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As one of the globally strategic critical metals, rhenium often exists in copper ores in an associated form. Copper smelting waste acid, an important carrier of rhenium resources, exhibits complex characteristics including high acidity, high impurity content, and low rhenium concentration. The characteristics pose formidable challenges to the rhenium recovery process. The key technologies for rhenium recovery from waste acid, with a particular emphasis on the progress of advanced purification technologies targeting the leaching solution are systematically summarized. The working principles, process optimization approaches, and industrial application effectiveness of solvent extraction and ion exchange methods are analyzed in depth. Moreover, the differentiated technical routes for leaching solution purification employed by major copper smelting enterprises worldwide are compared. Based on this, the key technical bottlenecks and potential breakthroughs for future development in this field are explored from multiple perspectives, including innovation of separation materials, process intensification, process integration, and secondary pollution control. The aim is to offer in-depth theoretical references and practical guidelines for the efficient, environmentally friendly, and high-value recovery of rhenium resources from waste acid.
, authors=Guolong XU
1, 2, 3, Aifei YI
2, 4, Ye TIAN
1, Yuan YUAN
1, Chong ZHANG
1, Mingqian CAO
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铼作为全球性战略性关键金属之一,常以伴生形式存在于铜矿中。而铜冶炼污酸作为铼资源的重要载体,具有高酸、高杂质、低铼浓度的复杂特性,给铼回收工艺带来了严峻挑战。系统梳理了从污酸中回收铼的关键技术,并着重介绍了以浸出液为核心对象的深度提纯技术进展。深入剖析了溶剂萃取法与离子交换法的工作原理、工艺优化路径及其工业应用实效,对比了全球主要铜冶炼企业基于浸出液提纯的差异化技术路线。并在此基础上,从分离材料创新、过程强化、工艺集成及二次污染控制等多个维度,探讨了该领域未来发展的关键技术瓶颈与突破口,旨在为实现污酸中铼资源的高效、绿色、高值化回收提供深入的理论参考与实践指引。
, authors=胥国龙
1, 2, 3, 易爱飞
2, 4, 田野
1, 原渊
1, 张翀
1, 曹鸣谦
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