Article(id=1241049976726409733, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1241049962679694215, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1717603200000, receivedDateStr=2024-06-06, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1773818972044, onlineDateStr=2026-03-18, pubDate=1737302400000, pubDateStr=2025-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1773818972044, onlineIssueDateStr=2026-03-18, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1773818972044, creator=13701087609, updateTime=1773818972044, updator=13701087609, issue=Issue{id=1241049962679694215, tenantId=1146029695717560320, journalId=1234093305789726721, year='2025', volume='45', issue='1', pageStart='1', pageEnd='592', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1773818968696, creator=13701087609, updateTime=1773819749443, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1241053237428671382, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1241049962679694215, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1241053237428671383, tenantId=1146029695717560320, journalId=1234093305789726721, issueId=1241049962679694215, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=538, endPage=556, ext={EN=ArticleExt(id=1241049978597069349, articleId=1241049976726409733, tenantId=1146029695717560320, journalId=1234093305789726721, language=EN, title=Reactive organic carbon emissions from automotive manufacturing industry in China, columnId=1234106390126588740, journalTitle=China Environmental Science, columnName=Carbon Emission Control, runingTitle=null, highlight=null, articleAbstract=

Eight representative automobile manufacturing enterprises were investigated, and 109 samples of raw and auxiliary materials, including coatings and adhesives, were collected to determine reactive organic carbon (ROC) and to establish the source composition spectrum of ROC in automobile manufacturing industry. The maximum incremental reactivity (MIR) method and two-product parametric method were used to quantify the corresponding contributions of ROC to the generation of O₃ and SOA. The results showed that: ① The VOC contents in different types of raw and auxiliary materials varied considerably: the average ρ(VOCs)of water-based and solvent-based automotive coatings were 289.92 and 490.32g/L; the average ρ(VOCs) of water-based, bulk and solvent-based adhesives were 27.00, 27.50 and 196.67g/L, respectively; and the average ρ(VOCs) of water-based and solvent-based cleaning agents were 116.60 and 831.20g/L. ② The main components of water-based coatings were alcohol ethers and ether esters, esters and alcohols, the main components of solvent-based coatings were aromatic hydrocarbons, esters and alcohols, and the main components of both bulk and solvent-based adhesives were alkanes. ③ In water-based coatings, the mass proportions of various organics were SVOCs (36.03%), IVOCs (37.77%) and VOCs (26.21%). In solvent-based coatings, the mass proportions of various organics were IVOCs (4.59%) and VOCs (95.41%). In bulk adhesives, the main organics was VOCs (100%). In solvent-based adhesives, the mass proportions of various organics were IVOCs (2.64%) and VOCs (97.36%). ④ The OFP productions by water-based coatings, solvent-based coatings, bulk and solvent-based adhesives were 93.67, 2679.27, 25.82, and 41.82g O₃/(L raw materials), respectively, and the primary contributing species were diethylene glycol butyl ether (42.03%), 1,2,3-trimethylbenzene(28.29%), 2,2,4,6,6-pentamethylheptane (52.20%), and 2,2,4,6,6-pentamethylheptae (78.63%), respectively. ⑤ The SOA productions by water-based coatings, solvent-based coatings, bulk and solvent-based adhesives were 18.49, 16.70, 4.82, and 4.28g SOA/(L raw materials), respectively. The largest contributions to SOA formation were caused by IVOC and SVOC species in water-based coatings, yet the largest contributions to SOA formation were VOCs species in solvent-based coatings and adhesives. ⑥After adding the assessment of the contribution of IVOCs and SVOCs species to SOA generation in the study, it was found that SOA productions per unit volume of water-based coatings were higher than that for solvent-based coatings and adhesives, which showed that the effects of SVOCs and IVOCs in water-based coatings on the atmospheric environment should be taken into account in pollution prevention policies formulation.

