Article(id=1172617834585797389, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1172617833407197957, articleNumber=1009-2617(2024)05-0473-10, orderNo=null, doi=10.13355/j.cnki.sfyj.2024.05.001, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1715270400000, receivedDateStr=2024-05-10, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1757503477951, onlineDateStr=2025-09-10, pubDate=1729353600000, pubDateStr=2024-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1757503477951, onlineIssueDateStr=2025-09-10, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1757503477951, creator=13701087609, updateTime=1757503477951, updator=13701087609, issue=Issue{id=1172617833407197957, tenantId=1146029695717560320, journalId=1146120122248306696, year='2024', volume='43', issue='5', pageStart='473', pageEnd='591', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1757503477670, creator=13701087609, updateTime=1758275998347, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1175858020027347895, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1172617833407197957, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1175858020027347896, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1172617833407197957, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=473, endPage=482, ext={EN=ArticleExt(id=1172617834808095502, articleId=1172617834585797389, tenantId=1146029695717560320, journalId=1146120122248306696, language=EN, title=Research Progress on Membrane Extraction Technology in Hydrometallurgy, columnId=1152626642049446094, journalTitle=Hydrometallurgy of China, columnName=Reviews, runingTitle=null, highlight=null, articleAbstract=

The composition, preparation methods, and mass transfer mechanisms of ELM (emulsion liquid membrane), SLM (supported liquid membrane), and PIM (polymeric inclusion membrane), and the research progress of these three types of membranes in hydrometallurgy in recent 5 years are reviewed. Additionally, the advantages and disadvantages of the three membranes in hydrometallurgy were summarized, and the solution to the problems such as ELM films exhibited instability and difficulties with emulsion breaking, SLM membranes tended to be unstable with the membrane phase is lost to the water phase and PIM demonstrated lower mass transfer efficiency requiring longer time to reach equilibrium are proposed. Finally, the future development direction for the three membranes in the field of hydrometallurgy are prospected, providing a crucial foundation for further promoting the application of membrane extraction technology in hydrometallurgy and expediting the industrial production of membrane extraction technology.

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综述了乳状液膜(ELM)、支撑液膜(SLM)和聚合物包容膜(PIM)的组成、制备方法、传质机制,以及近5年来3种膜在湿法冶金中的研究进展,总结了3种膜在湿法冶金中存在的优点和缺点。针对ELM膜相不稳定、破乳困难,SLM膜相不稳定、易流失,PIM传质效率较低、耗时长等缺点提出了相应的弥补方法。对3种膜在湿法冶金领域未来的发展方向进行了展望,为进一步促进膜萃取技术在湿法冶金中的应用研究,加快膜萃取技术工业化生产提供了重要依据。

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朱山(1989—),男,博士,教授,硕士生导师,主要研究方向为冶金固废资源化。

