Article(id=1308543983526183239, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1308543982137860950, articleNumber=null, orderNo=null, doi=10.13355/j.cnki.sfyj.2025.05.007, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1743868800000, receivedDateStr=2025-04-06, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1789910797242, onlineDateStr=2026-09-20, pubDate=1760889600000, pubDateStr=2025-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1789910797242, onlineIssueDateStr=2026-09-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1789910797242, creator=13701087609, updateTime=1789910797242, updator=13701087609, issue=Issue{id=1308543982137860950, tenantId=1146029695717560320, journalId=1146120122248306696, year='2025', volume='44', issue='5', pageStart='583', pageEnd='705', issueExtLink='null', onlineDate='null', pubDate='1760889600000', pubDateStr='2025-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1789910796911, creator='13701087609', updateTime=1789955335202, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1308730789341266049, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1308543982137860950, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1308730789341266050, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1308543982137860950, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=626, endPage=634, ext={EN=ArticleExt(id=1308543983962390856, articleId=1308543983526183239, tenantId=1146029695717560320, journalId=1146120122248306696, language=EN, title=Preparation of Fe and F Co-doped Manganese Ion Sieve and Its Adsorption Performance for Lithium, columnId=1152626641181700664, journalTitle=Hydrometallurgy of China, columnName=Experiment Research, runingTitle=null, highlight=null, articleAbstract=

Iron and fluorine co-doped manganese ion sieve HMFeO-F was prepared by high temperature solid phase method. The effects of calcination temperature, calcination time and doping ratio on the structure of the ion sieve were investigated by XRD, SEM, FT-IR and BET, and its adsorption performance was studied. The results show that the adsorption capacity for lithium of HMFeO-F is 31.57 mg/g under the conditions of calcination temperature of 800 ℃, calcination time of 10 h, molar ratio of lithium to manganese of 1/2, and doping mole fractions of Fe and F of 5% and 10%, respectively. The Mn dissolution loss rate during the adsorption process is only 4.52%, which is 61% lower than that of the undoped. At the same time, the introduction of magnetic Fe3O4 makes the magnetic recovery rate of the material can reach 90.2%. After five cycles of tests, the equilibrium adsorption capacity for lithium of HMFeO-F can still reach 25.87 mg/g, and the manganese dissolution loss rate remains within 5%. For a coal gangue acid leaching solution with a lithium mass concentration of 12.98 mg/L, lithium is adsorbed by HMFeO-F, and the lithium adsorption rate can reach 99%. The use of ion sieve to extract lithium from coal gangue can not only develop a new way to extract lithium, but also is expected to achieve the high-value utilization of coal gangue.

, authors=Wenpeng XIE, Suling YAO, Yuanpeng FU, Xianshu DONG, authorsList=Wenpeng XIE, Suling YAO, Yuanpeng FU, Xianshu DONG, authorCompany=null, correspAuthors=Suling YAO, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1308543984402792777, articleId=1308543983526183239, tenantId=1146029695717560320, journalId=1146120122248306696, language=CN, title=铁氟共掺杂锰系离子筛的制备及其对锂的吸附性能研究, columnId=1152626641328501305, journalTitle=湿法冶金, columnName=试验研究, runingTitle=null, highlight=null, articleAbstract=

研究了采用高温固相法制备Fe/F共掺杂锰系离子筛HMFeO-F,通过XRD、SEM、FT-IR、BET等手段考察了煅烧温度、煅烧时间和掺杂配比对离子筛结构的影响,并探讨了其对锂的吸附性能。结果表明:在煅烧温度800 ℃、煅烧时间10 h、锂锰物质的量比1/2、Fe、F掺杂摩尔分数分别为5%、10%条件下,HMFeO-F对锂的吸附容量为31.57 mg/g,吸附过程中锰溶损率仅为4.52%,相较于未掺杂时降低61%,同时磁性Fe3O4的引入使材料磁回收率达90.2%;经过5次循环试验后,HMFeO-F的平衡吸附容量仍可达25.87 mg/g,锰溶损率保持在5%以内;针对锂质量浓度为12.98 mg/L的某煤矸石酸浸液,用HMFeO-F吸附锂,锂吸附率可达99%。采用该离子筛提取煤矸石中的锂不仅为提锂提供了一种新的途径,而且有望实现煤矸石的高值化利用。

, authors=解文鹏, 姚素玲, 付元鹏, 董宪姝, authorsList=解文鹏, 姚素玲, 付元鹏, 董宪姝, authorCompany=null, correspAuthors=姚素玲, authorNote=

解文鹏(1991—),男,硕士研究生,工程师,主要研究方向为煤炭固废综合利用。

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姚素玲(1969—),女,博士,副教授,主要研究方向为煤炭综合利用。E-mail: 。
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解文鹏(1991—),男,硕士研究生,工程师,主要研究方向为煤炭固废综合利用。

