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Volatile organic compounds(VOCs)were identified as chemicals that caused odor pollution in cars. Nanostructured water ion(EWNS)technology was demonstrated to be capable of producing large amounts of hydroxyl radicals to degrade VOCs, though systematic research on odor VOC removal had not been conducted. In this study, VOCs components from 9cars were first analyzed offline using TD-GC-MS, and the main odor VOCs in actual car interiors were determined through the comprehensive scoring method. A mixture gas containing the average concentration ratio of detected odor VOCs was then introduced into the experimental vehicle, where degradation efficiency was evaluated using EWNS technology. Human health risk assessment was also performed. The results revealed that aliphatic compounds were detected most frequently(7species)in car interior VOCs, while aromatic compounds were found to have the highest detection rate and concentration. Through odor identification scoring, xylene, toluene, ethyl acetate, o-xylene, n-butanol, and hexanal were selected as representative odor VOCs. After EWNS treatment, significant removal effects were observed for all representative odor VOCs, with toluene removal rate being recorded at 92.8%. However, EWNS degradation efficiency was found to vary with placement locations in the vehicle, where better removal effects were achieved in rear positions compared to front positions, potentially associated with hydroxyl radical diffusion efficiency. Meanwhile, the carcinogenic risks of benzene and ethylbenzene were significantly reduced, transitioning from carcinogenic risk to risk-free status.
, correspAuthors=Xiao-bing PANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, authorCompany=null, fund=null, authors=null, authorsList=Zi-han SUN, Geng WANG, Peng-kai TANG, Chao HUANG, Zhi-biao YANG, Xiao-bing PANG), CN=ArticleExt(id=1241057228728365166, articleId=1241057223422571194, tenantId=1146029695717560320, journalId=1234093305789726721, language=CN, title=小客车室内异味VOCs的治理及健康风险评估, columnId=1234106388364981004, journalTitle=中国环境科学, columnName=大气污染与控制, runingTitle=null, highlight=null, articleAbstract=
挥发性有机物(VOCs)是造成汽车室内异味污染的重要物质之一,纳米结构水离子(EWNS)技术可产生大量羟基自由基降解VOCs,但对于异味VOCs的去除缺少系统研究.使用TD-GC-MS对9辆汽车进行VOCs成分离线分析,根据综合评分法确定实际车内的主要异味VOCs.后在实验车内添加依据检出异味VOCs的平均浓度比配置的混标气体,使用EWNS进行降解,测定其对异味VOCs的降解效率,并进行人体健康风险评估.结果表明,车内VOCs中脂肪族化合物数量最多(7种)而芳香族化合物的检出率和检出浓度最高,通过异味识别综合得分排名情况选择间二甲苯、甲苯、乙酸乙酯、邻二甲苯、正丁醇和正己醛为代表性异味VOCs.经过EWNS治理后,对各代表性异味VOCs物质有明显的去除效果,其中对甲苯去除达到92.8%.然而EWNS在车内的放置位置不同,降解效率存在一定的差异,后排的去除效果优于前排,可能与羟基自由基的扩散效率有关.同时,苯和乙苯的致癌风险显著降低,从致癌风险下降到无风险.
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孙孜涵(2001-),男,安徽宿州人,浙江工业大学硕士研究生,主要从事大气环境的监测与研究.sunlucky1621@163.com.