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Journal of Hazardous Materials, 2022, 436.DOI:10.1016/j.jhazmat.2022.129315., articleTitle=Vanadium recovery by electrodialysis using polymer inclusion membranes, refAbstract=null), Reference(id=1176949699996168535, tenantId=1146029695717560320, journalId=1146120122248306696, articleId=1172617834585797389, doi=null, pmid=null, pmcid=null, year=2023, volume=456, issue=null, pageStart=null, pageEnd=null, url=null, language=null, rfNumber=[93], rfOrder=92, authorNames=WANG Y, WANG P, XIE H, journalName=Journal of Hazardous Materials, refType=null, unstructuredReference=WANG Y, WANG P, XIE H, et al. Mechanistic investigation of intensified separation of molybdenum(Ⅵ) and vanadium(Ⅴ) using polymer inclusion membrane electrodialysis[J]. 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Journal of Hazardous Materials, 2020, 386.DOI:10.1016/j.jhazmat.2019.121990., articleTitle=Electro-membrane extraction of cadmium(Ⅱ) by bis(2-ethylhexyl) phosphate/kerosene/polyvinyl chloride polymer inclusion membrane, refAbstract=null), Reference(id=1176949700101026137, tenantId=1146029695717560320, journalId=1146120122248306696, articleId=1172617834585797389, doi=null, pmid=null, pmcid=null, year=2021, volume=202, issue=null, pageStart=null, pageEnd=null, url=null, language=null, rfNumber=[95], rfOrder=94, authorNames=MENG X, LONG Y, TIAN Y, journalName=Hydrometallurgy, refType=null, unstructuredReference=MENG X, LONG Y, TIAN Y, et al. Electro-membrane extraction of lithium with D2EHPA/TBP compound extractant[J]. 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膜相(载体-膜溶剂-表面活性剂-增膜剂)	内相	外相	萃取分离效果	参考文献
D2EHPA-煤油-span80-液体石蜡	HCl	Cd(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ)	均达98%以上	[18]
N503-煤油-span80-液体石蜡	EDTA	Pd(Ⅱ)	96.6%	[19]
TOPO-葵花籽油-PGPR+Tween 80-无	Na2CO3	Cr(Ⅵ)	96%	[20]
D2EHPA-葵花籽油-span80-无	HCl	Cu(Ⅱ)	94%	[21]
1-己基-3-甲基咪唑六氟磷酸盐- 煤油-span80-Al(OH)3	NaOH	Sb(Ⅲ)	99%	[22]
D2EHPA-煤油-span80-Fe2O3	H2SO4	Pb(Ⅱ)	97.2%	[23]
Cyanex 272-煤油-span80+Tween-SiO2	H2SO4	Mn(Ⅱ)	大于97%	[24]
N2O3型Schiff碱-二氯甲烷-span80-液体石蜡	HCl	Cu(Ⅱ)、Pb(Ⅱ)、Cd(Ⅱ)、 Zn(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)、Cr(Ⅲ)	除Pb(Ⅱ)外,可选择性 回收Cu(Ⅱ)	[25]
Aliquat 336-棕桐油-span80-1-辛醇	硫脲、H2SO4	Cr(Ⅵ)	82%被反萃取为Cr(Ⅲ)	[26]
D2EHPA+EDTA-煤油-鼠李糖脂-无	H2SO4	Mn(Ⅱ)	77%	[27]
M2EHPA+D2EHPA-正己烷-span80-无	H2SO4	Cu(Ⅱ)	99.95%	[28]
D2EHPA-煤油-Triton X 100-无	H2SO4	Cd(Ⅱ)	98%	[29]
D2EHPA-基于植物油的餐饮废油-span80-无	H2SO4	Pb(Ⅱ)	97.39%	[30]
D2EHPA-煤油-span80-无	H2SO4	Sb(Ⅲ)	99%	[31]
M5640-煤油-span80-无	H2SO4	Cu(Ⅱ)、Ni(Ⅱ)	Cu(Ⅱ) 99.9%、Ni(Ⅱ) 4.2%	[32]

), ArticleFig(id=1176949691620143287, tenantId=1146029695717560320, journalId=1146120122248306696, articleId=1172617834585797389, language=CN, label=表1, caption=

ELM分离富集金属离子的研究进展

, figureFileSmall=null, figureFileBig=null, tableContent=

膜相(载体-膜溶剂-表面活性剂-增膜剂)	内相	外相	萃取分离效果	参考文献
D2EHPA-煤油-span80-液体石蜡	HCl	Cd(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ)	均达98%以上	[18]
N503-煤油-span80-液体石蜡	EDTA	Pd(Ⅱ)	96.6%	[19]
TOPO-葵花籽油-PGPR+Tween 80-无	Na2CO3	Cr(Ⅵ)	96%	[20]
D2EHPA-葵花籽油-span80-无	HCl	Cu(Ⅱ)	94%	[21]
1-己基-3-甲基咪唑六氟磷酸盐- 煤油-span80-Al(OH)3	NaOH	Sb(Ⅲ)	99%	[22]
D2EHPA-煤油-span80-Fe2O3	H2SO4	Pb(Ⅱ)	97.2%	[23]
Cyanex 272-煤油-span80+Tween-SiO2	H2SO4	Mn(Ⅱ)	大于97%	[24]
N2O3型Schiff碱-二氯甲烷-span80-液体石蜡	HCl	Cu(Ⅱ)、Pb(Ⅱ)、Cd(Ⅱ)、 Zn(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)、Cr(Ⅲ)	除Pb(Ⅱ)外,可选择性 回收Cu(Ⅱ)	[25]
Aliquat 336-棕桐油-span80-1-辛醇	硫脲、H2SO4	Cr(Ⅵ)	82%被反萃取为Cr(Ⅲ)	[26]
D2EHPA+EDTA-煤油-鼠李糖脂-无	H2SO4	Mn(Ⅱ)	77%	[27]
M2EHPA+D2EHPA-正己烷-span80-无	H2SO4	Cu(Ⅱ)	99.95%	[28]
D2EHPA-煤油-Triton X 100-无	H2SO4	Cd(Ⅱ)	98%	[29]
D2EHPA-基于植物油的餐饮废油-span80-无	H2SO4	Pb(Ⅱ)	97.39%	[30]
D2EHPA-煤油-span80-无	H2SO4	Sb(Ⅲ)	99%	[31]
M5640-煤油-span80-无	H2SO4	Cu(Ⅱ)、Ni(Ⅱ)	Cu(Ⅱ) 99.9%、Ni(Ⅱ) 4.2%	[32]