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以汽车制造行业为对象，选取8家典型企业，采集109个涂料、胶粘剂等原辅料样品，检测其活性有机碳(ROC)，建立汽车制造行业ROC源成分谱.通过最大增量反应活性法和二次产物的参数化产率法，量化样品中ROC对臭氧(O₃)和SOA的生成贡献.结果表明：①不同类型原辅料中VOCs含量差异较大，水性和溶剂型汽车涂料平均ρ(VOCs)为289.92和490.32g/L；水性、本体型及溶剂型胶粘剂平均ρ(VOCs)为27.00,27.50和196.67g/L；水性和溶剂型清洗剂平均ρ(VOCs)为116.60和831.20g/L.②水性涂料的主要组分为醇醚及醚酯类、酯类和醇类，溶剂型涂料的主要组分为芳香烃、酯类和醇类，本体型胶粘剂和溶剂型胶粘剂的主要组分均为烷烃.③水性涂料中，各种类型有机物质量占比依次为SVOCs(36.03%)、IVOCs(37.77%)和VOCs(26.21%)；溶剂型涂料中，主要为VOCs(95.41%)，仅含少量IVOCs(4.59%)，未检出SVOCs；本体型胶粘剂中仅检测出VOCs；溶剂型胶粘剂中，主要为VOCs(97.36%)，含少量IVOCs(2.64%)，未检出SVOCs.④水性涂料、溶剂型涂料、本体型胶粘剂和溶剂型胶粘剂中ROC的OFP值分别为93.67,2679.27,25.82和41.82g O₃/(L 原辅料)，首要贡献物种分别为二乙二醇丁醚(42.03%)、1,2,3-三甲苯(28.29%)、2,2,4,6,6-五甲基庚烷(52.20%)和2,2,4,6,6-五甲基庚烷(78.63%).⑤水性涂料、溶剂型涂料、本体型胶粘剂和溶剂型胶粘剂中ROC的SOA值分别为18.49,16.70,4.82和4.28g SOA/(L原辅料)，水性涂料中IVOCs和SVOCs物种对SOA生成贡献率最高；溶剂型涂料及胶粘剂中VOCs物种对SOA生成贡献率最高.⑥本研究加入IVOCs和SVOCs物种对SOA生成贡献的评估后，发现单位体积水性涂料所生成的SOA值高于溶剂型涂料和胶粘剂，应在污染防治政策制定中重视水性涂料中SVOCs和IVOCs对大气环境的影响.

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贾海洋(2000-)，男，山西大同人，硕士研究生，主要研究方向为VOCs污染防治.发表论文1篇.jiahaiyang0225@163.com.

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贾海洋(2000-)，男，山西大同人，硕士研究生，主要研究方向为VOCs污染防治.发表论文1篇.jiahaiyang0225@163.com.

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a1.邻苯二甲酸二异辛酯，a2.二乙二醇丁醚，a3.乙二醇乙醚，a4.N-甲基吡咯烷酮，a5.正丁醇，a6.丙二醇丁醚，a7.丙二醇甲醚，a8.2-乙基己醇，a9.正丙醇，a10.1,1'-[(1-甲基-1,2-乙亚基)二(氧)]二-(2-丙醇)；b1.3-乙氧基丙酸乙酯，b2.1,2,3-三甲苯，b3.正丁醇，b4.间-二甲苯，b5.3-乙基甲苯，b6.乙酸丁酯，b7.1,2,4-三甲苯，b8.邻-二甲苯，b9.异丁醇，b10.1,4-二乙基苯；c1.2,2,4,6,6-五甲基庚烷，c2.2-甲基癸烷，c3.十一烷，c4.3-甲基癸烷，c5.2,2,4,4-四甲基辛烷；d1.2,2,4,6,6-五甲基庚烷，d2.2,2,4,4-四甲基辛烷，d3.2-乙基己醇

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a1.二乙二醇丁醚，a2.乙二醇乙醚，a3.N-甲基吡咯烷酮，a4.正丁醇，a5.N，N-二甲基乙醇胺，a6.丙二醇丁醚，a7.丙二醇甲醚，a8.正丙醇，a9.二丙二醇甲醚，a10.4-甲基-2-戊酮；b1.1,2,3-三甲苯，b2.间-二甲苯，b3.3-乙基甲苯，b4.3-乙氧基丙酸乙酯，b5.正丁醇，b6.1,2,4-三甲苯，b7.邻-二甲苯，b8.1,4-二乙基苯，b9.邻-乙基甲苯，b10.异丁醇；c1.2,2,4,6,6-五甲基庚烷，c2.2-甲基癸烷，c3.3-甲基癸烷，c4.十一烷，c5.2,2,4,4-四甲基辛烷；d1.2,2,4,6,6-五甲基庚烷，d2.2,2,4,4-四甲基辛烷，d3.2-乙基己醇

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Classification and basic information of samples