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1.浙江工业大学环境学院,浙江 杭州 310014)]), AuthorCompany(id=1241057230674522293, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, xref=2., ext=[AuthorCompanyExt(id=1241057230682910902, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, companyId=1241057230674522293, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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2.松下家电(中国)有限公司,浙江 杭州 310018)])], figs=[ArticleFig(id=1241057236299084467, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Fig.1, caption=
Schematic diagram of EWNS operational principles, figureFileSmall=UF6qNl3z8hhCr/AHdvTkjw==, figureFileBig=KRh04MspZgWBU7fkMsEATQ==, tableContent=null), ArticleFig(id=1241057236517188282, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=图1, caption=
EWNS工作原理, figureFileSmall=UF6qNl3z8hhCr/AHdvTkjw==, figureFileBig=KRh04MspZgWBU7fkMsEATQ==, tableContent=null), ArticleFig(id=1241057236794012372, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Fig.2, caption=
Schematic diagram of cabin air sampling in test vehicles, figureFileSmall=jQim/uU2C8FGhliI6pw9+A==, figureFileBig=CTMXMFcBhYbTqez8TmFSgA==, tableContent=null), ArticleFig(id=1241057236924035806, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=图2, caption=
测试车辆室内空气采样示意, figureFileSmall=jQim/uU2C8FGhliI6pw9+A==, figureFileBig=CTMXMFcBhYbTqez8TmFSgA==, tableContent=null), ArticleFig(id=1241057237007921894, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Fig.3, caption=
Organic compounds speciation profile in vehicle cabin, figureFileSmall=bBMCt0ujgXfFWvIcS6SHxQ==, figureFileBig=EdnHbs3elWkP5KiqBomPOg==, tableContent=null), ArticleFig(id=1241057237116973802, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=图3, caption=
车舱中有机物种类分布, figureFileSmall=bBMCt0ujgXfFWvIcS6SHxQ==, figureFileBig=EdnHbs3elWkP5KiqBomPOg==, tableContent=null), ArticleFig(id=1241057237293134587, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Fig.4, caption=
Detection prevalence and concentration profiling of VOCs in vehicle cabin, figureFileSmall=CyAiSai/nlCz6nYQv9W/gQ==, figureFileBig=Zc1GFrQzrejKzHBpqRk57Q==, tableContent=null), ArticleFig(id=1241057237418963718, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=图4, caption=
车舱中VOCs的检出率及浓度, figureFileSmall=CyAiSai/nlCz6nYQv9W/gQ==, figureFileBig=Zc1GFrQzrejKzHBpqRk57Q==, tableContent=null), ArticleFig(id=1241057237528015632, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Fig.5, caption=
Temporal variation of substance concentrations and removal efficiency under different operational conditions, figureFileSmall=kFz/OWOb0C4G7qTdkVCh4A==, figureFileBig=JqDyNFfdyMijnoKwUkxE0w==, tableContent=null), ArticleFig(id=1241057237708370719, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=图5, caption=