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膜相(萃取剂-稀释剂)	支撑体	料液相	接收相	萃取分离效果	参考文献
P507-庚烷	LiCl改性PVDF	Er(Ⅲ)	HCl	94.8%	[38]
N235-煤油	PVDF	页岩提钒酸浸液	Na2CO3	V(Ⅴ) 92%,其余金属 低于2%	[39]
[C4mim][NTf2]+ TBP-无	PVDF	Li(Ⅰ)、Na(Ⅰ)、Mg(Ⅱ)、 Co(Ⅱ)、Ni(Ⅱ)	Na2CO3+NaHCO3	可选择性分离Li(Ⅰ)	[40]
HFDOD+ TOPO-十二烷	PVDF	Li(Ⅰ)、Na(Ⅰ)	HCl	Li(Ⅰ) 100%被萃取, Li(Ⅰ)和Na(Ⅰ)成功分离	[41]
D2EHPA-矿物油	PVDF	粉煤灰渗滤液	HNO3	重稀土元素>75%; 轻稀土元素<50%	[42]
[C4mim][NTf2]+ TOPO+TBP-煤油	PVDF	永磁NdFeB浸出液	H2SO4	Nd(Ⅲ)和Dy(Ⅲ) 均在90%左右	[43]
三月桂胺-THF	PP	As(Ⅲ)	NaOH	93%	[44]
薄荷醇+水杨酸-无	PP	Ni(Ⅱ)、Mn(Ⅱ)、Cd(Ⅱ)、Pb(Ⅱ)、 Cu(Ⅱ)、Fe(Ⅱ)、Ag(Ⅰ)	Na2S2O3	可选择性分离Ag(Ⅰ)	[45]

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SLM分离富集金属离子的研究进展

, figureFileSmall=null, figureFileBig=null, tableContent=

膜相(萃取剂-稀释剂)	支撑体	料液相	接收相	萃取分离效果	参考文献
P507-庚烷	LiCl改性PVDF	Er(Ⅲ)	HCl	94.8%	[38]
N235-煤油	PVDF	页岩提钒酸浸液	Na2CO3	V(Ⅴ) 92%,其余金属 低于2%	[39]
[C4mim][NTf2]+ TBP-无	PVDF	Li(Ⅰ)、Na(Ⅰ)、Mg(Ⅱ)、 Co(Ⅱ)、Ni(Ⅱ)	Na2CO3+NaHCO3	可选择性分离Li(Ⅰ)	[40]
HFDOD+ TOPO-十二烷	PVDF	Li(Ⅰ)、Na(Ⅰ)	HCl	Li(Ⅰ) 100%被萃取, Li(Ⅰ)和Na(Ⅰ)成功分离	[41]
D2EHPA-矿物油	PVDF	粉煤灰渗滤液	HNO3	重稀土元素>75%; 轻稀土元素<50%	[42]
[C4mim][NTf2]+ TOPO+TBP-煤油	PVDF	永磁NdFeB浸出液	H2SO4	Nd(Ⅲ)和Dy(Ⅲ) 均在90%左右	[43]
三月桂胺-THF	PP	As(Ⅲ)	NaOH	93%	[44]
薄荷醇+水杨酸-无	PP	Ni(Ⅱ)、Mn(Ⅱ)、Cd(Ⅱ)、Pb(Ⅱ)、 Cu(Ⅱ)、Fe(Ⅱ)、Ag(Ⅰ)	Na2S2O3	可选择性分离Ag(Ⅰ)	[45]

