Article(id=1222499162646630682, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1222499161174434087, articleNumber=null, orderNo=null, doi=10.19666/j.rlfd.202302053, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1676908800000, receivedDateStr=2023-02-21, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1769396113310, onlineDateStr=2026-01-26, pubDate=1695571200000, pubDateStr=2023-09-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1769396113310, onlineIssueDateStr=2026-01-26, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1769396113310, creator=13701087609, updateTime=1769396113310, updator=13701087609, issue=Issue{id=1222499161174434087, tenantId=1146029695717560320, journalId=1210938733613449225, year='2023', volume='52', issue='9', pageStart='1', pageEnd='204', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1769396112960, creator=13701087609, updateTime=1769396581892, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1222501128068129514, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1222499161174434087, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1222501128068129515, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1222499161174434087, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=190, endPage=194, ext={EN=ArticleExt(id=1222499164588593444, articleId=1222499162646630682, tenantId=1146029695717560320, journalId=1210938733613449225, language=EN, title=Case analysis and discussion on the influence of temperature compensation in online pH measurement, columnId=1211002409397129992, journalTitle=Thermal Power Generation, columnName=Power generation technology forum, runingTitle=null, highlight=null, articleAbstract=

The pH values of boiler feed water, steam, boiler water and other measuring points in a chemical power plant were abnormally low, and the problem could not be effectively solved by adjusting the boiler water dosing process. In order to solve this problem and ensure the safe operation of the unit, this paper discusses and analyzes the influence of water sample temperature on pH electrode, Nernst temperature coefficient slope and solution temperature coefficient (ionic activity), and verifies through experiments that the abnormally low pH measurement value is caused by the large deviation of water sample temperature from 25 ℃, and the pH measurement method cannot provide correct temperature compensation. Strict control of water sample temperature, adoption of computational pH meter or selection of high-precision pH meter with precise non-linear temperature compensation function can effectively solve the problem of abnormally low pH measurement in the water and steam system.

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某电站锅炉给水、蒸汽、炉水等测点的pH值持续异常偏低，且无法通过调整炉水加药工艺得到有效解决。为此，探讨分析了水样温度对pH电极、能斯特温度系数斜率以及溶液温度系数（离子活度）的影响情况，并通过试验验证了pH测量值异常偏低是由于水样温度偏离25 ℃较大，而pH测量手段无法提供正确的温度补偿造成的。提出通过严格控制水样温度、采用计算型pH仪表或选择有精密非线性温度补偿功能的高精度pH表等手段，可有效解决该机组水汽系统pH测量异常偏低的问题。

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田利（1971），女，硕士，研究员，主要研究方向为电厂化学专业及在线化学监督技术，tianli@tpri.com.cn。

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田利（1971），女，硕士，研究员，主要研究方向为电厂化学专业及在线化学监督技术，tianli@tpri.com.cn。

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