不同条件下各物质浓度和去除率随时间的变化, figureFileSmall=kFz/OWOb0C4G7qTdkVCh4A==, figureFileBig=JqDyNFfdyMijnoKwUkxE0w==, tableContent=null), ArticleFig(id=1241057239239291689, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Fig.6, caption=
Comparative health risk assessment of target contaminants pre- and post-remediation, figureFileSmall=4hN8OhAXhNXMPqyn0M8EJQ==, figureFileBig=G+S5KdyRrWU+zbvt250sJA==, tableContent=null), ArticleFig(id=1241057239373509427, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=图6, caption=
治理前后各物质健康风险评估变化, figureFileSmall=4hN8OhAXhNXMPqyn0M8EJQ==, figureFileBig=G+S5KdyRrWU+zbvt250sJA==, tableContent=null), ArticleFig(id=1241057239482561338, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Table 1, caption=
The compilation of experimental vehicle baseline parameters
, figureFileSmall=null, figureFileBig=null, tableContent=
| 车辆编号 | 品牌 | 使用年限 (月) | 行驶里程 (km) | 内饰材质 |
|---|
| 测试车辆1 | 特斯拉 | 33 | 35000 | 皮革 |
| 测试车辆2 | 沃尔沃 | 24 | 30000 | 皮革 |
| 测试车辆3 | 奔驰 | 24 | 40000 | 皮革 |
| 测试车辆4 | 奥迪 | 72 | 71000 | 皮革 |
| 测试车辆5 | 丰田 | 48 | 80000 | 皮革 |
| 测试车辆6 | 雷克萨斯 | 18 | 10000 | 皮革 |
| 测试车辆7 | 宝马 | 18 | 16000 | 皮革 |
| 测试车辆8 | 福特 | 6 | 7000 | 皮革 |
| 测试车辆9 | 奔驰 | 12 | 26000 | 皮革 |
| 实验车辆1 | 比亚迪 | <1 | <100 | 皮革 |
| 实验车辆2 | 比亚迪 | <1 | <100 | 皮革 |
), ArticleFig(id=1241057239616779080, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=表1, caption=
实验车辆基本信息汇总
, figureFileSmall=null, figureFileBig=null, tableContent=
| 车辆编号 | 品牌 | 使用年限 (月) | 行驶里程 (km) | 内饰材质 |
|---|
| 测试车辆1 | 特斯拉 | 33 | 35000 | 皮革 |
| 测试车辆2 | 沃尔沃 | 24 | 30000 | 皮革 |
| 测试车辆3 | 奔驰 | 24 | 40000 | 皮革 |
| 测试车辆4 | 奥迪 | 72 | 71000 | 皮革 |
| 测试车辆5 | 丰田 | 48 | 80000 | 皮革 |
| 测试车辆6 | 雷克萨斯 | 18 | 10000 | 皮革 |
| 测试车辆7 | 宝马 | 18 | 16000 | 皮革 |
| 测试车辆8 | 福特 | 6 | 7000 | 皮革 |
| 测试车辆9 | 奔驰 | 12 | 26000 | 皮革 |
| 实验车辆1 | 比亚迪 | <1 | <100 | 皮革 |
| 实验车辆2 | 比亚迪 | <1 | <100 | 皮革 |
), ArticleFig(id=1241057239759385429, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Table 2, caption=
The analytical parameters for TD-GC-MS system configuration
, figureFileSmall=null, figureFileBig=null, tableContent=
| TD | GC | MS |
|---|
| 参数 | 值 | 参数 | 值 | 参数 | 值 |
| 吹扫时间(min) | 2 | 进样口温度(℃) | 200 | 接口温度(℃) | 280 |
| 样品解析时间(min) | 10 | 分流比 | 20:1 | 离子源温度(℃) | 250 |
| 样品解析温度(℃) | 320 | 载气流速(mL/min) | 1.0 | 扫描模式 | 全扫描 |
| 冷阱吹扫时间(min) | 2 | 溶剂延迟时间(min) | 0 | 扫描范围(amu) | 26~250 |
| 冷阱解析时间(min) | 5 | | | | |
| 冷阱加热速率(℃/min) | 40 | | | | |
| 冷阱低温(℃) | -30 | | | | |
| 冷阱高温(℃) | 325 | | | | |
), ArticleFig(id=1241057239901991775, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=表2, caption=
TD-GC-MS联用仪分析条件参数
, figureFileSmall=null, figureFileBig=null, tableContent=
| TD | GC | MS |
|---|
| 参数 | 值 | 参数 | 值 | 参数 | 值 |
| 吹扫时间(min) | 2 | 进样口温度(℃) | 200 | 接口温度(℃) | 280 |
| 样品解析时间(min) | 10 | 分流比 | 20:1 | 离子源温度(℃) | 250 |
| 样品解析温度(℃) | 320 | 载气流速(mL/min) | 1.0 | 扫描模式 | 全扫描 |
| 冷阱吹扫时间(min) | 2 | 溶剂延迟时间(min) | 0 | 扫描范围(amu) | 26~250 |
| 冷阱解析时间(min) | 5 | | | | |
