Article(id=1236372360723493850, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1236372356109751006, articleNumber=null, orderNo=null, doi=10.19666/j.rlfd.202505075, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1747324800000, receivedDateStr=2025-05-16, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1772703741484, onlineDateStr=2026-03-05, pubDate=1756051200000, pubDateStr=2025-08-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1772703741484, onlineIssueDateStr=2026-03-05, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1772703741484, creator=13701087609, updateTime=1772703741484, updator=13701087609, issue=Issue{id=1236372356109751006, tenantId=1146029695717560320, journalId=1210938733613449225, year='2025', volume='54', issue='8', pageStart='1', pageEnd='174', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1772703740384, creator=13701087609, updateTime=1772788131769, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1236726319342481872, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1236372356109751006, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1236726319342481873, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1236372356109751006, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=124, endPage=130, ext={EN=ArticleExt(id=1236372361038066661, articleId=1236372360723493850, tenantId=1146029695717560320, journalId=1210938733613449225, language=EN, title=Effect of co-firing hydrogen/ammonia on nitrogen oxides emissions from boilers, columnId=1236372358878000047, journalTitle=Thermal Power Generation, columnName=Carbon neutral fuel coupled combustion and emission control, runingTitle=null, highlight=null, articleAbstract=
The effect of co-firing hydrogen/ammonia on nitrogen oxides emissions from boilers is investigated. The reaction kinetics file is modified based on coal quality analysis and experimental results. A psr reactor network based on CFD simulation results is constructed according to the fluid dynamics (CFD) simulation results. Combing with the chemical reaction kinetics analysis method, the NOx emissions after burning hydrogen/ ammonia at four positions of primary air, peripheral air, secondary air and post secondary air in five schemes are analyzed. The results show that, for the researched boiler, when the hydrogen co-firing position is located in the secondary air scheme, and the hydrogen mixing ratio is 20%, the NO emission reduces by 32.4%, and the emission concentration of unburned carbon does not change much compared to the pure coal condition. When the ammonia co-firing position is located behind the secondary air, the NO emission mass concentration is slightly higher than that under the pure coal condition, and the emission mass concentration of unburned carbon reduces significantly. The above two schemes are recommended for co-firing hydrogen/ammonia in the coal-fired boiler, with nitrogen oxide emissions as the evaluation index. This method and conclusion provides a theoretical basis for the engineering implementation of hydrogen/ammonia co-firing technology.
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x排放的影响, columnId=1236372359070938034, journalTitle=热力发电, columnName=碳中性燃料耦合燃烧与排放控制, runingTitle=null, highlight=null, articleAbstract=
分析某600 MW燃煤机组掺烧氢/氨对NOx排放的影响。根据煤质分析及试验结果修正反应动力学文件,根据流体动力学(CFD)模拟结果构建完全搅拌全混流反应器(perfectly stirred reactor,psr)反应器网络,结合采用化学反应动力学分析方法,对锅炉在一次风、周界风、二次风、二次风后4个位置的5个方案,分别掺烧氢/氨后的NOx排放进行分析,结果表明:对于所研究的锅炉,氢气掺烧位置位于二次风方案,掺氢20%工况,NO降低32.4%、未燃尽碳排放量与纯煤工况相当;氨气掺烧位置位于二次风后方案,NO排放量略高于纯煤工况,未燃尽碳排放量显著减小。上述2个方案是该锅炉以NOx排放作为评价指标的掺氢/氨燃烧的推荐方案。该方法和结论可为掺烧氢/氨技术的工程实施提供设计依据。
