Article(id=1317114946039697827, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1317114928411034576, articleNumber=null, orderNo=null, doi=10.13355/j.cnki.sfyj.2026.05.016, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1776873600000, receivedDateStr=2026-04-23, revisedDate=1782316800000, revisedDateStr=2026-06-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1791954273947, onlineDateStr=2026-10-14, pubDate=1792425600000, pubDateStr=2026-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791954273947, onlineIssueDateStr=2026-10-14, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791954273947, creator=13701087609, updateTime=1791954273947, updator=13701087609, issue=Issue{id=1317114928411034576, tenantId=1146029695717560320, journalId=1146120122248306696, year='2026', volume='45', issue='5', pageStart='613', pageEnd='782', issueExtLink='null', onlineDate='null', pubDate='1792425600000', pubDateStr='2026-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1791954269745, creator='13701087609', updateTime=1792120411533, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1317811777694450639, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1317114928411034576, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1317811777694450640, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1317114928411034576, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=763, endPage=772, ext={EN=ArticleExt(id=1317114946236830116, articleId=1317114946039697827, tenantId=1146029695717560320, journalId=1146120122248306696, language=EN, title=Classified Recovery and Reuse of Aluminum from Decommissioned Crystalline Silicon Photovoltaic Modules, columnId=1152626641181700664, journalTitle=Hydrometallurgy of China, columnName=Experiment Research, runingTitle=null, highlight=null, articleAbstract=

Aluminum in decommissioned crystalline silicon photovoltaic modules exists in two forms: aluminum frames and aluminum back-surface fields on solar cells, which have significantly different recovery routes. Current technologies face bottlenecks such as complex pretreatment and high environmental load. The classified recovery process was studied. For aluminum frames, temperature-controlled remelting combined with second-phase strengthening technology was used to produce recycled aluminum ingots. For aluminum in solar cells, a citric acid-hydrogen peroxide green chelating leaching system was employed for selective leaching, and the leachate was concentrated, followed by ethanol anti-solvent precipitation to produce aluminum citrate particles. The results show that the remelted aluminum ingots have an average grain size of 162.11 μm and a Vickers hardness of 42.4 HV, meeting the requirements of the national standard (GB/T 1196—2023) standard. The comprehensive processing cost of recycled aluminum is approximately 1.3-2.0 CNY/kg, with energy consumption only 4.86% that of primary aluminum and carbon emissions only 1/24 that of primary aluminum. Orthogonal experiments determined the optimal leaching conditions as follows: reaction temperature 80 ℃, reaction time 5 h, and citric acid concentration 1.5 mol/L. Under the conditions, the leaching rate of aluminum reaches 95.15%. FT-IR characterization confirmed that the product is aluminum citrate, which can be used to prepare crosslinking agents for oilfield profile control and water shutoff. This process does not require deep pretreatment of aluminum frames, avoids the high environmental load of traditional strong acid systems, achieves efficient recovery of aluminum in different forms, and provides a new pathway for the green and large-scale recycling of aluminum from decommissioned photovoltaic modules.

, authors=Zhipeng LIU¹, Danxi ZHAO^{2, 3}, Huichao HE¹, Xinji DING¹, Guoying BAO¹, Shan WANG¹, authorsList=Zhipeng LIU, Danxi ZHAO, Huichao HE, Xinji DING, Guoying BAO, Shan WANG, authorCompany=null, correspAuthors=Shan WANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1317114946735952293, articleId=1317114946039697827, tenantId=1146029695717560320, journalId=1146120122248306696, language=CN, title=退役晶硅光伏组件中铝的分质回收与再利用研究, columnId=1152626641328501305, journalTitle=湿法冶金, columnName=试验研究, runingTitle=null, highlight=null, articleAbstract=

退役晶硅光伏组件中铝以铝边框和电池片铝背场两种形态存在，二者回收路径差异显著，现有技术面临预处理复杂、环境负荷高等瓶颈。研究采用分质回收工艺，对铝边框采用控温重熔结合第二相强化技术制备再生铝锭，对电池片中铝采用枸橼酸-过氧化氢绿色螯合浸出体系进行选择性浸出，浸出液经浓缩、乙醇反溶沉淀后制得枸橼酸铝颗粒。结果表明：重熔铝锭平均晶粒尺寸为162.11 μm，维氏硬度达42.4 HV，满足国标（GB/T 1196—2023）要求；再生铝综合处理成本1.3～2.0元/kg，能耗仅为原生铝的4.86%，碳排放仅为原生铝的1/24。正交试验确定最佳浸出条件为：反应温度80 ℃、反应时间5 h、枸橼酸浓度1.5 mol/L，在该条件下，铝浸出率达95.15%；FT-IR表征结果证实产物为枸橼酸铝，可用于制备油田调剖堵水交联剂。该工艺无须对铝边框深度预处理，避免了传统强酸体系的高环境负荷，实现了不同形态铝的高效回收，为退役光伏组件铝的绿色规模化回收提供了一条新路径。

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刘志鹏（1999—），男，硕士研究生，主要研究方向为光伏组件回收。

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刘志鹏（1999—），男，硕士研究生，主要研究方向为光伏组件回收。

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