| 冷阱加热速率(℃/min) | 40 | | | | |
| 冷阱低温(℃) | -30 | | | | |
| 冷阱高温(℃) | 325 | | | | |
), ArticleFig(id=1241057240048792429, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Table 3, caption=
Screening indexes and grading criteria for each pollutant
, figureFileSmall=null, figureFileBig=null, tableContent=
赋值 (r) | 嗅阈值r1 (mg/m3) | 浓度r2 (µg/m3) | 挥发性r3 (kPa2) | 检出率r4 (%) |
|---|
| 1 | >100 | 0~50 | <10-5 | 0~20 |
| 2 | 1~100 | 50~100 | 10-5~1 | 20~40 |
| 3 | 10-2~1 | 100~150 | 1~10 | 40~60 |
| 4 | 10-3~10-2 | 150~200 | 10~100 | 60~80 |
| 5 | <10-4 | >200 | >100 | 80~100 |
), ArticleFig(id=1241057240191398774, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=表3, caption=
各污染物筛选指标与赋分标准
, figureFileSmall=null, figureFileBig=null, tableContent=
赋值 (r) | 嗅阈值r1 (mg/m3) | 浓度r2 (µg/m3) | 挥发性r3 (kPa2) | 检出率r4 (%) |
|---|
| 1 | >100 | 0~50 | <10-5 | 0~20 |
| 2 | 1~100 | 50~100 | 10-5~1 | 20~40 |
| 3 | 10-2~1 | 100~150 | 1~10 | 40~60 |
| 4 | 10-3~10-2 | 150~200 | 10~100 | 60~80 |
| 5 | <10-4 | >200 | >100 | 80~100 |
), ArticleFig(id=1241057240304644987, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Table 4, caption=
Comprehensive odor recognition scoring ranking of detected compounds
, figureFileSmall=null, figureFileBig=null, tableContent=
| 排名 | 物质 | 嗅阈值 (mg/m3) | 浓度 (µg/m3) | 挥发性 (kPa) | 检出率 (%) | 分值 |
|---|
| 1 | 间二甲苯 | 9.1×10-2 | 175.12 | 1.16 | 100 | 3.50 |
| 2 | 甲苯 | 9.8×10-2 | 280.31 | 3.80 | 100 | 3.45 |
| 3 | 乙酸乙酯 | 0.84 | 175.04 | 1.59×101 | 100 | 3.30 |
| 4 | 邻二甲苯 | 2.80 | 102.35 | 8.01×10-1 | 100 | 2.94 |
| 5 | 正丁醇 | 6.60×10-2 | 133.69 | 8.20×10-1 | 100 | 2.92 |
| 6 | 正己醛 | 1.25×10-3 | 31.58 | 1.45 | 100 | 2.89 |
| 7 | 异辛醇 | 5.41×10-2 | 54.70 | 5.50×101 | 80 | 2.89 |
| 8 | 乙苯 | 8.06×10-1 | 63.80 | 1.23 | 100 | 2.84 |
| 9 | 乙酸丁酯 | 1.16×10-2 | 98.31 | 2.00 | 70 | 2.84 |
| 10 | 壬醇 | 5.80×10-3 | 71.80 | 8.40×10-1 | 50 | 2.83 |
| 11 | 乙醇 | 1.07 | 115.10 | 5.66 | 70 | 2.69 |
| 12 | 苯 | 9.42 | 57.17 | 1.33×101 | 100 | 2.64 |
| 13 | 正己烷 | 5.77 | 68.40 | 3.00×101 | 70 | 2.54 |
| 14 | 丁二烯 | 1.63×10-2 | 60.70 | 8.25×10-1 | 70 | 2.46 |
| 15 | 三甲苯 | 9.12×10-1 | 17.10 | 1.93 | 50 | 2.31 |
| 16 | 甲基环己烷 | 6.57×10-1 | 32.30 | 5.73 | 50 | 2.31 |
| 17 | 甲基异丁基甲酮 | 1.10×10-1 | 40.34 | 2.66 | 50 | 2.21 |
| 18 | 甲基叔丁基醚 | / | 28.80 | 3.27×101 | 50 | 2.11 |
| 19 | 十一烷 | 6.07 | 55.90 | 7.50×10-2 | 60 | 2.08 |
| 20 | 三甲基庚烷 | 9.51 | 44.80 | 2.61 | 70 | 2.03 |
| 21 | 丙二醇 | 5.44×10-1 | 18.80 | 9.60×10-2 | 50 | 2.03 |
| 22 | 异戊烷 | 4.19 | 45.30 | 7.93×101 | 50 | 2.01 |
| 23 | 正丁烷 | 3.11×103 | 89.90 | 1.42×101 | 50 | 1.96 |
| 24 | 苯甲醛 | 9.95 | 12.36 | 1.29×10-1 | 100 | 1.95 |
| 25 | 2,2-二甲基丙醚 | 2.75×10-1/ | 38.10 | 8.33 | 50 | 1.88 |
| 26 | 3-乙基-3甲基庚烷 | 9.53 | 66.10 | 3.47×10-1 | 50 | 1.88 |
| 27 | 乙二醇 | 1.30 | 16.60 | 1.30 | 50 | 1.83 |
| 28 | 苯乙酮 | / | 16.27 | 4.90×10-2 | 60 | 1.75 |
), ArticleFig(id=1241057240422085508, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=表4, caption=