, figureFileSmall=null, figureFileBig=null, tableContent=

产品类别	产品类型	分散介质类型	样品个数	样品品牌数
涂料	电泳底漆(包括其他底漆)	水性	8	6
	中涂	水性	10	6
	底色漆	水性	40	6
		溶剂型	2	1
	本色面漆	水性	8	3
	清漆	溶剂型	10	7
	PVC抗击石涂料	溶剂型	5	3
胶粘剂	水性		3	2
	溶剂型		3	3
	本体型		12	5
清洗剂	水性		3	3
	溶剂型		5	4
合计			109

), ArticleFig(id=1241050010473780064, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241049976726409733, language=CN, label=表1, caption=

样品分类情况及基本信息

, figureFileSmall=null, figureFileBig=null, tableContent=

产品类别	产品类型	分散介质类型	样品个数	样品品牌数
涂料	电泳底漆(包括其他底漆)	水性	8	6
	中涂	水性	10	6
	底色漆	水性	40	6
		溶剂型	2	1
	本色面漆	水性	8	3
	清漆	溶剂型	10	7
	PVC抗击石涂料	溶剂型	5	3
胶粘剂	水性		3	2
	溶剂型		3	3
	本体型		12	5
清洗剂	水性		3	3
	溶剂型		5	4
合计			109

), ArticleFig(id=1241050010658329457, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241049976726409733, language=EN, label=Table 2, caption=

Comparisons of the VOC contents in raw and auxiliary materials measured in this study with relevant standards and researches

, figureFileSmall=null, figureFileBig=null, tableContent=

产品类别	产品类型	分散介质类型	标准限值(g/L)	本研究平均VOCs含量(g/L)	样品数量	达标率(%)	其他研究结果(g/L)
涂料	底漆(电泳底漆)	水性	250.00[39]	169.95	8	75.00	260.06[26]
	中涂	水性	350.00[39]	178.71	10	100.00	199.90[26]
	底色漆	水性	530.00[39]	311.58	40	87.50	186.73[26]
		溶剂型	750.00[39]	615.56	2	100.00	669.48[26]
	本色面漆	水性	420.00[39]	440.61	8	37.50	—
	清漆	溶剂型	550.00[39]	465.28	10	90.00	429.60[26]
	PVC抗击石涂料	溶剂型	—	71.80	5	—	—
胶粘剂		水性	50.00[43]	27.00	3	66.67	—
		溶剂型	250.00[43]	196.67	3	66.67	—
		本体型	100.00[43]	27.50	12	100.00	—
清洗剂		水性	50.00[44]	116.60	3	0.00	—
		溶剂型	900.00[44]	831.20	5	100.00	—

), ArticleFig(id=1241050010901599101, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241049976726409733, language=CN, label=表2, caption=

原辅料VOCs含量检测结果与相关标准及研究结果比对

, figureFileSmall=null, figureFileBig=null, tableContent=

产品类别	产品类型	分散介质类型	标准限值(g/L)	本研究平均VOCs含量(g/L)	样品数量	达标率(%)	其他研究结果(g/L)
涂料	底漆(电泳底漆)	水性	250.00[39]	169.95	8	75.00	260.06[26]
	中涂	水性	350.00[39]	178.71	10	100.00	199.90[26]
	底色漆	水性	530.00[39]	311.58	40	87.50	186.73[26]
		溶剂型	750.00[39]	615.56	2	100.00	669.48[26]
	本色面漆	水性	420.00[39]	440.61	8	37.50	—
	清漆	溶剂型	550.00[39]	465.28	10	90.00	429.60[26]
	PVC抗击石涂料	溶剂型	—	71.80	5	—	—
胶粘剂		水性	50.00[43]	27.00	3	66.67	—
		溶剂型	250.00[43]	196.67	3	66.67	—
		本体型	100.00[43]	27.50	12	100.00	—
清洗剂		水性	50.00[44]	116.60	3	0.00	—
		溶剂型	900.00[44]	831.20	5	100.00	—

), ArticleFig(id=1241050011081954193, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241049976726409733, language=EN, label=Table 3, caption=

