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A fully symmetric "dual-anion membrane" flow-electrode capacitive deionization (SFCDI) device was developed for treating wastewater containing hexavalent chromium (Cr(Ⅵ)). By employing dual anion-exchange membranes and operating in a short-circuit discharge mode, efficient Cr(Ⅵ) removal can be achieved without the need for high concentration background ions. Results showed that, a key feature of this configuration is its ability to prevent Cr3+ back-diffusion and total chromium concentration rebound, which are common issues in traditional FCDI systems using cation-exchange membranes. Under conditions of 1.2V applied voltage and an initial pH of 5.0, the SFCDI reduced the Cr(Ⅵ) concentration from 50mg/L to 0.41mg/L within 150minutes, achieving a total chromium removal efficiency of 97.55% with an energy consumption of only 0.12kWh/m3. Compared to traditional FCDI, SFCDI significantly improved the total chromium removal efficiency while effectively preventing Cr3+ backflow. Further research systematically analyzed the effects of voltage, activated carbon content, pH, and coexisting anions on performance and demonstrated the applicability and stability of SFCDI in continuous operation and actual electroplating wastewater treatment. Within 180minutes, the removal rate of Cr(Ⅵ) in actual electroplating wastewater reached 97.68%, showcasing its potential as a green, efficient, and low-energy solution.

, authors=Han-long LIU1, 2, Chun-peng ZHANG1, 2, *, Si-yao ZHANG1, 2, Yang ZHANG1, 2, Xue-zhi REN1, 2, Ya-lin DU1, 2, Shuang ZHANG1, 2, Yu-fan MA1, Yu-yang WANG1, 2, authorsList=Han-long LIU, Chun-peng ZHANG, Si-yao ZHANG, Yang ZHANG, Xue-zhi REN, Ya-lin DU, Shuang ZHANG, Yu-fan MA, Yu-yang WANG, authorCompany=null, correspAuthors=Chun-peng ZHANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314917504821059772, articleId=1314917504116416698, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=双阴膜流动电极电容去离子净化含铬废水, columnId=1234106386565624579, journalTitle=中国环境科学, columnName=水污染与控制, runingTitle=null, highlight=null, articleAbstract=

开发了一种完全对称的“双阴膜”流动电极电容去离子(SFCDI)装置处理含六价铬Cr(Ⅵ)废水,采用双阴离子交换膜和短路闭合模式,无需高浓度背景离子,即可实现高效Cr(Ⅵ)去除.结果表明,这一构型的显著特点是避免了传统FCDI中因使用阳离子交换膜而导致的Cr3+回渗与总Cr浓度反弹问题.在1.2V电压、初始pH 5.0条件下,SFCDI在150min内将Cr(Ⅵ)浓度从50mg/L降低至0.41mg/L,总Cr去除效率达97.55%,能耗仅为0.12kWh/m3.与传统FCDI相比,SFCDI显著提高了总Cr去除效率并有效阻止Cr3+回流.进一步研究分析了电压、活性炭含量、pH值及共存阴离子对处理性能的影响,并验证了SFCDI在连续运行及实际电镀废水处理中的适用性和稳定性.在180min内,对实际电镀废水的Cr(Ⅵ)去除率达97.68%,展现出绿色、高效、低能耗的应用潜力.

, authors=刘翰隆1, 2, 张春鹏1, 2, *, 张思瑶1, 2, 张洋1, 2, 任学志1, 2, 杜雅琳1, 2, 张爽1, 2, 马语璠1, 王彧洋1, 2, authorsList=刘翰隆, 张春鹏, 张思瑶, 张洋, 任学志, 杜雅琳, 张爽, 马语璠, 王彧洋, authorCompany=null, correspAuthors=张春鹏, authorNote=

刘翰隆(2003-),男,湖北鄂州人,吉林大学硕士研究生,主要从事电化学对水中污染物去除的研究..

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双阴膜流动电极电容去离子净化含铬废水
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刘翰隆 1, 2 , 张春鹏 1, 2, * , 张思瑶 1, 2 , 张洋 1, 2 , 任学志 1, 2 , 杜雅琳 1, 2 , 张爽 1, 2 , 马语璠 1 , 王彧洋 1, 2
中国环境科学 | 水污染与控制 2025,45(7): 3799-3806
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中国环境科学 |水污染与控制 2025 , 45 (7) : 3799 -3806
双阴膜流动电极电容去离子净化含铬废水
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刘翰隆(2003-),男,湖北鄂州人,吉林大学硕士研究生,主要从事电化学对水中污染物去除的研究..

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刘翰隆(2003-),男,湖北鄂州人,吉林大学硕士研究生,主要从事电化学对水中污染物去除的研究..

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刘翰隆1, 2 , 张春鹏1, 2, * , 张思瑶1, 2, 张洋1, 2, 任学志1, 2, 杜雅琳1, 2, 张爽1, 2, 马语璠1, 王彧洋1, 2
作者信息
  • 1.吉林大学,石油化工污染场地控制与修复技术国家地方联合工程实验室,吉林 长春 130061
  • 2.吉林大学新能源与环境学院,吉林 长春 130021
通讯作者:
* 责任作者,副教授,
作者简介:

刘翰隆(2003-),男,湖北鄂州人,吉林大学硕士研究生,主要从事电化学对水中污染物去除的研究..