检出物异味识别综合得分排名
, figureFileSmall=null, figureFileBig=null, tableContent=
| 排名 | 物质 | 嗅阈值 (mg/m3) | 浓度 (µg/m3) | 挥发性 (kPa) | 检出率 (%) | 分值 |
|---|
| 1 | 间二甲苯 | 9.1×10-2 | 175.12 | 1.16 | 100 | 3.50 |
| 2 | 甲苯 | 9.8×10-2 | 280.31 | 3.80 | 100 | 3.45 |
| 3 | 乙酸乙酯 | 0.84 | 175.04 | 1.59×101 | 100 | 3.30 |
| 4 | 邻二甲苯 | 2.80 | 102.35 | 8.01×10-1 | 100 | 2.94 |
| 5 | 正丁醇 | 6.60×10-2 | 133.69 | 8.20×10-1 | 100 | 2.92 |
| 6 | 正己醛 | 1.25×10-3 | 31.58 | 1.45 | 100 | 2.89 |
| 7 | 异辛醇 | 5.41×10-2 | 54.70 | 5.50×101 | 80 | 2.89 |
| 8 | 乙苯 | 8.06×10-1 | 63.80 | 1.23 | 100 | 2.84 |
| 9 | 乙酸丁酯 | 1.16×10-2 | 98.31 | 2.00 | 70 | 2.84 |
| 10 | 壬醇 | 5.80×10-3 | 71.80 | 8.40×10-1 | 50 | 2.83 |
| 11 | 乙醇 | 1.07 | 115.10 | 5.66 | 70 | 2.69 |
| 12 | 苯 | 9.42 | 57.17 | 1.33×101 | 100 | 2.64 |
| 13 | 正己烷 | 5.77 | 68.40 | 3.00×101 | 70 | 2.54 |
| 14 | 丁二烯 | 1.63×10-2 | 60.70 | 8.25×10-1 | 70 | 2.46 |
| 15 | 三甲苯 | 9.12×10-1 | 17.10 | 1.93 | 50 | 2.31 |
| 16 | 甲基环己烷 | 6.57×10-1 | 32.30 | 5.73 | 50 | 2.31 |
| 17 | 甲基异丁基甲酮 | 1.10×10-1 | 40.34 | 2.66 | 50 | 2.21 |
| 18 | 甲基叔丁基醚 | / | 28.80 | 3.27×101 | 50 | 2.11 |
| 19 | 十一烷 | 6.07 | 55.90 | 7.50×10-2 | 60 | 2.08 |
| 20 | 三甲基庚烷 | 9.51 | 44.80 | 2.61 | 70 | 2.03 |
| 21 | 丙二醇 | 5.44×10-1 | 18.80 | 9.60×10-2 | 50 | 2.03 |
| 22 | 异戊烷 | 4.19 | 45.30 | 7.93×101 | 50 | 2.01 |
| 23 | 正丁烷 | 3.11×103 | 89.90 | 1.42×101 | 50 | 1.96 |
| 24 | 苯甲醛 | 9.95 | 12.36 | 1.29×10-1 | 100 | 1.95 |
| 25 | 2,2-二甲基丙醚 | 2.75×10-1/ | 38.10 | 8.33 | 50 | 1.88 |
| 26 | 3-乙基-3甲基庚烷 | 9.53 | 66.10 | 3.47×10-1 | 50 | 1.88 |
| 27 | 乙二醇 | 1.30 | 16.60 | 1.30 | 50 | 1.83 |
| 28 | 苯乙酮 | / | 16.27 | 4.90×10-2 | 60 | 1.75 |
), ArticleFig(id=1241057240585663378, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=EN, label=Table 5, caption=
Comparative analysis of removal efficiency based on installation positions and EWNS quantity(%)
, figureFileSmall=null, figureFileBig=null, tableContent=
| 物质 | 去除率 |
|---|
| 1台 (前排通风口) | 2台 (前排通风口) | 1台 (后排通风口) | 2台 (后排通风口) |
|---|
| 正己醛 | 70.82 | 82.33 | 75.19 | 86.12 |
| 甲苯 | 73.51 | 87.29 | 80.38 | 92.87 |
| 正丁醇 | 72.90 | 84.14 | 79.22 | 90.53 |
| 间二甲苯 | 73.06 | 86.93 | 78.90 | 91.42 |
| 邻二甲苯 | 75.28 | 88.11 | 80.14 | 90.31 |
| 乙酸乙酯 | 72.39 | 86.95 | 79.34 | 92.44 |
), ArticleFig(id=1241057240719881117, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241057223422571194, language=CN, label=表5, caption=
不同放置位置及EWNS数量的去除效率对比(%)
, figureFileSmall=null, figureFileBig=null, tableContent=
| 物质 | 去除率 |
|---|
| 1台 (前排通风口) | 2台 (前排通风口) | 1台 (后排通风口) | 2台 (后排通风口) |
|---|
| 正己醛 | 70.82 | 82.33 | 75.19 | 86.12 |
| 甲苯 | 73.51 | 87.29 | 80.38 | 92.87 |
| 正丁醇 | 72.90 | 84.14 | 79.22 | 90.53 |
| 间二甲苯 | 73.06 | 86.93 | 78.90 | 91.42 |
| 邻二甲苯 | 75.28 | 88.11 | 80.14 | 90.31 |
| 乙酸乙酯 | 72.39 | 86.95 | 79.34 | 92.44 |
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