ROC emission composition spectrum of automotive manufacturing industry

, figureFileSmall=null, figureFileBig=null, tableContent=

类别	编号	组分名称	有机物种类型	质量分数±标准偏差(%)
				水性涂料	溶剂型涂料	本体型胶粘剂	溶剂型胶粘剂
烷烃	1	3-乙基戊烷	VOC	n.d.	0.14±0.20	n.d.	n.d.
	2	庚烷	VOC	n.d.	1.03±1.46	n.d.	n.d.
	3	壬烷	VOC	n.d.	0.17±0.24	n.d.	n.d.
	4	癸烷	VOC	0.52±0.60	n.d.	n.d.	n.d.
	5	十一烷	VOC	1.54±1.84	n.d.	11.38±8.05	n.d.
	6	2-甲基癸烷	VOC	n.d.	n.d.	16.49±11.66	n.d.
	7	3-甲基癸烷	VOC	n.d.	n.d.	10.72±7.58	n.d.
	8	2,6-二甲基癸烷	VOC	n.d.	n.d.	n.d.	n.d.
	9	2,2,4,6,6-五甲基庚烷	VOC	n.d.	n.d.	51.84±21.99	82.94±11.89
	10	2,2,4,4-四甲基辛烷	VOC	n.d.	n.d.	9.57±3.43	14.42±3.43
	11	十三烷	IVOC	0.47±0.94	n.d.	n.d.	n.d.
	12	2,4,6-三甲基癸烷	IVOC	n.d.	n.d.	n.d.	n.d.
	13	十四烷	IVOC	0.23±0.46	n.d.	n.d.	n.d.
		小计		2.76±3.84	1.34±1.89	100.00±52.71	97.36±15.32
芳香烃	14	乙苯	VOC	n.d.	2.29±2.83	n.d.	n.d.
	15	间-二甲苯	VOC	n.d.	10.79±13.69	n.d.	n.d.
	16	邻-二甲苯	VOC	n.d.	3.95±4.06	n.d.	n.d.
	17	异丙苯	VOC	n.d.	0.22±0.31	n.d.	n.d.
	18	丙基苯	VOC	n.d.	0.56±0.79	n.d.	n.d.
	19	3-乙基甲苯	VOC	n.d.	9.85±4.36	n.d.	n.d.
	20	1,2,3-三甲苯	VOC	n.d.	13.95±9.14	n.d.	n.d.
	21	1,2,4-三甲苯	VOC	n.d.	4.22±1.62	n.d.	n.d.
	22	邻-乙基甲苯	VOC	n.d.	1.57±2.22	n.d.	n.d.
	23	萘	VOC	n.d.	0.44±0.63	n.d.	n.d.
	24	4-异丙基甲苯	VOC	0.49±0.98	n.d.	n.d.	n.d.
	25	3-丙基甲苯	VOC	n.d.	0.34±0.48	n.d.	n.d.
	26	1,4-二乙基苯	VOC	n.d.	2.92±2.36	n.d.	n.d.
	27	1,3-二甲基-4-乙基苯	VOC	n.d.	0.88±0.44	n.d.	n.d.
	28	1,2,4,5-四甲苯	VOC	n.d.	0.54±0.40	n.d.	n.d.
	29	1,2,3,4-四甲苯	VOC	n.d.	0.18±0.26	n.d.	n.d.
	30	1-甲基-2-异丙基苯	VOC	n.d.	0.54±0.76	n.d.	n.d.
	31	2-乙基对二甲苯	VOC	n.d.	0.66±0.94	n.d.	n.d.
	32	4-乙基邻二甲苯	VOC	n.d.	0.13±0.18	n.d.	n.d.
		小计		0.49±0.98	54.04±45.47	n.d.	n.d.
醇类	33	正丙醇	VOC	1.68±3.37	n.d.	n.d.	n.d.
	34	正丁醇	VOC	3.17±4.65	13.06±4.36	n.d.	n.d.
	35	异丁醇	VOC	0.26±0.52	3.09±4.38	n.d.	n.d.
	36	2-乙基己醇	IVOC	1.88±3.76	n.d.	n.d.	2.64±1.87
	37	1,1'-[(1-甲基-1,2-乙亚基)二(氧)]二-(2-丙醇)	SVOC	1.61±3.22	n.d.	n.d.	n.d.
	38	2-己基-1-癸醇	SVOC	0.59±1.19	n.d.	n.d.	n.d.
		小计		9.20±16.70	16.15±8.73	n.d.	2.64±1.87
酯类	39	乙酸丁酯	VOC	n.d.	5.93±2.65	n.d.	n.d.
	40	乙酸异丁酯	VOC	n.d.	0.22±0.30	n.d.	n.d.
	41	3-乙氧基丙酸乙酯	VOC	n.d.	16.85±5.05	n.d.	n.d.
	42	戊二酸二甲酯	VOC	n.d.	0.88±1.24	n.d.	n.d.
	43	碳酸二丁酯	IVOC	n.d.	0.24±0.33	n.d.	n.d.
	44	邻苯二甲酸二异辛酯	SVOC	33.82±31.49	n.d.	n.d.	n.d.
		小计		33.82±31.49	24.11±9.58	n.d.	n.d.
醇醚及醚酯类	45	丙二醇甲醚	VOC	2.68±4.82	n.d.	n.d.	n.d.
	46	乙二醇乙醚	IVOC	7.12±14.24	n.d.	n.d.	n.d.
	47	丙二醇甲醚醋酸酯	VOC	1.05±2.10	n.d.	n.d.	n.d.
	48	乙二醇丁醚醋酸酯	VOC	n.d.	2.76±3.90	n.d.	n.d.
	49	丙二醇丁醚	IVOC	2.86±5.71	n.d.	n.d.	n.d.
	50	二丙二醇甲醚	IVOC	1.57±3.14	n.d.	n.d.	n.d.
	51	仲丁醚	VOC	0.37±0.74	n.d.	n.d.	n.d.
	52	二乙二醇丁醚	IVOC	29.25±39.16	1.60±2.26	n.d.	n.d.
	53	十八烷基乙烯基醚	IVOC	1.51±3.03	n.d.	n.d.	n.d.
		小计		46.41±72.94	4.36±6.16	n.d.	n.d.
酮类	54	4-甲基-2-戊酮	VOC	1.04±2.08	n.d.	n.d.	n.d.
	55	N-甲基吡咯烷酮	VOC	4.72±9.44	n.d.	n.d.	n.d.
		小计		5.76±11.52	n.d.	n.d.	n.d.
胺类	56	N，N-二甲基乙醇胺	VOC	1.56±2.01	n.d.	n.d.	n.d.
		小计		1.56±2.01	n.d.	n.d.	n.d.

