Article(id=1317114950011703771, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1317114928411034576, articleNumber=null, orderNo=null, doi=10.13355/j.cnki.sfyj.2026.05.009, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1777996800000, receivedDateStr=2026-05-06, revisedDate=1780588800000, revisedDateStr=2026-06-05, acceptedDate=null, acceptedDateStr=null, onlineDate=1791954274894, onlineDateStr=2026-10-14, pubDate=1792425600000, pubDateStr=2026-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791954274894, onlineIssueDateStr=2026-10-14, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791954274894, creator=13701087609, updateTime=1791954274894, updator=13701087609, issue=Issue{id=1317114928411034576, tenantId=1146029695717560320, journalId=1146120122248306696, year='2026', volume='45', issue='5', pageStart='613', pageEnd='782', issueExtLink='null', onlineDate='null', pubDate='1792425600000', pubDateStr='2026-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1791954269745, creator='13701087609', updateTime=1792120411533, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1317811777694450639, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1317114928411034576, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1317811777694450640, tenantId=1146029695717560320, journalId=1146120122248306696, issueId=1317114928411034576, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=691, endPage=699, ext={EN=ArticleExt(id=1317114950200447452, articleId=1317114950011703771, tenantId=1146029695717560320, journalId=1146120122248306696, language=EN, title=Recovery Process of Germanium from Zinc Concentrate Oxygen Pressure Leaching Residue by Oxygen Pressure Acid Leaching, columnId=1152626641181700664, journalTitle=Hydrometallurgy of China, columnName=Experiment Research, runingTitle=null, highlight=null, articleAbstract=

To address the problems of high energy consumption in pyrometallurgical recovery and low germanium leaching rate in atmospheric hydrometallurgical recovery of germanium from oxygen pressure leaching residues of zinc concentrates, the leaching of germanium in a high-temperature and high-pressure sulfuric acid system, using oxygen as the oxidant and sodium lignosulfonate as the activating agent was investigated. The effects of key parameters, including leaching temperature and time, mass concentration of sulfuric acid, oxygen pressure, liquid volume to solid mass ratio, and sodium lignosulfonate dosage on the leaching rate of germanium were examined. The results show that the oxygen pressure leaching process can enhance the oxidative decomposition of refractory sulfides such as sphalerite in the oxygen pressure leaching residue of zinc concentrates, destroy their crystal lattice structures, and enable the dissociation and leaching of isomorphous germanium. Under the optimized conditions of leaching temperature of 150 ℃, leaching time of 3 h, mass concentration of sulfuric acid of 180 g/L, oxygen pressure of 1.0 MPa, and liquid volume to solid mass ratio of 8 mL/1 g, and sodium lignosulfonate dosage of 3% by mass of the oxygen pressure leaching residue of zinc concentrates, the leaching rate of germanium reaches 72.17%, which is significantly improved compared with the atmospheric acid leaching method, and the leaching rate of zinc reaches 89.39%. This study provides technical reference for the green and efficient recovery of germanium from oxygen pressure leaching residue and is of great significance for ensuring the sustainable supply of germanium resources.

, authors=Guixiang HE1, 2, Yongzhi LONG1, Xuexian JIANG2, Jiaxin LI2, Jierong ZHOU2, Xingqin XIE2, Yizhao WANG2, Jun WU3, Chuanjian WANG3, authorsList=Guixiang HE, Yongzhi LONG, Xuexian JIANG, Jiaxin LI, Jierong ZHOU, Xingqin XIE, Yizhao WANG, Jun WU, Chuanjian WANG, authorCompany=null, correspAuthors=Jun WU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1317114950674403805, articleId=1317114950011703771, tenantId=1146029695717560320, journalId=1146120122248306696, language=CN, title=锌精矿氧压浸出渣中锗的氧压酸浸回收工艺研究, columnId=1152626641328501305, journalTitle=湿法冶金, columnName=试验研究, runingTitle=null, highlight=null, articleAbstract=

