Article(id=1271501738331807995, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1271501633826530070, articleNumber=PA20260121_3GQNfkvM, orderNo=null, doi=10.19666/j.rlfd.202503041, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1741968000000, receivedDateStr=2025-03-15, revisedDate=1743955200000, revisedDateStr=2025-04-07, acceptedDate=1744819200000, acceptedDateStr=2025-04-17, onlineDate=1781079237778, onlineDateStr=2026-06-10, pubDate=1769270400000, pubDateStr=2026-01-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1781079237777, onlineIssueDateStr=2026-06-10, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1781079237777, creator=admin, updateTime=1781079237777, updator=admin, issue=Issue{id=1271501633826530070, tenantId=1146029695717560320, journalId=1210938733613449225, year='2026', volume='55', issue='1', pageStart='1', pageEnd='186', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=0, articleOrder=1, issueType=1, specialIssue=null, createTime=1781079212860, creator=ztmeta, updateTime=1781079304307, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1271502017525657824, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1271501633826530070, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1271502017529852129, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1271501633826530070, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=113, endPage=121, ext={EN=ArticleExt(id=1271501739812397310, articleId=1271501738331807995, tenantId=1146029695717560320, journalId=1210938733613449225, language=EN, title=Performance optimization of Mn-based thermochemical coating for high-temperature receivers to dampen solar irradiance fluctuations, columnId=null, journalTitle=Thermal Power Generation, columnName=null, runingTitle=null, highlight=null, articleAbstract=The Brayton cycle-based tower solar thermal power system features a flexible layout and operates at high receiver temperatures. However, fluctuations in solar irradiance can lead to thermal fatigue of receiver materials or excessive surface temperatures, necessitating effective strategies to mitigate temperature fluctuations. This study develops a manganese-based thermochemical thermal protection coating utilizing a reversible redox reaction. When solar radiation intensifies and the temperature exceeds 978 ℃, the coating undergoes a reduction endothermic reaction, reducing the heating rate. Conversely, when solar radiation decreases and the temperature drops below 878 ℃, an oxidation exothermic reaction occurs, slowing the cooling rate, thereby stabilizing receiver surface temperature fluctuations. Experimental results indicate that when the mass ratio of the coating material to the binder is 4:3, the adhesion strength reaches the highest national standard level, and the solar weighed average absorptivity achieves 94.93%. After undergoing 500 hours of thermal aging at 950 ℃, 100 cycles of thermal cycling, and 200 cycles of redox reaction tests, the coating’s weighed average absorptivity decreased by only 0.82, 0.98, and 2.61 percentage points, respectively, while maintaining the highest adhesion strength. Under a sudden change in concentrated solar radiation flux of ±9.7 kW/m², the heating and cooling rates in the first 100 seconds were reduced by 59.66% and 67.09%, respectively. Additionally, the time required for a 20 ℃ increase and decrease was extended by 182.50% and 438.60%, respectively. The manganese-based thermochemical coating demonstrates excellent aging resistance and effectively suppresses absorber temperature fluctuations, making it highly promising for applications in Brayton cycle-based tower solar thermal power systems., correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, authorCompany=null, fund=null, authors=null, authorsList=null), CN=ArticleExt(id=1271501739741094141, articleId=1271501738331807995, tenantId=1146029695717560320, journalId=1210938733613449225, language=CN, title=平抑太阳能波动的高温吸热器锰基热化学涂层性能优化, columnId=null, journalTitle=热力发电, columnName=null, runingTitle=null, highlight=null, articleAbstract=塔式光热布雷顿循环发电系统的布置灵活,其吸热器工作温度较高,太阳能波动容易造成吸热器材料热疲劳或表面超温,亟需探索平抑吸热器温度波动的有效途径。开发了一种基于可逆氧化还原反应的锰基热化学热防护涂层,当太阳辐射增强且温度超过978 ℃时,涂层材料发生还原吸热反应,降低升温速率;当太阳辐射减弱且温度低于878 ℃时,发生氧化放热反应,减缓降温速率,进而平抑吸热器表面温度波动。研究表明:涂层材料与黏结剂的质量比为4:3时附着力可达国家标准的最高级,太阳光加权平均吸收率达到94.93%;在950 ℃恒温老化500 h、冷热交变老化100次循环以及氧化还原反应试验200次循环后,涂层加权平均吸收率仅分别衰减0.82百分点、0.98百分点和2.61百分点,且附着力保持在最高级;在±9.7 kW/m2的聚光辐射能流突变条件下,前100 s升温和降温速率分别降低59.66%和67.09%,升温和降温20 ℃所需的时间分别延长182.50%和438.60%。锰基热化学涂层表现出优秀的抗老化性能,并能有效平抑吸热器的温度波动,在塔式光热布雷顿循环系统中具有广阔的应用前景。, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, 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平抑太阳能波动的高温吸热器锰基热化学涂层性能优化