), ArticleFig(id=1241050011371361181, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241049976726409733, language=CN, label=表3, caption=

汽车制造行业ROC源成分谱

, figureFileSmall=null, figureFileBig=null, tableContent=

类别	编号	组分名称	有机物种类型	质量分数±标准偏差(%)
				水性涂料	溶剂型涂料	本体型胶粘剂	溶剂型胶粘剂
烷烃	1	3-乙基戊烷	VOC	n.d.	0.14±0.20	n.d.	n.d.
	2	庚烷	VOC	n.d.	1.03±1.46	n.d.	n.d.
	3	壬烷	VOC	n.d.	0.17±0.24	n.d.	n.d.
	4	癸烷	VOC	0.52±0.60	n.d.	n.d.	n.d.
	5	十一烷	VOC	1.54±1.84	n.d.	11.38±8.05	n.d.
	6	2-甲基癸烷	VOC	n.d.	n.d.	16.49±11.66	n.d.
	7	3-甲基癸烷	VOC	n.d.	n.d.	10.72±7.58	n.d.
	8	2,6-二甲基癸烷	VOC	n.d.	n.d.	n.d.	n.d.
	9	2,2,4,6,6-五甲基庚烷	VOC	n.d.	n.d.	51.84±21.99	82.94±11.89
	10	2,2,4,4-四甲基辛烷	VOC	n.d.	n.d.	9.57±3.43	14.42±3.43
	11	十三烷	IVOC	0.47±0.94	n.d.	n.d.	n.d.
	12	2,4,6-三甲基癸烷	IVOC	n.d.	n.d.	n.d.	n.d.
	13	十四烷	IVOC	0.23±0.46	n.d.	n.d.	n.d.
		小计		2.76±3.84	1.34±1.89	100.00±52.71	97.36±15.32
芳香烃	14	乙苯	VOC	n.d.	2.29±2.83	n.d.	n.d.
	15	间-二甲苯	VOC	n.d.	10.79±13.69	n.d.	n.d.
	16	邻-二甲苯	VOC	n.d.	3.95±4.06	n.d.	n.d.
	17	异丙苯	VOC	n.d.	0.22±0.31	n.d.	n.d.
	18	丙基苯	VOC	n.d.	0.56±0.79	n.d.	n.d.
	19	3-乙基甲苯	VOC	n.d.	9.85±4.36	n.d.	n.d.
	20	1,2,3-三甲苯	VOC	n.d.	13.95±9.14	n.d.	n.d.
	21	1,2,4-三甲苯	VOC	n.d.	4.22±1.62	n.d.	n.d.
	22	邻-乙基甲苯	VOC	n.d.	1.57±2.22	n.d.	n.d.
	23	萘	VOC	n.d.	0.44±0.63	n.d.	n.d.
	24	4-异丙基甲苯	VOC	0.49±0.98	n.d.	n.d.	n.d.
	25	3-丙基甲苯	VOC	n.d.	0.34±0.48	n.d.	n.d.
	26	1,4-二乙基苯	VOC	n.d.	2.92±2.36	n.d.	n.d.
	27	1,3-二甲基-4-乙基苯	VOC	n.d.	0.88±0.44	n.d.	n.d.
	28	1,2,4,5-四甲苯	VOC	n.d.	0.54±0.40	n.d.	n.d.
