Article(id=1311349780568170643, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1311349772552859828, articleNumber=null, orderNo=null, doi=10.13355/j.cnki.sfyj.2025.06.006, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1751299200000, receivedDateStr=2025-07-01, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1790579751388, onlineDateStr=2026-09-28, pubDate=1766160000000, pubDateStr=2025-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1790579751388, onlineIssueDateStr=2026-09-28, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1790579751388, creator=13701087609, updateTime=1790579751388, updator=13701087609, issue=Issue{id=1311349772552859828, tenantId=1146029695717560320, journalId=1146120122248306696, year='2025', volume='44', issue='6', pageStart='707', pageEnd='838', issueExtLink='null', onlineDate='null', pubDate='1766160000000', pubDateStr='2025-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1790579749477, creator='13701087609', updateTime=1790588567303, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1311386757267022261, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1311349772552859828, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1311386757267022262, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1311349772552859828, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=749, endPage=758, ext={EN=ArticleExt(id=1311349780782080148, articleId=1311349780568170643, tenantId=1146029695717560320, journalId=1146120122248306696, language=EN, title=Adsorption of Se(Ⅳ) with Feldspar, Illite and Kaolin, columnId=1152626641181700664, journalTitle=Hydrometallurgy of China, columnName=Experiment Research, runingTitle=null, highlight=null, articleAbstract=

In the geological disposal of high-level radioactive waste, the mineral composition of surrounding rock and buffer materials is complex. Therefore, research is conducted from the perspective of rock composition to simplify research process of nuclide migration in geological media. The adsorption behavior of common minerals such as feldspar, illite and kaolinite on Se(Ⅳ) in granite, clay rock and bentonite was studied through batch experiments. The results show that under different conditions such as contact time, solution pH, ionic strength, initial mass concentration of Se(Ⅳ), solid mass to liquid volume ratio and temperature, the variation laws of the adsorption rates of Se(Ⅳ) by the three minerals are consistent, while the adsorption capacity of illite for Se(Ⅳ) is slightly higher than that of the other two minerals. The adsorption processes of Se(Ⅳ) by the three minerals all follow the pseudo-second-order kinetic model, which conforms to the Freundlich isotherm model, and the adsorption process is a spontaneous endothermic reaction. It is found through SEM, XRD and FT-IR characterization that there are no obvious changes in the three minerals before and after the adsorption of Se(Ⅳ).

, authors=Hui ZHANG^{1, 2, 3}, Ju WANG^{1, 2}, Zhichao ZHOU^{1, 2}, Hui LING^{1, 2}, authorsList=Hui ZHANG, Ju WANG, Zhichao ZHOU, Hui LING, authorCompany=null, correspAuthors=Ju WANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1311349781092458645, articleId=1311349780568170643, tenantId=1146029695717560320, journalId=1146120122248306696, language=CN, title=长石、伊利石和高岭土对Se（Ⅳ）的吸附试验研究, columnId=1152626641328501305, journalTitle=湿法冶金, columnName=试验研究, runingTitle=null, highlight=null, articleAbstract=

在高放废物地质处置中，围岩和缓冲材料的矿物组成较复杂，因此选择从岩石组成开展研究，以简化核素在岩石中迁移的研究过程。通过批次试验研究了花岗岩、黏土岩和膨润土中的常见矿物长石、伊利石和高岭土对Se（Ⅳ）的吸附行为。结果表明：在不同接触时间、溶液pH、离子强度、Se（Ⅳ）初始质量浓度、固液质量体积比和温度等条件下，3种矿物对Se（Ⅳ）的吸附率的影响变化规律一致，而伊利石对Se（Ⅳ）的吸附能力略高于其他2种矿物；3种矿物对Se（Ⅳ）的吸附过程均遵循拟二级动力学模型，符合Freundlich等温线模型，吸附过程为自发吸热反应；通过SEM、XRD和FT-IR表征发现，3种矿物吸附Se（Ⅳ）前、后没有明显变化。

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张慧（1981—），女，博士，工程师，主要研究方向为高放废物地质处置。

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张慧（1981—），女，博士，工程师，主要研究方向为高放废物地质处置。

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