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In order to efficiently enrich indium (In) in zinc oxide dust and realize the directional separation and recovery of associated elements, Zn, Fe, Pb and In were leached from the dust by choline chloride-oxalate dihydrate low eutectic solvent, and the “hydrolytic removal of zinc and lead-ultraviolet light reduction iron removal” process was used to remove impurities step by step. The results show that the leaching rates of Zn, In, Pb and Fe can reach 95.52%, 88.91%, 80.82% and 89.13%, respectively, under the optimal leaching conditions of liquid volume to solid mass ratio of 12 mL/1 g, temperature of 70 ℃ and time of 6 h. Zn/Pb is removed by hydrolytic precipitation, and then Fe is removed by ultraviolet reduction precipitation. After the step-by-step precipitation and impurity removal treatment, the mass fraction of indium in the solution has increased from 0.03% to 1.5%, successfully achieving efficient enrichment of indium and directional separation and recovery of associated elements such as Zn, Pb, and Fe.

, authors=Liangjin ZHANG1, 2, Yongzhi LIU1, 3, Qiyuan YU1, 3, Yue LONG1, 3, Yuzhu ZHANG1, 3, authorsList=Liangjin ZHANG, Yongzhi LIU, Qiyuan YU, Yue LONG, Yuzhu ZHANG, authorCompany=null, correspAuthors=Yuzhu ZHANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1311350617923220329, articleId=1311350617445069671, tenantId=1146029695717560320, journalId=1146120122248306696, language=CN, title=用氯化胆碱-草酸从次氧化锌粉尘中梯级分离铟及伴生元素, columnId=1152626641328501305, journalTitle=湿法冶金, columnName=试验研究, runingTitle=null, highlight=null, articleAbstract=

为高效富集次氧化锌粉尘中的铟并实现伴生元素的定向分离回收,研究采用氯化胆碱-草酸二水合物低共熔溶剂浸出粉尘中的Zn、Fe、Pb、In,并结合“水解脱锌铅—紫外光还原除铁”工艺进行分步除杂。结果表明:在液固体积质量比12 mL/1 g、温度 70 ℃、时间 6 h的优化浸出条件下,Zn、In、Pb、Fe浸出率分别达95.52%、88.91%、80.82% 和89.13%;浸出液通过水解沉淀可脱除Zn/Pb,再经紫外光还原沉淀可脱除Fe;经此分步沉淀除杂处理后,溶液中In质量分数由0.03%提升至1.5%,能成功实现铟的高效富集,以及Zn、Pb、Fe等伴生元素的定向分离回收。

, authors=张良进1, 2, 刘勇志1, 3, 于奇元1, 3, 龙跃1, 3, 张玉柱1, 3, authorsList=张良进, 刘勇志, 于奇元, 龙跃, 张玉柱, authorCompany=null, correspAuthors=张玉柱, authorNote=

张良进(1990—),男,博士研究生,主要研究方向为冶金固废资源化利用。

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张玉柱(1956—),男,博士,教授,主要研究方向为冶金节能与资源优化。E-mail:。
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张良进(1990—),男,博士研究生,主要研究方向为冶金固废资源化利用。

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张良进(1990—),男,博士研究生,主要研究方向为冶金固废资源化利用。

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用氯化胆碱-草酸从次氧化锌粉尘中梯级分离铟及伴生元素
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张良进 1, 2 , 刘勇志 1, 3 , 于奇元 1, 3 , 龙跃 1, 3 , 张玉柱 1, 3
湿法冶金 | 试验研究 2026,45(1): 52-57
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湿法冶金 |试验研究 2026 , 45 (1) : 52 -57
用氯化胆碱-草酸从次氧化锌粉尘中梯级分离铟及伴生元素
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张良进(1990—),男,博士研究生,主要研究方向为冶金固废资源化利用。

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张良进1, 2, 刘勇志1, 3, 于奇元1, 3, 龙跃1, 3, 张玉柱1, 3
作者信息
  • 1.华北理工大学 冶金与能源学院,河北 唐山 063210
  • 2.中冶检测认证有限公司,北京 100088
  • 3.华北理工大学 现代冶金技术教育部重点实验室,河北 唐山 063210
通讯作者:
张玉柱(1956—),男,博士,教授,主要研究方向为冶金节能与资源优化。E-mail:。
作者简介:

张良进(1990—),男,博士研究生,主要研究方向为冶金固废资源化利用。

Step-up Separation of Indium and Associated Elements from Zinc Oxide Dust Using Choline-Oxalic Acid Chloride
Liangjin ZHANG1, 2, Yongzhi LIU1, 3, Qiyuan YU1, 3, Yue LONG1, 3, Yuzhu ZHANG1, 3
Affiliations
  • 1.School of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063210, China
  • 2.Inspection and Certification Co., Ltd., MCC, Beijing 100088, China
  • 3.Key Laboratory of Modern Metallurgical Technology, Ministry of Education, North China University of Science and Technology, Tangshan 063210, China
出版时间: 2026-02-20 doi: 10.13355/j.cnki.sfyj.2026.01.008
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为高效富集次氧化锌粉尘中的铟并实现伴生元素的定向分离回收,研究采用氯化胆碱-草酸二水合物低共熔溶剂浸出粉尘中的Zn、Fe、Pb、In,并结合“水解脱锌铅—紫外光还原除铁”工艺进行分步除杂。结果表明:在液固体积质量比12 mL/1 g、温度 70 ℃、时间 6 h的优化浸出条件下,Zn、In、Pb、Fe浸出率分别达95.52%、88.91%、80.82% 和89.13%;浸出液通过水解沉淀可脱除Zn/Pb,再经紫外光还原沉淀可脱除Fe;经此分步沉淀除杂处理后,溶液中In质量分数由0.03%提升至1.5%,能成功实现铟的高效富集,以及Zn、Pb、Fe等伴生元素的定向分离回收。

低共熔溶剂  /  次氧化锌粉尘  /  铟  /  梯级提取  /  浸出  /  分离  /  回收

In order to efficiently enrich indium (In) in zinc oxide dust and realize the directional separation and recovery of associated elements, Zn, Fe, Pb and In were leached from the dust by choline chloride-oxalate dihydrate low eutectic solvent, and the “hydrolytic removal of zinc and lead-ultraviolet light reduction iron removal” process was used to remove impurities step by step. The results show that the leaching rates of Zn, In, Pb and Fe can reach 95.52%, 88.91%, 80.82% and 89.13%, respectively, under the optimal leaching conditions of liquid volume to solid mass ratio of 12 mL/1 g, temperature of 70 ℃ and time of 6 h. Zn/Pb is removed by hydrolytic precipitation, and then Fe is removed by ultraviolet reduction precipitation. After the step-by-step precipitation and impurity removal treatment, the mass fraction of indium in the solution has increased from 0.03% to 1.5%, successfully achieving efficient enrichment of indium and directional separation and recovery of associated elements such as Zn, Pb, and Fe.

deep eutectic solvent  /  zinc oxide dust  /  indium  /  cascade extraction  /  leaching  /  separation  /  recovery
张良进, 刘勇志, 于奇元, 龙跃, 张玉柱. 用氯化胆碱-草酸从次氧化锌粉尘中梯级分离铟及伴生元素. 湿法冶金, 2026 , 45 (1) : 52 -57 . DOI: 10.13355/j.cnki.sfyj.2026.01.008
Liangjin ZHANG, Yongzhi LIU, Qiyuan YU, Yue LONG, Yuzhu ZHANG. Step-up Separation of Indium and Associated Elements from Zinc Oxide Dust Using Choline-Oxalic Acid Chloride[J]. Hydrometallurgy of China, 2026 , 45 (1) : 52 -57 . DOI: 10.13355/j.cnki.sfyj.2026.01.008
  • 国家自然科学基金区域创新发展联合基金资助项目(U20A20271)
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2026年第45卷第1期
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doi: 10.13355/j.cnki.sfyj.2026.01.008
  • 接收时间:2025-05-12
  • 首发时间:2026-09-28
  • 出版时间:2026-02-20
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  • 收稿日期:2025-05-12
  • 修回日期:2025-08-17
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国家自然科学基金区域创新发展联合基金资助项目(U20A20271)
作者信息
    1.华北理工大学 冶金与能源学院,河北 唐山 063210
    2.中冶检测认证有限公司,北京 100088
    3.华北理工大学 现代冶金技术教育部重点实验室,河北 唐山 063210

通讯作者:

张玉柱(1956—),男,博士,教授,主要研究方向为冶金节能与资源优化。E-mail:。
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2种不同金属材料的力学参数
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total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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