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载体	基础聚合物-增塑剂	料液相	接收相	萃取分离效果	参考文献
N,N-二癸基-2- 氨甲基吡啶	PVC-NPOE	Cu(Ⅱ)、Ni(Ⅱ)、Co(Ⅱ)	HCl	可选择性分离Cu(Ⅱ)	[62]
D2EHPA	PVC-无	Cu(Ⅱ)、Zn(Ⅱ)、Mn(Ⅱ)、Co(Ⅱ)、 Ni(Ⅱ)、Cd(Ⅱ)、Al(Ⅲ)、Mo(Ⅵ)、 Cr(Ⅲ)、Bi(Ⅲ)	H2SO4	可选择性分离Bi(Ⅲ)	[63]
D2EHPA	CTA-NPOE	Cu(Ⅱ)、Zn(Ⅱ)、Cd(Ⅱ)、Pb(Ⅱ)	HNO3	Zn(Ⅱ)≥Pb(Ⅱ)>Cd(Ⅱ)> Cu(Ⅱ)	[64]
M5640	PVC-无	Cu(Ⅱ)	H2SO4	98%	[65]
D2EHPA+ 辛基异羟肟酸	PVC-无	Zn(Ⅱ)、Ni(Ⅱ)	H2SO4	可选择性分离Zn(Ⅱ)	[66]
Kelex 100	CTA-TEHP	Zn(Ⅱ)、Ni(Ⅱ)、Pb(Ⅱ)、 Cu(Ⅱ)、Ca(Ⅱ)、Mg(Ⅱ)	HCl	当Pb(Ⅱ)不存在时,可选择性 分离Ni(Ⅱ)与Ca(Ⅱ)和Mg(Ⅱ)	[67]
1-戊基三唑	CTA-邻硝基 苯戊醚	Zn(Ⅱ)、Ni(Ⅱ)、Pd(Ⅱ)	HCl	Pd(Ⅱ)>Zn(Ⅱ)>Ni(Ⅱ)	[68]
D2EHPA	PVC-无	In(Ⅲ)、Zn(Ⅱ)、Fe(Ⅲ)	HCl	In(Ⅲ) 100%	[69]
乙二胺- 双乙酰丙酮	CTA-邻硝基 苯戊醚	Zn(Ⅱ)、Cd(Ⅱ)、Co(Ⅱ)、 Cu(Ⅱ)、Ni(Ⅱ)	H2O	Zn(Ⅱ)>Cd(Ⅱ)>Co(Ⅱ)> Cu(Ⅱ)>Ni(Ⅱ)	[70]
TTA+TOPO	CTA-无	Li(Ⅰ)、Na(Ⅰ)、K(Ⅰ)	HCl	可高度选择性分离Li(Ⅰ)	[71]
TOA	CTA-TBP	Bi(Ⅲ)、Cu(Ⅱ)、Pb(Ⅱ)、Zn(Ⅱ)、 Ni(Ⅱ)、Co(Ⅱ)、Cd(Ⅱ)、Fe(Ⅲ)、 Cr(Ⅲ)、Mo(Ⅵ)、W(Ⅵ)	Na2CO3	Bi(Ⅲ)>95%,几乎无 其他金属离子	[72]
LIX84I+新癸酸	PVC-NPOE	Cu(Ⅱ)	H2SO4	97%	[73]
P227	PVDF-无	Lu(Ⅲ)、La(Ⅲ)、Sm(Ⅲ)	HCl	Lu(Ⅲ) 91%,Sm(Ⅲ) 5%, 无La(Ⅲ)	[74]
A336	PVC-聚氧乙 烯烷基醚	Te(IV)	Na2CO3	55.56%	[75]
A336	PVDF-HTP-邻苯 二甲酸二丁酯	Al(Ⅲ)、Co(Ⅱ)、Cu(Ⅱ)、Fe(Ⅲ)、 Mn(Ⅱ)、Ni(Ⅱ)、V(Ⅴ)	H2SO4+ H2O2	可选择性分离V(Ⅴ)	[76]
A336	CTA+聚己二酸- 对苯二甲酸丁 二醇酯-无	Cr(Ⅵ)、Cd(Ⅱ)、Pb(Ⅱ)、Fe(Ⅲ)、 Zn(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ)、Co(Ⅱ)	NaOH	单Cr(Ⅵ) 99%;多金属混合, 可选择性分离Cr(Ⅵ),91.5%	[77]
A336	CTA-无	As(Ⅲ)、As(Ⅴ)	NaCl	As(Ⅴ) 99.7%	[78]
A336	PVDF-NPOE	Cr(Ⅵ)、Cd(Ⅱ)、Pb(Ⅱ)、Fe(Ⅲ)、 Zn(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ)、Co(Ⅱ)	醋酸+ 醋酸铵	可选择性分离Cr(Ⅵ),97%	[79]
[A336][SCN]	PVDF-NPOE	Au(Ⅰ)	KSCN	98.2%	[80]
A336或 Cyphos IL 101	PVDF-HTP-无	Cr(Ⅵ)	NaNO3	79%或66%	[81]
A336	PVC-无	Fe(Ⅲ)、Zn(Ⅱ)、Cu(Ⅱ)、Cd(Ⅱ)	HCl	分离系数β(Zn/Cu)、β(Zn/Fe)和 β(Cd/Cu)分别为1 996、606和112	[82]
1,3-癸基-1-咪唑- 3-溴化铵	PVC-NPOE	Fe(Ⅱ)、Zn(Ⅱ)、Ni(Ⅱ)、 Cr(Ⅲ)、Co(Ⅱ)、Cd(Ⅱ)	NH4OH	可有效去除Cd(Ⅱ)	[83]
三辛基(十二 烷基)氯化磷	PVDF-HTP-NPOE	Pt(Ⅳ)、Pd(Ⅱ)、Rh(Ⅲ)	HCl等	Pt(Ⅳ) 93%,Pd(Ⅱ) 93%	[84]
溴化3-(1,3- 二乙氧基-1,3- 二氧代丙-2-基)- 1-辛基咪唑	CTA-NPOE	Zn(Ⅱ)、Cu(Ⅱ)、Cd(Ⅱ)、Pb(Ⅱ)	HNO3	Cd(Ⅱ)>Zn(Ⅱ)>Pb(Ⅱ)≫ Cu(Ⅱ)	[85]
苯扎氯铵	PVC-DOP	As(Ⅴ)	NaCl	91%	[86]

