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columnId=null, journalTitle=热力发电, columnName=null, runingTitle=null, highlight=null, articleAbstract=燃煤烟气中CO2与N2的高效资源化利用是推动能源系统低碳转型的重要途径。电化学法耦合烟气中CO2与N2直接合成尿素，可在温和条件下将温室气体转化为高附加值化肥，兼具碳减排与资源循环双重效益。系统综述了该领域近期进展，通过异质结、导电MOF等新型催化剂设计优化反应路径，实现N2与CO2协同活化及C-N偶联效率提升，最高尿素法拉第效率达48%；未来突破需聚焦仿生催化材料开发、光-电耦合系统集成以及绿电驱动下碳捕集-转化-产物分离一体化工艺创新；从技术原理、工程挑战及产业衔接层面，论证了电催化尿素合成在煤电碳氮协同治理中的关键作用，为推进其规模化应用提供前瞻性策略思考。, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, 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