Article(id=1311350721560273209, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1311350454089515639, articleNumber=null, orderNo=null, doi=10.13355/j.cnki.sfyj.2026.01.005, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1753632000000, receivedDateStr=2025-07-28, revisedDate=1756051200000, revisedDateStr=2025-08-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1790579975738, onlineDateStr=2026-09-28, pubDate=1771516800000, pubDateStr=2026-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1790579975738, onlineIssueDateStr=2026-09-28, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1790579975738, creator=13701087609, updateTime=1790579975738, updator=13701087609, issue=Issue{id=1311350454089515639, tenantId=1146029695717560320, journalId=1146120122248306696, year='2026', volume='45', issue='1', pageStart='1', pageEnd='128', issueExtLink='null', onlineDate='null', pubDate='1771516800000', pubDateStr='2026-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1790579911968, creator='13701087609', updateTime=1790588535732, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1311386624836071671, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1311350454089515639, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1311386624836071672, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1311350454089515639, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=31, endPage=38, ext={EN=ArticleExt(id=1311350721719656762, articleId=1311350721560273209, tenantId=1146029695717560320, journalId=1146120122248306696, language=EN, title=Synergistic Leaching of Zinc and Germanium from Germanium-rich Zinc Concentrate, columnId=1152626641181700664, journalTitle=Hydrometallurgy of China, columnName=Experiment Research, runingTitle=null, highlight=null, articleAbstract=

The leaching of zinc and germanium from germanium-rich zinc concentrate by oxygen pressure leaching process was studied. The effects of key factors such as the initial acidity of sulfuric acid, reaction temperature, leaching time, oxygen partial pressure, sodium lignosulfonate addition amount, liquid volume to solid mass ratio, and stirring speed on the leaching rates of zinc and germanium were systematically investigated. The optimal process conditions for oxygen pressure leaching are determined through single-factor experiments as follows:leaching temperature is 160 ℃, leaching time is 150 min, initial acidity of sulfuric acid is 160 g/L, partial pressure of oxygen is 1.2 MPa, addition amount of sodium lignosulfonate is 1 g, liquid volume to solid mass ratio is 8/1, and stirring speed is 600 r/min. Under the conditions, the germanium leaching rate reaches 94.86% and the zinc leaching rate reaches 99.98%. Compared with the traditional atmospheric pressure leaching, the optimized oxygen pressure process can increase the germanium leaching rate by more than 15%, shorten the leaching time by 40%, and also avoid the emission of high-concentration H2S gas, reducing environmental pollution and providing a technical reference for the comprehensive utilization of valuable elements in zinc concentrate.

, authors=Zhichao FENG1, Peiyan PANG2, Xuexian JIANG2, Guixiang HE2, Jierong ZHOU2, Zhonglin LI1, Yibing LI1, authorsList=Zhichao FENG, Peiyan PANG, Xuexian JIANG, Guixiang HE, Jierong ZHOU, Zhonglin LI, Yibing LI, authorCompany=null, correspAuthors=Guixiang HE, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1311350722000675131, articleId=1311350721560273209, tenantId=1146029695717560320, journalId=1146120122248306696, language=CN, title=富锗锌精矿协同浸出锌锗工艺研究, columnId=1152626641328501305, journalTitle=湿法冶金, columnName=试验研究, runingTitle=null, highlight=null, articleAbstract=

研究了采用氧压浸出工艺从富锗锌精矿中浸出锌、锗,系统考察了硫酸初始酸度、反应温度、浸出时间、氧分压、木质素磺酸钠添加量、液固体积质量比、搅拌速度等关键因素对锌、锗浸出率的影响。通过单因素试验优化确定氧压浸出最佳工艺条件为:浸出温度160 ℃、浸出时间150 min、硫酸初始酸度160 g/L、氧分压1.2 MPa、木质素磺酸钠添加量1 g、液固体积质量比8/1、搅拌速度600 r/min,该条件下锗浸出率达94.86%,锌浸出率达99.98%。与传统常压浸出相比,优化后的氧压工艺锗浸出率可提升15%以上,浸出时间缩短40%,还可避免高浓度H2S气体排放,减少对环境的污染,可为实现锌精矿中有价元素的综合利用提供技术参考。

, authors=俸智超1, 庞沛彦2, 蒋学先2, 何贵香2, 周街荣2, 李中林1, 李义兵1, authorsList=俸智超, 庞沛彦, 蒋学先, 何贵香, 周街荣, 李中林, 李义兵, authorCompany=null, correspAuthors=何贵香, authorNote=

俸智超(1999—),男,硕士研究生,主要研究方向为有色金属冶炼。

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何贵香(1973—),女,博士,教授,主要研究方向为有色金属冶炼。E-mail:。
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俸智超(1999—),男,硕士研究生,主要研究方向为有色金属冶炼。