Purification of chromium-containing wastewater using symmetric anion-exchange membrane flow-electrode capacitive deionization
Han-long LIU1, 2 , Chun-peng ZHANG1, 2, * , Si-yao ZHANG1, 2, Yang ZHANG1, 2, Xue-zhi REN1, 2, Ya-lin DU1, 2, Shuang ZHANG1, 2, Yu-fan MA1, Yu-yang WANG1, 2
Affiliations
  • 1.National and Local Joint Engineering Laboratory for Petrochemical Contaminated Site Control and Remediation Technology, Jilin University, Changchun 130061, China
  • 2.College of New Energy and Environment, Jilin University, Changchun 130021, China
出版时间: 2025-07-20
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开发了一种完全对称的“双阴膜”流动电极电容去离子(SFCDI)装置处理含六价铬Cr(Ⅵ)废水,采用双阴离子交换膜和短路闭合模式,无需高浓度背景离子,即可实现高效Cr(Ⅵ)去除.结果表明,这一构型的显著特点是避免了传统FCDI中因使用阳离子交换膜而导致的Cr3+回渗与总Cr浓度反弹问题.在1.2V电压、初始pH 5.0条件下,SFCDI在150min内将Cr(Ⅵ)浓度从50mg/L降低至0.41mg/L,总Cr去除效率达97.55%,能耗仅为0.12kWh/m3.与传统FCDI相比,SFCDI显著提高了总Cr去除效率并有效阻止Cr3+回流.进一步研究分析了电压、活性炭含量、pH值及共存阴离子对处理性能的影响,并验证了SFCDI在连续运行及实际电镀废水处理中的适用性和稳定性.在180min内,对实际电镀废水的Cr(Ⅵ)去除率达97.68%,展现出绿色、高效、低能耗的应用潜力.

双阴膜设计  /  流动电极电容去离子  /  六价铬  /  含铬废水  /  电镀废水

A fully symmetric "dual-anion membrane" flow-electrode capacitive deionization (SFCDI) device was developed for treating wastewater containing hexavalent chromium (Cr(Ⅵ)). By employing dual anion-exchange membranes and operating in a short-circuit discharge mode, efficient Cr(Ⅵ) removal can be achieved without the need for high concentration background ions. Results showed that, a key feature of this configuration is its ability to prevent Cr3+ back-diffusion and total chromium concentration rebound, which are common issues in traditional FCDI systems using cation-exchange membranes. Under conditions of 1.2V applied voltage and an initial pH of 5.0, the SFCDI reduced the Cr(Ⅵ) concentration from 50mg/L to 0.41mg/L within 150minutes, achieving a total chromium removal efficiency of 97.55% with an energy consumption of only 0.12kWh/m3. Compared to traditional FCDI, SFCDI significantly improved the total chromium removal efficiency while effectively preventing Cr3+ backflow. Further research systematically analyzed the effects of voltage, activated carbon content, pH, and coexisting anions on performance and demonstrated the applicability and stability of SFCDI in continuous operation and actual electroplating wastewater treatment. Within 180minutes, the removal rate of Cr(Ⅵ) in actual electroplating wastewater reached 97.68%, showcasing its potential as a green, efficient, and low-energy solution.

symmetric anion exchange membrane design  /  flow-electrode capacitive deionization  /  hexavalent chromium  /  chromium-contaminated wastewater  /  electroplating wastewater
刘翰隆, 张春鹏, 张思瑶, 张洋, 任学志, 杜雅琳, 张爽, 马语璠, 王彧洋. 双阴膜流动电极电容去离子净化含铬废水. 中国环境科学, 2025 , 45 (7) : 3799 -3806 .
Han-long LIU, Chun-peng ZHANG, Si-yao ZHANG, Yang ZHANG, Xue-zhi REN, Ya-lin DU, Shuang ZHANG, Yu-fan MA, Yu-yang WANG. Purification of chromium-containing wastewater using symmetric anion-exchange membrane flow-electrode capacitive deionization[J]. China Environmental Science, 2025 , 45 (7) : 3799 -3806 .
  • 国家重点研发计划项目(2022YFC3702200)
  • 国家自然科学基金青年基金资助项目(42107483)
  • 吉林大学研究生创新基金资助项目(2024CX324)
  • 吉林大学本科生科研训练计划项目(25210803; 25210215; 25220423; 25220431)
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  • 接收时间:2024-12-12
  • 首发时间:2026-10-08
  • 出版时间:2025-07-20
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  • 收稿日期:2024-12-12
基金
国家重点研发计划项目(2022YFC3702200)
国家自然科学基金青年基金资助项目(42107483)
吉林大学研究生创新基金资助项目(2024CX324)
吉林大学本科生科研训练计划项目(25210803; 25210215; 25220423; 25220431)
作者信息
    1.吉林大学,石油化工污染场地控制与修复技术国家地方联合工程实验室,吉林 长春 130061
    2.吉林大学新能源与环境学院,吉林 长春 130021

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* 责任作者,副教授,
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