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铁氟共掺杂锰系离子筛的制备及其对锂的吸附性能研究
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解文鹏 , 姚素玲 , 付元鹏 , 董宪姝
湿法冶金 | 试验研究 2025,44(5): 626-634
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湿法冶金 |试验研究 2025 , 44 (5) : 626 -634
铁氟共掺杂锰系离子筛的制备及其对锂的吸附性能研究
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解文鹏, 姚素玲 , 付元鹏, 董宪姝
作者信息
  • 太原理工大学 矿业工程学院,山西 太原 030024
通讯作者:
姚素玲(1969—),女,博士,副教授,主要研究方向为煤炭综合利用。E-mail: 。
作者简介:

解文鹏(1991—),男,硕士研究生,工程师,主要研究方向为煤炭固废综合利用。

Preparation of Fe and F Co-doped Manganese Ion Sieve and Its Adsorption Performance for Lithium
Wenpeng XIE, Suling YAO , Yuanpeng FU, Xianshu DONG
Affiliations
  • College of Mining Engineering, Taiyuan University of Technology, Taiyuan 030024, China
出版时间: 2025-10-20 doi: 10.13355/j.cnki.sfyj.2025.05.007
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研究了采用高温固相法制备Fe/F共掺杂锰系离子筛HMFeO-F,通过XRD、SEM、FT-IR、BET等手段考察了煅烧温度、煅烧时间和掺杂配比对离子筛结构的影响,并探讨了其对锂的吸附性能。结果表明:在煅烧温度800 ℃、煅烧时间10 h、锂锰物质的量比1/2、Fe、F掺杂摩尔分数分别为5%、10%条件下,HMFeO-F对锂的吸附容量为31.57 mg/g,吸附过程中锰溶损率仅为4.52%,相较于未掺杂时降低61%,同时磁性Fe3O4的引入使材料磁回收率达90.2%;经过5次循环试验后,HMFeO-F的平衡吸附容量仍可达25.87 mg/g,锰溶损率保持在5%以内;针对锂质量浓度为12.98 mg/L的某煤矸石酸浸液,用HMFeO-F吸附锂,锂吸附率可达99%。采用该离子筛提取煤矸石中的锂不仅为提锂提供了一种新的途径,而且有望实现煤矸石的高值化利用。

煤矸石酸浸液  /  锰系锂离子筛  /  铁氟共掺杂  /  锂  /  吸附

Iron and fluorine co-doped manganese ion sieve HMFeO-F was prepared by high temperature solid phase method. The effects of calcination temperature, calcination time and doping ratio on the structure of the ion sieve were investigated by XRD, SEM, FT-IR and BET, and its adsorption performance was studied. The results show that the adsorption capacity for lithium of HMFeO-F is 31.57 mg/g under the conditions of calcination temperature of 800 ℃, calcination time of 10 h, molar ratio of lithium to manganese of 1/2, and doping mole fractions of Fe and F of 5% and 10%, respectively. The Mn dissolution loss rate during the adsorption process is only 4.52%, which is 61% lower than that of the undoped. At the same time, the introduction of magnetic Fe3O4 makes the magnetic recovery rate of the material can reach 90.2%. After five cycles of tests, the equilibrium adsorption capacity for lithium of HMFeO-F can still reach 25.87 mg/g, and the manganese dissolution loss rate remains within 5%. For a coal gangue acid leaching solution with a lithium mass concentration of 12.98 mg/L, lithium is adsorbed by HMFeO-F, and the lithium adsorption rate can reach 99%. The use of ion sieve to extract lithium from coal gangue can not only develop a new way to extract lithium, but also is expected to achieve the high-value utilization of coal gangue.

coal gangue acid leaching solution  /  manganese series lithium ion sieve  /  Fe and F co-doping  /  lithium  /  adsorption
解文鹏, 姚素玲, 付元鹏, 董宪姝. 铁氟共掺杂锰系离子筛的制备及其对锂的吸附性能研究. 湿法冶金, 2025 , 44 (5) : 626 -634 . DOI: 10.13355/j.cnki.sfyj.2025.05.007
Wenpeng XIE, Suling YAO, Yuanpeng FU, Xianshu DONG. Preparation of Fe and F Co-doped Manganese Ion Sieve and Its Adsorption Performance for Lithium[J]. Hydrometallurgy of China, 2025 , 44 (5) : 626 -634 . DOI: 10.13355/j.cnki.sfyj.2025.05.007
  • 国家自然科学基金青年基金项目(52504303)
  • 山西省重点研发计划项目(202202090301009)
  • 山西省基础研究计划项目(202103021223045)
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2025年第44卷第5期
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文章信息
doi: 10.13355/j.cnki.sfyj.2025.05.007
  • 接收时间:2025-04-06
  • 首发时间:2026-09-20
  • 出版时间:2025-10-20
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  • 收稿日期:2025-04-06
基金
国家自然科学基金青年基金项目(52504303)
山西省重点研发计划项目(202202090301009)
山西省基础研究计划项目(202103021223045)
作者信息
    太原理工大学 矿业工程学院,山西 太原 030024

通讯作者:

姚素玲(1969—),女,博士,副教授,主要研究方向为煤炭综合利用。E-mail: 。
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https://castjournals.cast.org.cn/joweb/sfyj/CN/10.13355/j.cnki.sfyj.2025.05.007
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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