Article(id=1317114939978924067, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1317114928411034576, articleNumber=null, orderNo=null, doi=10.13355/j.cnki.sfyj.2026.05.012, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1777305600000, receivedDateStr=2026-04-28, revisedDate=1779638400000, revisedDateStr=2026-05-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1791954272502, onlineDateStr=2026-10-14, pubDate=1792425600000, pubDateStr=2026-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791954272502, onlineIssueDateStr=2026-10-14, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791954272502, creator=13701087609, updateTime=1791954272502, updator=13701087609, issue=Issue{id=1317114928411034576, tenantId=1146029695717560320, journalId=1146120122248306696, year='2026', volume='45', issue='5', pageStart='613', pageEnd='782', issueExtLink='null', onlineDate='null', pubDate='1792425600000', pubDateStr='2026-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1791954269745, creator='13701087609', updateTime=1792120411533, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1317811777694450639, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1317114928411034576, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1317811777694450640, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1317114928411034576, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=723, endPage=733, ext={EN=ArticleExt(id=1317114940180250660, articleId=1317114939978924067, tenantId=1146029695717560320, journalId=1146120122248306696, language=EN, title=Synthesis of Flower-Like MoS₂@CNT Composites with Expanded Interlayer Spacing and Their Electrochemical Properties, columnId=1152626641181700664, journalTitle=Hydrometallurgy of China, columnName=Experiment Research, runingTitle=null, highlight=null, articleAbstract=

A one-step hydrothermal method was employed, using urea (H₂NCONH₂) as an interlayer modulation agent, to realize the in situ growth of molybdenum disulfide (MoS₂) within a three-dimensional conductive network constructed by carbon nanotubes (CNTs). MoS₂@CNT composite was prpared and used as anode materials for sodium ion batteries, and theri electrochemical properties investigated. The results indicate that the MoS₂@CNT composite materials can effectively alleviate volume expansion during sodium-ion insertion and extraction, thereby improving the sodium storage reaction kinetics and structural stability. Structural characterization results reveal that the incorporation of H₂NCONH₂ increases the interlayer spacing of MoS₂ from 0.62 nm to 0.71 nm, thereby providing additional active sites and shortening ion diffusion pathways. Electrochemical properties test results demonstrate that, after 100 cycles at a current density of 0.1 A/g, the composite maintains a reversible capacity of 387.2 mAh/g, corresponding to a capacity retention rate of 97.5%. Furthermore, after cycling at various current densities, the specific capacity recovers to 402.3 mAh/g, indicating excellent rate capability and superior cycling stability.

, authors=Li SI, Zhonglin LI, Fengqi LU, authorsList=Li SI, Zhonglin LI, Fengqi LU, authorCompany=null, correspAuthors=Fengqi LU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1317114942088658981, articleId=1317114939978924067, tenantId=1146029695717560320, journalId=1146120122248306696, language=CN, title=具有扩展层间距的花球状MoS₂@CNT复合材料的制备及其电化学性能研究, columnId=1152626641328501305, journalTitle=湿法冶金, columnName=试验研究, runingTitle=null, highlight=null, articleAbstract=

研究了采用一步水热法，以尿素（H₂NCONH₂）为扩层调控剂，促使二硫化钼（MoS₂）在碳纳米管（CNT）构建的三维导电网络中的原位生长，制备了MoS₂@CNT复合材料并用作钠离子电池的负极材料，同时考察了其电化学性能。研究结果表明，MoS₂@CNT复合材料在钠离子嵌入与脱出过程中起到缓解体积膨胀的作用，改善了其储钠反应动力学及结构稳定性。结构分析结果表明，加入H₂NCONH₂后，MoS₂的层间距由0.62 nm扩展至0.71 nm，能提供更多反应活性位点，并有效缩短离子迁移路径。电化学性能测试结果表明，该材料在0.1 A/g电流密度条件下循环100次后，可逆容量仍可保持在387.2 mAh/g，保持率达97.5%；经过不同电流密度测试后，其比容量还能恢复至402.3 mAh/g，倍率性能良好，具有优异的循环稳定性。

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司立（2000—），男，硕士研究生，主要研究方向为钠离子电池负极材料。

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司立（2000—），男，硕士研究生，主要研究方向为钠离子电池负极材料。

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