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张波(1977),男,博士,正高级工程师,主要研究方向为燃烧过程反应动力学及流体动力学分析,zhangbo@tpri.com.cn。
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张波(1977),男,博士,正高级工程师,主要研究方向为燃烧过程反应动力学及流体动力学分析,zhangbo@tpri.com.cn。
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Structural diagram of the combustion system, figureFileSmall=G33Asld3qup7z4lxSYt/jg==, figureFileBig=+ShU9ySEvEA52SFNiQf44A==, tableContent=null), ArticleFig(id=1236372367837032862, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图1, caption=
燃烧系统结构, figureFileSmall=G33Asld3qup7z4lxSYt/jg==, figureFileBig=+ShU9ySEvEA52SFNiQf44A==, tableContent=null), ArticleFig(id=1236372368055136677, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.2, caption=
Streamlines and residence time, figureFileSmall=LuDcHkkkTPm9GgveE6h1+Q==, figureFileBig=GIkQJlLSDIxzHA50XL7sHg==, tableContent=null), ArticleFig(id=1236372368164188588, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图2, caption=
气流流线及停留时间, figureFileSmall=LuDcHkkkTPm9GgveE6h1+Q==, figureFileBig=GIkQJlLSDIxzHA50XL7sHg==, tableContent=null), ArticleFig(id=1236372368277434800, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.3, caption=
The psr analysis network, figureFileSmall=Lp8RIAHCqqt2bR4LXKE9nw==, figureFileBig=iFmZSLZ4/RK9GdcMBCBjjQ==, tableContent=null), ArticleFig(id=1236372368373903796, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图3, caption=
psr分析网络, figureFileSmall=Lp8RIAHCqqt2bR4LXKE9nw==, figureFileBig=iFmZSLZ4/RK9GdcMBCBjjQ==, tableContent=null), ArticleFig(id=1236372368478761403, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.4, caption=
Schematic diagram of four hydrogen/ammonia doping positions, figureFileSmall=QvsTHGNYhaa6MNy4cPvR9w==, figureFileBig=bY5J+x7WNsWFvvjw21iTlQ==, tableContent=null), ArticleFig(id=1236372368726225343, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图4, caption=
4个掺氢/氨位置示意, figureFileSmall=QvsTHGNYhaa6MNy4cPvR9w==, figureFileBig=bY5J+x7WNsWFvvjw21iTlQ==, tableContent=null), ArticleFig(id=1236372368835277254, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.5, caption=
NO volume fractions after hydrogen blending, figureFileSmall=s08ptoJk8BmYp/10PvVeig==, figureFileBig=2l6nSuw0+PsQ+dUK44r3YQ==, tableContent=null), ArticleFig(id=1236372368961106378, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图5, caption=
掺氢后NO体积分数, figureFileSmall=s08ptoJk8BmYp/10PvVeig==, figureFileBig=2l6nSuw0+PsQ+dUK44r3YQ==, tableContent=null), ArticleFig(id=1236372369074352590, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.6, caption=
The NO volume fractions in different areas of the furnace with hydrogen mixing ratio of 20%, figureFileSmall=+q20wT9UUlnVbT/dyMnmBA==, figureFileBig=BV0dCs8BqoOPY2gY/3Up2A==, tableContent=null), ArticleFig(id=1236372369212764628, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图6, caption=
掺氢20%炉内不同区域NO体积分数, figureFileSmall=+q20wT9UUlnVbT/dyMnmBA==, figureFileBig=BV0dCs8BqoOPY2gY/3Up2A==, tableContent=null), ArticleFig(id=1236372369351176667, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.7, caption=
Emission mass concentrations of the unburned carbon after hydrogen blending, figureFileSmall=7+vPf7WZxWyHL7pOOf45kw==, figureFileBig=+8sn/eMGpqfG6AlygFKLPQ==, tableContent=null), ArticleFig(id=1236372369464422876, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图7, caption=
掺氢后未燃尽碳排放质量浓度, figureFileSmall=7+vPf7WZxWyHL7pOOf45kw==, figureFileBig=+8sn/eMGpqfG6AlygFKLPQ==, tableContent=null), ArticleFig(id=1236372369565086176, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.8, caption=