针对锌精矿氧压浸出渣中的锗,采用火法或常压湿法回收存在的能耗高或锗浸出率低等问题,研究了在高温高压硫酸体系中,以氧气为氧化剂、木质素磺酸钠为活化剂浸出锗,并考察了浸出温度和时间、硫酸质量浓度、氧压、液固体积质量比及木质素磺酸钠添加量等关键参数对锗浸出率的影响。结果表明:氧压浸出法可强化锌精矿氧压浸出渣中闪锌矿等难溶硫化物的氧化分解,破坏晶格结构,使类质同象态锗解离浸出;在浸出温度为150 ℃、浸出时间为3 h、硫酸质量浓度为180 g/L、氧压为1.0 MPa、液固体积质量比为8 mL/1 g、木质素磺酸钠添加量为锌精矿氧压浸出渣质量的3%优化条件下,锗浸出率为72.17%,相较常压酸浸法有明显提升,锌浸出率为89.39%。该研究可为氧压浸出渣中锗的绿色高效回收提供技术参考,对保障锗资源可持续供给具有重要意义。

, authors=何贵香1, 2, 龙永智1, 蒋学先2, 李嘉欣2, 周街荣2, 谢幸秦2, 王益昭2, 吴军3, 王传建3, authorsList=何贵香, 龙永智, 蒋学先, 李嘉欣, 周街荣, 谢幸秦, 王益昭, 吴军, 王传建, authorCompany=null, correspAuthors=吴军, authorNote=

何贵香(1973—),女,博士,教授,主要研究方向为有色金属冶金与资源循环利。

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吴军(1981—),男,大专,工程师,主要研究方向为有色金属冶金。E-mail:。
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锌精矿氧压浸出渣中锗的氧压酸浸回收工艺研究
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何贵香 1, 2 , 龙永智 1 , 蒋学先 2 , 李嘉欣 2 , 周街荣 2 , 谢幸秦 2 , 王益昭 2 , 吴军 3 , 王传建 3
湿法冶金 | 试验研究 2026,45(5): 691-699
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湿法冶金 |试验研究 2026 , 45 (5) : 691 -699
锌精矿氧压浸出渣中锗的氧压酸浸回收工艺研究
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何贵香(1973—),女,博士,教授,主要研究方向为有色金属冶金与资源循环利。

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何贵香1, 2, 龙永智1, 蒋学先2, 李嘉欣2, 周街荣2, 谢幸秦2, 王益昭2, 吴军3 , 王传建3
作者信息
  • 1.桂林理工大学 材料科学与工程学院,广西 桂林 541004
  • 2.桂林理工大学南宁分校 冶金与资源工程学院,广西 南宁 530001
  • 3.广西誉升锗业高新技术有限公司,广西 河池 547000
通讯作者:
吴军(1981—),男,大专,工程师,主要研究方向为有色金属冶金。E-mail:。
作者简介:

何贵香(1973—),女,博士,教授,主要研究方向为有色金属冶金与资源循环利。

Recovery Process of Germanium from Zinc Concentrate Oxygen Pressure Leaching Residue by Oxygen Pressure Acid Leaching
Guixiang HE1, 2, Yongzhi LONG1, Xuexian JIANG2, Jiaxin LI2, Jierong ZHOU2, Xingqin XIE2, Yizhao WANG2, Jun WU3 , Chuanjian WANG3
Affiliations
  • 1.College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China
  • 2.College of Metallurgical and Resources Engineering, Guilin University of Technology at Nanning, Nanning 530001, China
  • 3.Guangxi Yusheng Germanium Industry High-tech Co., Ltd., Hechi 547000, China
出版时间: 2026-10-20 doi: 10.13355/j.cnki.sfyj.2026.05.009
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针对锌精矿氧压浸出渣中的锗,采用火法或常压湿法回收存在的能耗高或锗浸出率低等问题,研究了在高温高压硫酸体系中,以氧气为氧化剂、木质素磺酸钠为活化剂浸出锗,并考察了浸出温度和时间、硫酸质量浓度、氧压、液固体积质量比及木质素磺酸钠添加量等关键参数对锗浸出率的影响。结果表明:氧压浸出法可强化锌精矿氧压浸出渣中闪锌矿等难溶硫化物的氧化分解,破坏晶格结构,使类质同象态锗解离浸出;在浸出温度为150 ℃、浸出时间为3 h、硫酸质量浓度为180 g/L、氧压为1.0 MPa、液固体积质量比为8 mL/1 g、木质素磺酸钠添加量为锌精矿氧压浸出渣质量的3%优化条件下,锗浸出率为72.17%,相较常压酸浸法有明显提升,锌浸出率为89.39%。该研究可为氧压浸出渣中锗的绿色高效回收提供技术参考,对保障锗资源可持续供给具有重要意义。