	29	1,2,3,4-四甲苯	VOC	n.d.	0.18±0.26	n.d.	n.d.
	30	1-甲基-2-异丙基苯	VOC	n.d.	0.54±0.76	n.d.	n.d.
	31	2-乙基对二甲苯	VOC	n.d.	0.66±0.94	n.d.	n.d.
	32	4-乙基邻二甲苯	VOC	n.d.	0.13±0.18	n.d.	n.d.
		小计		0.49±0.98	54.04±45.47	n.d.	n.d.
醇类	33	正丙醇	VOC	1.68±3.37	n.d.	n.d.	n.d.
	34	正丁醇	VOC	3.17±4.65	13.06±4.36	n.d.	n.d.
	35	异丁醇	VOC	0.26±0.52	3.09±4.38	n.d.	n.d.
	36	2-乙基己醇	IVOC	1.88±3.76	n.d.	n.d.	2.64±1.87
	37	1,1'-[(1-甲基-1,2-乙亚基)二(氧)]二-(2-丙醇)	SVOC	1.61±3.22	n.d.	n.d.	n.d.
	38	2-己基-1-癸醇	SVOC	0.59±1.19	n.d.	n.d.	n.d.
		小计		9.20±16.70	16.15±8.73	n.d.	2.64±1.87
酯类	39	乙酸丁酯	VOC	n.d.	5.93±2.65	n.d.	n.d.
	40	乙酸异丁酯	VOC	n.d.	0.22±0.30	n.d.	n.d.
	41	3-乙氧基丙酸乙酯	VOC	n.d.	16.85±5.05	n.d.	n.d.
	42	戊二酸二甲酯	VOC	n.d.	0.88±1.24	n.d.	n.d.
	43	碳酸二丁酯	IVOC	n.d.	0.24±0.33	n.d.	n.d.
	44	邻苯二甲酸二异辛酯	SVOC	33.82±31.49	n.d.	n.d.	n.d.
		小计		33.82±31.49	24.11±9.58	n.d.	n.d.
醇醚及醚酯类	45	丙二醇甲醚	VOC	2.68±4.82	n.d.	n.d.	n.d.
	46	乙二醇乙醚	IVOC	7.12±14.24	n.d.	n.d.	n.d.
	47	丙二醇甲醚醋酸酯	VOC	1.05±2.10	n.d.	n.d.	n.d.
	48	乙二醇丁醚醋酸酯	VOC	n.d.	2.76±3.90	n.d.	n.d.
	49	丙二醇丁醚	IVOC	2.86±5.71	n.d.	n.d.	n.d.
	50	二丙二醇甲醚	IVOC	1.57±3.14	n.d.	n.d.	n.d.
	51	仲丁醚	VOC	0.37±0.74	n.d.	n.d.	n.d.
	52	二乙二醇丁醚	IVOC	29.25±39.16	1.60±2.26	n.d.	n.d.
	53	十八烷基乙烯基醚	IVOC	1.51±3.03	n.d.	n.d.	n.d.
		小计		46.41±72.94	4.36±6.16	n.d.	n.d.
酮类	54	4-甲基-2-戊酮	VOC	1.04±2.08	n.d.	n.d.	n.d.
	55	N-甲基吡咯烷酮	VOC	4.72±9.44	n.d.	n.d.	n.d.
		小计		5.76±11.52	n.d.	n.d.	n.d.
胺类	56	N，N-二甲基乙醇胺	VOC	1.56±2.01	n.d.	n.d.	n.d.
		小计		1.56±2.01	n.d.	n.d.	n.d.

