,NTP协同多元催化剂的降解效率相较于单独NTP降解,提高54%以上,达90.22,CO2选择性也提高约34%,达63.97%.在协同催化反应中,降解效率与初始浓度、气量和催化剂含水量呈负相关,与电压呈正相关,同时可以有效地抑制O3等副产物的产生.NTP协同催化氧化异丙醇的降解路径可能涵盖多个机制:如单独NTP条件下的少量矿化、中间氧化阶段以及深度氧化还原过程.
, authors=谢贝嘉, 李济吾
*, 唐秀娟
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谢贝嘉(1997-),男,浙江台州人,浙江工商大学硕士研究生,主要从事大气复合污染控制研究.发表论文1篇.510136964@qq.com.
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谢贝嘉(1997-),男,浙江台州人,浙江工商大学硕士研究生,主要从事大气复合污染控制研究.发表论文1篇.510136964@qq.com.
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