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An original strategy for immobilization of photocatalyst on the gelatinous membrane surface to fabricate the composite photocatalytic membrane through submerged precipitated phase inversion method based on the gel property of organic casting solution was proposed to solve the problem of membrane fouling and photocatalyst recovery. The effect of photocatalyst on the structure and performance of the composite photocatalytic membrane was studied systematically. With the increase of photocatalyst load, the micropore of the composite photocatalytic membrane was occupied by the photocatalyst to form a uniform and complete photocatalytic layer, which contributed to improve the optical property, hydrophilicity and water flux of the composite photocatalytic membrane. The water flux was 628L/(m²·h), 92.76% and 41.53% of fluvastatin and TOC were removed by the composite photocatalytic membrane with ZnIn₂S₄ loading of 1.2mg/cm². Compared with PVDF membrane, the permeability and photocatalytic performance were enhanced and the stability of performance was demonstrated during the long-term operation. The outstanding antifouling performance of the composite photocatalytic membrane was confirmed due to the photocatalytic degradation of pollutant adsorbed on the membrane surface or pore. The stable immobilization of photocatalyst and efficient utilization of incident light were simultaneously achieved for the composite photocatalytic membrane. The structure and performance of the composite photocatalytic membrane were also regulated. A feasible way for beneficial combination of photocatalysis and membrane separation was provided.

, authors=Ting-ting LIU^*, Jian BAI, Yu-xuan ZHANG, authorsList=Ting-ting LIU, Jian BAI, Yu-xuan ZHANG, authorCompany=null, correspAuthors=Ting-ting LIU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314917469148512946, articleId=1314917468557116080, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=表面复合光催化膜的制备及去除污染物性能, columnId=1234106386565624579, journalTitle=中国环境科学, columnName=水污染与控制, runingTitle=null, highlight=null, articleAbstract=

针对粉末光催化剂回收困难和超滤膜污染问题，提出基于铸膜液凝胶特性在凝胶相薄膜表面固定光催化剂经浸没沉淀相转化过程制备高稳定性表面复合光催化膜的新型制膜策略，研究催化剂参与相转化过程对分离膜结构和性能影响．结果表明，随催化剂负载量增加，表面复合光催化膜小孔结构被催化剂占据形成完整的光催化功能层，增强了分离膜对紫外-可见光吸收能力，提高了亲水性和纯水通量．在催化剂负载量为1.2mg/cm²最佳条件下获得的表面复合光催化膜纯水通量高达628L/（m²·h），对氟伐他汀和TOC去除率分别为92.76%和41.53%．与PVDF膜相比，其污染物去除性能和渗透性能明显增强且具有良好的稳定性．由于光催化功能层将吸附在膜面或膜孔内的污染物降解，表面复合光催化膜具备优异的抗污染性能．该策略在提高催化剂固定化程度的同时保证了催化剂对光源的高效利用并实现了膜结构与性能调控，为光催化和膜分离技术的优势结合提供参考．

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刘婷婷（1990-）女，山西太原人，讲师，博士，从事膜分离技术在水处理中的应用研究．发表论文10篇．ttliu@xpu.edu.cn.

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刘婷婷（1990-）女，山西太原人，讲师，博士，从事膜分离技术在水处理中的应用研究．发表论文10篇．ttliu@xpu.edu.cn.

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