), ArticleFig(id=1241050011572687780, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241049976726409733, language=EN, label=Table 4, caption=

Top ten species with the largest contribution of ROC to SOA in raw and auxiliary materials

, figureFileSmall=null, figureFileBig=null, tableContent=

序号	水性涂料			溶剂型涂料			本体型胶粘剂			溶剂型胶粘剂
	组分名称	物种类别	贡献率(%)	组分名称	物种类别	贡献率(%)	组分名称	物种类别	贡献率(%)	组分名称	物种类别	贡献率(%)
1	邻苯二甲酸二异辛酯	SVOC	62.84	间二甲苯	VOC	20.23	十一烷	VOC	31.17	2,2,4,6,6-五甲基庚烷	VOC	81.66
2	二乙二醇丁醚	IVOC	27.62	3-乙基甲苯	VOC	16.07	2-甲基癸烷	VOC	30.11	2,2,4,4-四甲基辛烷	VOC	14.20
3	丙二醇丁醚	IVOC	2.70	二乙二醇丁醚	IVOC	13.45	2,2,4,6,6-五甲基庚烷	VOC	29.68	2-乙基己醇	IVOC	4.15
4	十一烷	VOC	1.55	邻二甲苯	VOC	10.74	2,2,4,4-四甲基辛烷	VOC	5.48
5	2-己基-1-癸醇	SVOC	1.10	1,2,3-三甲基苯	VOC	7.58	3-甲基癸烷	VOC	3.56
6	1,1'-[(1-甲基-1,2-乙亚基)二(氧)]二-(2-丙醇)	SVOC	1.03	1,4-二乙基苯	VOC	4.76
7	十三烷	IVOC	0.79	乙二醇丁醚醋酸酯	IVOC	3.90
8	2-乙基己醇	IVOC	0.63	萘	VOC	3.62
9	二丙二醇甲醚	IVOC	0.57	乙苯	VOC	3.12
10	十八烷基乙烯基醚	IVOC	0.51	邻乙基甲苯	VOC	2.56
总计			99.34			86.04			100.00			100.00

), ArticleFig(id=1241050011723682734, tenantId=1146029695717560320, journalId=1234093305789726721, articleId=1241049976726409733, language=CN, label=表4, caption=

原辅料中ROC对SOA贡献率最高的前10位物种

, figureFileSmall=null, figureFileBig=null, tableContent=

序号	水性涂料			溶剂型涂料			本体型胶粘剂			溶剂型胶粘剂
	组分名称	物种类别	贡献率(%)	组分名称	物种类别	贡献率(%)	组分名称	物种类别	贡献率(%)	组分名称	物种类别	贡献率(%)
1	邻苯二甲酸二异辛酯	SVOC	62.84	间二甲苯	VOC	20.23	十一烷	VOC	31.17	2,2,4,6,6-五甲基庚烷	VOC	81.66
2	二乙二醇丁醚	IVOC	27.62	3-乙基甲苯	VOC	16.07	2-甲基癸烷	VOC	30.11	2,2,4,4-四甲基辛烷	VOC	14.20
3	丙二醇丁醚	IVOC	2.70	二乙二醇丁醚	IVOC	13.45	2,2,4,6,6-五甲基庚烷	VOC	29.68	2-乙基己醇	IVOC	4.15
4	十一烷	VOC	1.55	邻二甲苯	VOC	10.74	2,2,4,4-四甲基辛烷	VOC	5.48
5	2-己基-1-癸醇	SVOC	1.10	1,2,3-三甲基苯	VOC	7.58	3-甲基癸烷	VOC	3.56
6	1,1'-[(1-甲基-1,2-乙亚基)二(氧)]二-(2-丙醇)	SVOC	1.03	1,4-二乙基苯	VOC	4.76
7	十三烷	IVOC	0.79	乙二醇丁醚醋酸酯	IVOC	3.90
8	2-乙基己醇	IVOC	0.63	萘	VOC	3.62
9	二丙二醇甲醚	IVOC	0.57	乙苯	VOC	3.12
10	十八烷基乙烯基醚	IVOC	0.51	邻乙基甲苯	VOC	2.56
总计			99.34			86.04			100.00			100.00

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