), ArticleFig(id=1176949691993436351, tenantId=1146029695717560320, journalId=1146120122248306696, articleId=1172617834585797389, language=CN, label=表3, caption=

PIM分离富集金属离子的研究进展

, figureFileSmall=null, figureFileBig=null, tableContent=

载体	基础聚合物-增塑剂	料液相	接收相	萃取分离效果	参考文献
N,N-二癸基-2- 氨甲基吡啶	PVC-NPOE	Cu(Ⅱ)、Ni(Ⅱ)、Co(Ⅱ)	HCl	可选择性分离Cu(Ⅱ)	[62]
D2EHPA	PVC-无	Cu(Ⅱ)、Zn(Ⅱ)、Mn(Ⅱ)、Co(Ⅱ)、 Ni(Ⅱ)、Cd(Ⅱ)、Al(Ⅲ)、Mo(Ⅵ)、 Cr(Ⅲ)、Bi(Ⅲ)	H2SO4	可选择性分离Bi(Ⅲ)	[63]
D2EHPA	CTA-NPOE	Cu(Ⅱ)、Zn(Ⅱ)、Cd(Ⅱ)、Pb(Ⅱ)	HNO3	Zn(Ⅱ)≥Pb(Ⅱ)>Cd(Ⅱ)> Cu(Ⅱ)	[64]
M5640	PVC-无	Cu(Ⅱ)	H2SO4	98%	[65]
D2EHPA+ 辛基异羟肟酸	PVC-无	Zn(Ⅱ)、Ni(Ⅱ)	H2SO4	可选择性分离Zn(Ⅱ)	[66]
Kelex 100	CTA-TEHP	Zn(Ⅱ)、Ni(Ⅱ)、Pb(Ⅱ)、 Cu(Ⅱ)、Ca(Ⅱ)、Mg(Ⅱ)	HCl	当Pb(Ⅱ)不存在时,可选择性 分离Ni(Ⅱ)与Ca(Ⅱ)和Mg(Ⅱ)	[67]
1-戊基三唑	CTA-邻硝基 苯戊醚	Zn(Ⅱ)、Ni(Ⅱ)、Pd(Ⅱ)	HCl	Pd(Ⅱ)>Zn(Ⅱ)>Ni(Ⅱ)	[68]
D2EHPA	PVC-无	In(Ⅲ)、Zn(Ⅱ)、Fe(Ⅲ)	HCl	In(Ⅲ) 100%	[69]
乙二胺- 双乙酰丙酮	CTA-邻硝基 苯戊醚	Zn(Ⅱ)、Cd(Ⅱ)、Co(Ⅱ)、 Cu(Ⅱ)、Ni(Ⅱ)	H2O	Zn(Ⅱ)>Cd(Ⅱ)>Co(Ⅱ)> Cu(Ⅱ)>Ni(Ⅱ)	[70]
TTA+TOPO	CTA-无	Li(Ⅰ)、Na(Ⅰ)、K(Ⅰ)	HCl	可高度选择性分离Li(Ⅰ)	[71]
TOA	CTA-TBP	Bi(Ⅲ)、Cu(Ⅱ)、Pb(Ⅱ)、Zn(Ⅱ)、 Ni(Ⅱ)、Co(Ⅱ)、Cd(Ⅱ)、Fe(Ⅲ)、 Cr(Ⅲ)、Mo(Ⅵ)、W(Ⅵ)	Na2CO3	Bi(Ⅲ)>95%,几乎无 其他金属离子	[72]
LIX84I+新癸酸	PVC-NPOE	Cu(Ⅱ)	H2SO4	97%	[73]
