Article(id=1305178410590957924, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1305178373467169689, articleNumber=null, orderNo=null, doi=10.13355/j.cnki.sfyj.2026.03.014, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1773763200000, receivedDateStr=2026-03-18, revisedDate=1775664000000, revisedDateStr=2026-04-09, acceptedDate=null, acceptedDateStr=null, onlineDate=1789108382127, onlineDateStr=2026-09-11, pubDate=1781884800000, pubDateStr=2026-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1789108382127, onlineIssueDateStr=2026-09-11, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1789108382127, creator=13701087609, updateTime=1789108382127, updator=13701087609, issue=Issue{id=1305178373467169689, tenantId=1146029695717560320, journalId=1146120122248306696, year='2026', volume='45', issue='3', pageStart='273', pageEnd='454', issueExtLink='null', onlineDate='null', pubDate='1781884800000', pubDateStr='2026-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1789108373275, creator='13701087609', updateTime=1789108489171, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1305178859612168540, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1305178373467169689, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1305178859612168541, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1305178373467169689, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=392, endPage=398, ext={EN=ArticleExt(id=1305178410800673125, articleId=1305178410590957924, tenantId=1146029695717560320, journalId=1146120122248306696, language=EN, title=Process and Kinetics of P204 Synergistic Extraction of Uranium in Phosphoric Acid Medium, columnId=1152626641181700664, journalTitle=Hydrometallurgy of China, columnName=Experiment Research, runingTitle=null, highlight=null, articleAbstract=

A P204-TOPO-sulfonated kerosene synergistic extraction-Fe(Ⅱ) reduction stripping system was constructed. The effects of extraction reaction time, phosphoric acid concentration, extraction temperature, amount of iron powder and stripping temperature were investigated, and the optimal process conditions were determined. The results show that the extraction-stripping of uranium conforms to the law of diffusion control-in-phase reaction. The apparent activation energy of the extraction reaction is 34.76 kJ/mol, and that of the stripping reaction is 40.289 kJ/mol. The system is controlled by both mass transfer and chemical reaction. The optimal extraction conditions are room temperature, extraction time of 6 min, phosphoric acid concentration of 3.5 mol/L, and V_O/V_A=1/5. The optimal stripping conditions are temperature of 323.15 K, stripping time of 10 min, phosphoric acid concentration of 5 mol/L, reduced iron powder amount of 10 times the theoretical amount, and V_O/V_A=5/1. Under the optimal conditions, the uranium extraction rate is 96% and the stripping rate is 81.3%.

, authors=Jiayu ZHANG, Yuqing NIU, Shaohui KANG, Kaikai YE, Yan REN, Linghua CAO, Zhiquan ZHOU, Haonan SHEN, authorsList=Jiayu ZHANG, Yuqing NIU, Shaohui KANG, Kaikai YE, Yan REN, Linghua CAO, Zhiquan ZHOU, Haonan SHEN, authorCompany=null, correspAuthors=Yuqing NIU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1305178411035554150, articleId=1305178410590957924, tenantId=1146029695717560320, journalId=1146120122248306696, language=CN, title=P204协同萃取磷酸介质中铀的工艺与动力学, columnId=1152626641328501305, journalTitle=湿法冶金, columnName=试验研究, runingTitle=null, highlight=null, articleAbstract=

为从磷块岩制备磷酸所得溶液中，以副产品形式回收铀，研究构建了P204+TOPO-磺化煤油协同萃取-Fe（Ⅱ）还原反萃体系，考察了萃取反应时间、磷酸浓度、萃取温度及反萃取还原铁粉用量、反萃取温度等因素的影响，确定了最优工艺条件。结果表明：铀的萃取-反萃取符合扩散控制-相内反应规律，萃取反应表观活化能为34.76 kJ/mol，反萃取反应表观活化能为40.289 kJ/mol，体系同时受到传质与化学反应控制；最优萃取条件为室温，萃取时间6 min，磷酸浓度3.5 mol/L，V_O/V_A=1/5；最优反萃取条件为温度323.15 K，反萃取时间10 min，磷酸浓度5 mol/L，还原铁粉用量为理论用量的10倍，V_O/V_A=5/1；在最优条件下，铀萃取率为96%，反萃取率为81.3%。

, authors=张佳宇, 牛玉清, 康绍辉, 叶开凯, 任燕, 曹令华, 周志全, 申浩楠, authorsList=张佳宇, 牛玉清, 康绍辉, 叶开凯, 任燕, 曹令华, 周志全, 申浩楠, authorCompany=null, correspAuthors=牛玉清, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=gPSypreilB6L4JjKI1e14g==, magXml=hnsaTz6pDCuCYmofprVxlQ==, pdfUrl=null, pdf=Wu2L4Glq1AQyPZdAO+NSow==, pdfFileSize=1152530, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=WvsxQFlSEkWGuk8Oi/8daw==, mapNumber=null, fund=null)}, authors=[Author(id=1305178411333349739, tenantId=1146029695717560320, journalId=1146120122248306696, articleId=1305178410590957924, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1305178411413041517, tenantId=1146029695717560320, journalId=1146120122248306696, articleId=1305178410590957924, authorId=1305178411333349739, language=EN, stringName=Jiayu ZHANG, firstName=Jiayu, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=Beijing Research Institute of Chemical Engineering and Metallurgy, CNNC, Beijing　101149, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1305178413069791598, tenantId=1146029695717560320, journalId=1146120122248306696, articleId=1305178410590957924, authorId=1305178411333349739, language=CN, stringName=张佳宇, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=核工业北京化工冶金研究院，北京　101149, bio={"content":"

张佳宇（1996—），男，硕士，工程师，主要研究方向为铀纯化转化。

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张佳宇（1996—），男，硕士，工程师，主要研究方向为铀纯化转化。

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