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富锗锌精矿协同浸出锌锗工艺研究
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俸智超 1 , 庞沛彦 2 , 蒋学先 2 , 何贵香 2 , 周街荣 2 , 李中林 1 , 李义兵 1
湿法冶金 | 试验研究 2026,45(1): 31-38
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湿法冶金 |试验研究 2026 , 45 (1) : 31 -38
富锗锌精矿协同浸出锌锗工艺研究
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俸智超1, 庞沛彦2, 蒋学先2, 何贵香2 , 周街荣2, 李中林1, 李义兵1
作者信息
  • 1.桂林理工大学 材料科学与工程学院,广西 桂林 541004
  • 2.桂林理工大学南宁分校 冶金与资源工程学院,广西 南宁 530001
通讯作者:
何贵香(1973—),女,博士,教授,主要研究方向为有色金属冶炼。E-mail:。
作者简介:

俸智超(1999—),男,硕士研究生,主要研究方向为有色金属冶炼。

Synergistic Leaching of Zinc and Germanium from Germanium-rich Zinc Concentrate
Zhichao FENG1, Peiyan PANG2, Xuexian JIANG2, Guixiang HE2 , Jierong ZHOU2, Zhonglin LI1, Yibing LI1
Affiliations
  • 1.College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China
  • 2.College of Metallurgical and Resources Engineering, Guilin University of Technology at Nanning, Nanning 530001, China
出版时间: 2026-02-20 doi: 10.13355/j.cnki.sfyj.2026.01.005
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研究了采用氧压浸出工艺从富锗锌精矿中浸出锌、锗,系统考察了硫酸初始酸度、反应温度、浸出时间、氧分压、木质素磺酸钠添加量、液固体积质量比、搅拌速度等关键因素对锌、锗浸出率的影响。通过单因素试验优化确定氧压浸出最佳工艺条件为:浸出温度160 ℃、浸出时间150 min、硫酸初始酸度160 g/L、氧分压1.2 MPa、木质素磺酸钠添加量1 g、液固体积质量比8/1、搅拌速度600 r/min,该条件下锗浸出率达94.86%,锌浸出率达99.98%。与传统常压浸出相比,优化后的氧压工艺锗浸出率可提升15%以上,浸出时间缩短40%,还可避免高浓度H2S气体排放,减少对环境的污染,可为实现锌精矿中有价元素的综合利用提供技术参考。

富锗锌精矿  /  氧压浸出  /  锌  /  锗  /  硫酸

The leaching of zinc and germanium from germanium-rich zinc concentrate by oxygen pressure leaching process was studied. The effects of key factors such as the initial acidity of sulfuric acid, reaction temperature, leaching time, oxygen partial pressure, sodium lignosulfonate addition amount, liquid volume to solid mass ratio, and stirring speed on the leaching rates of zinc and germanium were systematically investigated. The optimal process conditions for oxygen pressure leaching are determined through single-factor experiments as follows:leaching temperature is 160 ℃, leaching time is 150 min, initial acidity of sulfuric acid is 160 g/L, partial pressure of oxygen is 1.2 MPa, addition amount of sodium lignosulfonate is 1 g, liquid volume to solid mass ratio is 8/1, and stirring speed is 600 r/min. Under the conditions, the germanium leaching rate reaches 94.86% and the zinc leaching rate reaches 99.98%. Compared with the traditional atmospheric pressure leaching, the optimized oxygen pressure process can increase the germanium leaching rate by more than 15%, shorten the leaching time by 40%, and also avoid the emission of high-concentration H2S gas, reducing environmental pollution and providing a technical reference for the comprehensive utilization of valuable elements in zinc concentrate.

germanium-rich zinc concentrate  /  oxygen pressure leaching  /  zinc  /  germanium  /  sulfuric acid
俸智超, 庞沛彦, 蒋学先, 何贵香, 周街荣, 李中林, 李义兵. 富锗锌精矿协同浸出锌锗工艺研究. 湿法冶金, 2026 , 45 (1) : 31 -38 . DOI: 10.13355/j.cnki.sfyj.2026.01.005
Zhichao FENG, Peiyan PANG, Xuexian JIANG, Guixiang HE, Jierong ZHOU, Zhonglin LI, Yibing LI. Synergistic Leaching of Zinc and Germanium from Germanium-rich Zinc Concentrate[J]. Hydrometallurgy of China, 2026 , 45 (1) : 31 -38 . DOI: 10.13355/j.cnki.sfyj.2026.01.005
  • 广西自然科学基金(2025GXNSFAA069249)
  • 中央引导地方科技发展资金项目(桂科ZY24212040)
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2026年第45卷第1期
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doi: 10.13355/j.cnki.sfyj.2026.01.005
  • 接收时间:2025-07-28
  • 首发时间:2026-09-28
  • 出版时间:2026-02-20
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  • 收稿日期:2025-07-28
  • 修回日期:2025-08-25
基金
广西自然科学基金(2025GXNSFAA069249)
中央引导地方科技发展资金项目(桂科ZY24212040)
作者信息
    1.桂林理工大学 材料科学与工程学院,广西 桂林 541004
    2.桂林理工大学南宁分校 冶金与资源工程学院,广西 南宁 530001

通讯作者:

何贵香(1973—),女,博士,教授,主要研究方向为有色金属冶炼。E-mail:。
参考文献
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https://castjournals.cast.org.cn/joweb/sfyj/CN/10.13355/j.cnki.sfyj.2026.01.005
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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