P227	PVDF-无	Lu(Ⅲ)、La(Ⅲ)、Sm(Ⅲ)	HCl	Lu(Ⅲ) 91%,Sm(Ⅲ) 5%, 无La(Ⅲ)	[74]
A336	PVC-聚氧乙 烯烷基醚	Te(IV)	Na2CO3	55.56%	[75]
A336	PVDF-HTP-邻苯 二甲酸二丁酯	Al(Ⅲ)、Co(Ⅱ)、Cu(Ⅱ)、Fe(Ⅲ)、 Mn(Ⅱ)、Ni(Ⅱ)、V(Ⅴ)	H2SO4+ H2O2	可选择性分离V(Ⅴ)	[76]
A336	CTA+聚己二酸- 对苯二甲酸丁 二醇酯-无	Cr(Ⅵ)、Cd(Ⅱ)、Pb(Ⅱ)、Fe(Ⅲ)、 Zn(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ)、Co(Ⅱ)	NaOH	单Cr(Ⅵ) 99%;多金属混合, 可选择性分离Cr(Ⅵ),91.5%	[77]
A336	CTA-无	As(Ⅲ)、As(Ⅴ)	NaCl	As(Ⅴ) 99.7%	[78]
A336	PVDF-NPOE	Cr(Ⅵ)、Cd(Ⅱ)、Pb(Ⅱ)、Fe(Ⅲ)、 Zn(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ)、Co(Ⅱ)	醋酸+ 醋酸铵	可选择性分离Cr(Ⅵ),97%	[79]
[A336][SCN]	PVDF-NPOE	Au(Ⅰ)	KSCN	98.2%	[80]
A336或 Cyphos IL 101	PVDF-HTP-无	Cr(Ⅵ)	NaNO3	79%或66%	[81]
A336	PVC-无	Fe(Ⅲ)、Zn(Ⅱ)、Cu(Ⅱ)、Cd(Ⅱ)	HCl	分离系数β(Zn/Cu)、β(Zn/Fe)和 β(Cd/Cu)分别为1 996、606和112	[82]
1,3-癸基-1-咪唑- 3-溴化铵	PVC-NPOE	Fe(Ⅱ)、Zn(Ⅱ)、Ni(Ⅱ)、 Cr(Ⅲ)、Co(Ⅱ)、Cd(Ⅱ)	NH4OH	可有效去除Cd(Ⅱ)	[83]
三辛基(十二 烷基)氯化磷	PVDF-HTP-NPOE	Pt(Ⅳ)、Pd(Ⅱ)、Rh(Ⅲ)	HCl等	Pt(Ⅳ) 93%,Pd(Ⅱ) 93%	[84]
溴化3-(1,3- 二乙氧基-1,3- 二氧代丙-2-基)- 1-辛基咪唑	CTA-NPOE	Zn(Ⅱ)、Cu(Ⅱ)、Cd(Ⅱ)、Pb(Ⅱ)	HNO3	Cd(Ⅱ)>Zn(Ⅱ)>Pb(Ⅱ)≫ Cu(Ⅱ)	[85]
苯扎氯铵	PVC-DOP	As(Ⅴ)	NaCl	91%	[86]

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