H2 emission volume fractions after hydrogen blending in different locations, figureFileSmall=CTACwc0h+DXKyYFTmp6kkg==, figureFileBig=dUzo+Bq5utzrvwe2Sx4vvQ==, tableContent=null), ArticleFig(id=1236372369669943779, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图8, caption=
不同掺烧位置方案H2排放体积分数, figureFileSmall=CTACwc0h+DXKyYFTmp6kkg==, figureFileBig=dUzo+Bq5utzrvwe2Sx4vvQ==, tableContent=null), ArticleFig(id=1236372369778995688, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.9, caption=
The NO emission volume fractions after ammonia blending, figureFileSmall=yMqZopS8OATCZ6sYt6TkPw==, figureFileBig=8APmAVbw3ASX7JNg8V71+g==, tableContent=null), ArticleFig(id=1236372369942573544, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图9, caption=
掺氨后NO排放体积分数, figureFileSmall=yMqZopS8OATCZ6sYt6TkPw==, figureFileBig=8APmAVbw3ASX7JNg8V71+g==, tableContent=null), ArticleFig(id=1236372370076791276, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.10, caption=
The NO volume fractions in different areas of the furnace with ammonia mixing ratio of 20%, figureFileSmall=yBp3mmyQykMaQqrPLslSpA==, figureFileBig=mChHijuzmel/wKmA19AE2g==, tableContent=null), ArticleFig(id=1236372370194231788, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图10, caption=
掺氨20%炉内不同区域NO体积分数, figureFileSmall=yBp3mmyQykMaQqrPLslSpA==, figureFileBig=mChHijuzmel/wKmA19AE2g==, tableContent=null), ArticleFig(id=1236372370299089393, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.11, caption=
The emission mass concentrations of unburned carbon after ammonia blending in different locations, figureFileSmall=IBDYh3OfjNUtKN6xNX0qQA==, figureFileBig=mgdc3jX6xpl+Pp6ZcgzuVw==, tableContent=null), ArticleFig(id=1236372370412335605, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图11, caption=
不同位置掺氨后未燃尽碳排放质量浓度, figureFileSmall=IBDYh3OfjNUtKN6xNX0qQA==, figureFileBig=mgdc3jX6xpl+Pp6ZcgzuVw==, tableContent=null), ArticleFig(id=1236372370559136249, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Fig.12, caption=
The NH3 emission volume fractions after ammonia blending, figureFileSmall=X+1y6hqPcUek1GvI1W0DQw==, figureFileBig=t2KlUJ0f64Wk4y8hTcvDSw==, tableContent=null), ArticleFig(id=1236372370680771071, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=图12, caption=
掺氨后NH3排放体积分数, figureFileSmall=X+1y6hqPcUek1GvI1W0DQw==, figureFileBig=t2KlUJ0f64Wk4y8hTcvDSw==, tableContent=null), ArticleFig(id=1236372370756268548, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=EN, label=Tab.1, caption=
Coal quality characteristic parameters
, figureFileSmall=null, figureFileBig=null, tableContent=
| 项目 | 设计煤种 | 校核煤种 |
|---|
| 全水分wt(M)/% | 24.81 | 25.13 |
| 空气干燥基水分wad(M)/% | 14.80 | 19.89 |
| 收到基灰分war(A)/% | 10.39 | 9.12 |
| 干燥无灰基挥发分wdaf(V)/% | 37.22 | 39.68 |
| 收到基碳war(C)/% | 52.20 | 50.90 |
| 收到基氢war(H)/% | 2.47 | 2.70 |
| 收到基氧war(O)/% | 8.42 | 10.83 |
| 收到基氮war(N)/% | 0.98 | 0.50 |
| 收到基全硫wt,ar(S)/% | 0.73 | 0.82 |
| 收到基低位发热量Qnet,ar/(MJ·kg–1) | 18.852 | 16.160 |
), ArticleFig(id=1236372370848543239, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1236372360723493850, language=CN, label=表1, caption=
煤质特性参数
, figureFileSmall=null, figureFileBig=null, tableContent=
| 项目 | 设计煤种 | 校核煤种 |
|---|
| 全水分wt(M)/% | 24.81 | 25.13 |
| 空气干燥基水分wad(M)/% | 14.80 | 19.89 |
| 收到基灰分war(A)/% | 10.39 | 9.12 |
| 干燥无灰基挥发分wdaf(V)/% | 37.22 | 39.68 |
| 收到基碳war(C)/% | 52.20 | 50.90 |
| 收到基氢war(H)/% | 2.47 | 2.70 |
| 收到基氧war(O)/% | 8.42 | 10.83 |
| 收到基氮war(N)/% | 0.98 | 0.50 |
| 收到基全硫wt,ar(S)/% | 0.73 | 0.82 |
| 收到基低位发热量Qnet,ar/(MJ·kg–1) | 18.852 | 16.160 |
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