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张 添 1,2,3,4,5,6,7,8 , 刘 静 1,2,3,4,5,6,7,8 , 孙田津 1,2,3,4,5,6,7,8 , 石丽萍 1,2,3,4,5,6,7,8 , 胡 锐 1,2,3,4,5,6,7,8 , 帅 威 1,2,3,4,5,6,7,8 , 何艺彬 1,2,3,4,5,6,7,8 , 祝培旺 1,2,3,4,5,6,7,8 , 肖 刚 1,2,3,4,5,6,7,8
热力发电 | 2026,55(1): 113-121
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热力发电 | 2026, 55(1): 113-121
平抑太阳能波动的高温吸热器锰基热化学涂层性能优化
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张 添1,2,3,4,5,6,7,8, 刘 静1,2,3,4,5,6,7,8, 孙田津1,2,3,4,5,6,7,8, 石丽萍1,2,3,4,5,6,7,8, 胡 锐1,2,3,4,5,6,7,8, 帅 威1,2,3,4,5,6,7,8, 何艺彬1,2,3,4,5,6,7,8, 祝培旺1,2,3,4,5,6,7,8, 肖 刚1,2,3,4,5,6,7,8
作者信息
  • 1.浙江 杭州 310027
  • 2.新疆 克拉玛依 834000
  • 3.浙江大学能源高效清洁利用全国重点实验室
  • 4.中国石油新疆油田分公司采油工艺研究院
  • 5.杭州华源前线能源设备有限公司
  • 6.浙江大学青山湖能源研究基地
  • 7.浙江 杭州 310030
  • 8.浙江 杭州 311300
Performance optimization of Mn-based thermochemical coating for high-temperature receivers to dampen solar irradiance fluctuations
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出版时间: 2026-01-25 doi: 10.19666/j.rlfd.202503041
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塔式光热布雷顿循环发电系统的布置灵活,其吸热器工作温度较高,太阳能波动容易造成吸热器材料热疲劳或表面超温,亟需探索平抑吸热器温度波动的有效途径。开发了一种基于可逆氧化还原反应的锰基热化学热防护涂层,当太阳辐射增强且温度超过978 ℃时,涂层材料发生还原吸热反应,降低升温速率;当太阳辐射减弱且温度低于878 ℃时,发生氧化放热反应,减缓降温速率,进而平抑吸热器表面温度波动。研究表明:涂层材料与黏结剂的质量比为4:3时附着力可达国家标准的最高级,太阳光加权平均吸收率达到94.93%;在950 ℃恒温老化500 h、冷热交变老化100次循环以及氧化还原反应试验200次循环后,涂层加权平均吸收率仅分别衰减0.82百分点、0.98百分点和2.61百分点,且附着力保持在最高级;在±9.7 kW/m2的聚光辐射能流突变条件下,前100 s升温和降温速率分别降低59.66%和67.09%,升温和降温20 ℃所需的时间分别延长182.50%和438.60%。锰基热化学涂层表现出优秀的抗老化性能,并能有效平抑吸热器的温度波动,在塔式光热布雷顿循环系统中具有广阔的应用前景。
热化学材料  /  涂层  /  太阳能吸热器  /  热防护
The Brayton cycle-based tower solar thermal power system features a flexible layout and operates at high receiver temperatures. However, fluctuations in solar irradiance can lead to thermal fatigue of receiver materials or excessive surface temperatures, necessitating effective strategies to mitigate temperature fluctuations. This study develops a manganese-based thermochemical thermal protection coating utilizing a reversible redox reaction. When solar radiation intensifies and the temperature exceeds 978 ℃, the coating undergoes a reduction endothermic reaction, reducing the heating rate. Conversely, when solar radiation decreases and the temperature drops below 878 ℃, an oxidation exothermic reaction occurs, slowing the cooling rate, thereby stabilizing receiver surface temperature fluctuations. Experimental results indicate that when the mass ratio of the coating material to the binder is 4:3, the adhesion strength reaches the highest national standard level, and the solar weighed average absorptivity achieves 94.93%. After undergoing 500 hours of thermal aging at 950 ℃, 100 cycles of thermal cycling, and 200 cycles of redox reaction tests, the coating’s weighed average absorptivity decreased by only 0.82, 0.98, and 2.61 percentage points, respectively, while maintaining the highest adhesion strength. Under a sudden change in concentrated solar radiation flux of ±9.7 kW/m², the heating and cooling rates in the first 100 seconds were reduced by 59.66% and 67.09%, respectively. Additionally, the time required for a 20 ℃ increase and decrease was extended by 182.50% and 438.60%, respectively. The manganese-based thermochemical coating demonstrates excellent aging resistance and effectively suppresses absorber temperature fluctuations, making it highly promising for applications in Brayton cycle-based tower solar thermal power systems.
thermochemical material  /  coating  /  solar receiver  /  thermal protection
张 添, 刘 静, 孙田津, 石丽萍, 胡 锐, 帅 威, 何艺彬, 祝培旺, 肖 刚. 平抑太阳能波动的高温吸热器锰基热化学涂层性能优化. 热力发电, 2026 , 55 (1) : 113 -121 . DOI: 10.19666/j.rlfd.202503041
. Performance optimization of Mn-based thermochemical coating for high-temperature receivers to dampen solar irradiance fluctuations[J]. Thermal Power Generation, 2026 , 55 (1) : 113 -121 . DOI: 10.19666/j.rlfd.202503041
  • 内蒙古自治区“揭榜挂帅”项目
  • 国家杰出青年基金项目
2026年第55卷第1期
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doi: 10.19666/j.rlfd.202503041
  • 接收时间:2025-03-15
  • 首发时间:2026-06-10
  • 出版时间:2026-01-25
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  • 收稿日期:2025-03-15
  • 修回日期:2025-04-07
  • 录用日期:2025-04-17
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内蒙古自治区“揭榜挂帅”项目
国家杰出青年基金项目
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    1.浙江 杭州 310027
    2.新疆 克拉玛依 834000
    3.浙江大学能源高效清洁利用全国重点实验室
    4.中国石油新疆油田分公司采油工艺研究院
    5.杭州华源前线能源设备有限公司
    6.浙江大学青山湖能源研究基地
    7.浙江 杭州 310030
    8.浙江 杭州 311300
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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