锌精矿氧压浸出渣  /  锗  /  锌  /  浸出  /  氧压酸浸

To address the problems of high energy consumption in pyrometallurgical recovery and low germanium leaching rate in atmospheric hydrometallurgical recovery of germanium from oxygen pressure leaching residues of zinc concentrates, the leaching of germanium in a high-temperature and high-pressure sulfuric acid system, using oxygen as the oxidant and sodium lignosulfonate as the activating agent was investigated. The effects of key parameters, including leaching temperature and time, mass concentration of sulfuric acid, oxygen pressure, liquid volume to solid mass ratio, and sodium lignosulfonate dosage on the leaching rate of germanium were examined. The results show that the oxygen pressure leaching process can enhance the oxidative decomposition of refractory sulfides such as sphalerite in the oxygen pressure leaching residue of zinc concentrates, destroy their crystal lattice structures, and enable the dissociation and leaching of isomorphous germanium. Under the optimized conditions of leaching temperature of 150 ℃, leaching time of 3 h, mass concentration of sulfuric acid of 180 g/L, oxygen pressure of 1.0 MPa, and liquid volume to solid mass ratio of 8 mL/1 g, and sodium lignosulfonate dosage of 3% by mass of the oxygen pressure leaching residue of zinc concentrates, the leaching rate of germanium reaches 72.17%, which is significantly improved compared with the atmospheric acid leaching method, and the leaching rate of zinc reaches 89.39%. This study provides technical reference for the green and efficient recovery of germanium from oxygen pressure leaching residue and is of great significance for ensuring the sustainable supply of germanium resources.

oxygen pressure leaching residue of zinc concentrates  /  germanium  /  zinc  /  leaching  /  oxygen pressure acid leaching
何贵香, 龙永智, 蒋学先, 李嘉欣, 周街荣, 谢幸秦, 王益昭, 吴军, 王传建. 锌精矿氧压浸出渣中锗的氧压酸浸回收工艺研究. 湿法冶金, 2026 , 45 (5) : 691 -699 . DOI: 10.13355/j.cnki.sfyj.2026.05.009
Guixiang HE, Yongzhi LONG, Xuexian JIANG, Jiaxin LI, Jierong ZHOU, Xingqin XIE, Yizhao WANG, Jun WU, Chuanjian WANG. Recovery Process of Germanium from Zinc Concentrate Oxygen Pressure Leaching Residue by Oxygen Pressure Acid Leaching[J]. Hydrometallurgy of China, 2026 , 45 (5) : 691 -699 . DOI: 10.13355/j.cnki.sfyj.2026.05.009
  • 广西自然科学基金(2025GXNSFAA069249)
  • 中央引导地方科技发展资金项目(桂科ZY24212040)
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doi: 10.13355/j.cnki.sfyj.2026.05.009
  • 接收时间:2026-05-06
  • 首发时间:2026-10-14
  • 出版时间:2026-10-20
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  • 收稿日期:2026-05-06
  • 修回日期:2026-06-05
基金
广西自然科学基金(2025GXNSFAA069249)
中央引导地方科技发展资金项目(桂科ZY24212040)
作者信息
    1.桂林理工大学 材料科学与工程学院,广西 桂林 541004
    2.桂林理工大学南宁分校 冶金与资源工程学院,广西 南宁 530001
    3.广西誉升锗业高新技术有限公司,广西 河池 547000

通讯作者:

吴军(1981—),男,大专,工程师,主要研究方向为有色金属冶金。E-mail:。
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2种不同金属材料的力学参数
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属数
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genus
种数
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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