Article(id=1221497394663965530, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1221497393514730153, articleNumber=null, orderNo=null, doi=10.19666/j.rlfd.202212146, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=null, receivedDateStr=null, revisedDate=1670860800000, revisedDateStr=2022-12-13, acceptedDate=null, acceptedDateStr=null, onlineDate=1769157273211, onlineDateStr=2026-01-23, pubDate=1682352000000, pubDateStr=2023-04-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1769157273211, onlineIssueDateStr=2026-01-23, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1769157273211, creator=13701087609, updateTime=1769157273211, updator=13701087609, issue=Issue{id=1221497393514730153, tenantId=1146029695717560320, journalId=1210938733613449225, year='2023', volume='52', issue='4', pageStart='1', pageEnd='166', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1769157272938, creator=13701087609, updateTime=1769157397933, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1221497917878223060, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1221497393514730153, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1221497917878223061, tenantId=1146029695717560320, journalId=1210938733613449225, issueId=1221497393514730153, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=99, endPage=103, ext={EN=ArticleExt(id=1221497394894652253, articleId=1221497394663965530, tenantId=1146029695717560320, journalId=1210938733613449225, language=EN, title=Oxidation mechanism of Incoloy 800H alloy in steam at 675 ℃, columnId=1221467202000175547, journalTitle=Thermal Power Generation, columnName=Thermal energy and science research, runingTitle=null, highlight=null, articleAbstract=

Incoloy 800H is used for high temperature section of heat transfer tubes of the first high temperature gas-cooled reactor nuclear power unit in China, of which the highest design temperature is 675 ℃. The steam oxidation properties of the Incoloy 800H at the design temperature are investigated. The structure of oxide scale of the Incoloy 800H is characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray energy dispersive spectroscopy (EDS). The results show that, the oxidation kinetic curve of the 800H alloy in steam at 675 ℃ is close to the cubic law, namely the cubic of the weight gain is nearly proportional to the oxidation time. The oxide scale has a double-layer structure. The outer layer is mainly composed of Fe3O4, Fe2O3 and a small amount of Ni, and the inner layer is Cr2O3 nanocrystalline with a small amount of Ni, Al2O3 and TiO2 particles distributed in it. Some internal oxide particles of Cr2O3, Al2O3 and TiO2 are distributed in the matrix metal adjacent to the oxide layer.

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Incoloy 800H合金被用于我国首台高温气冷堆核电机组传热管高温段,其最高设计温度达到675 ℃,对其在设计温度下的蒸汽氧化性能进行研究,采用扫描电镜(SEM)、透射电镜(TEM)和X射线能谱(EDS)等表征了Incoloy 800H合金的氧化层结构。试验结果表明:800H合金在675 ℃蒸汽中的氧化动力学曲线接近立方规律,氧化增重的立方与时间接近正比关系。氧化层呈双层结构,外层主要为Fe3O4和Fe2O3及少量Ni,内层为中间分布着少量金属Ni、Al2O3和TiO2颗粒的Cr2O3纳米晶,在邻近氧化层的基体金属中,分布着Cr2O3、Al2O3和TiO2内氧化颗粒。

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唐丽英(1978),女,硕士,正高级工程师,主要研究方向为火电、核电用金属材料性能,

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唐丽英(1978),女,硕士,正高级工程师,主要研究方向为火电、核电用金属材料性能,

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唐丽英(1978),女,硕士,正高级工程师,主要研究方向为火电、核电用金属材料性能,

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Incoloy 800H合金在675 ℃蒸汽中的氧化机理研究
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唐丽英 1 , 詹英杰 2 , 李江 1 , 徐安 2 , 龚兵 2 , 李季 1 , 周荣灿 1 , 王庆武 2
热力发电 | 热能科学研究 2023,52(4): 99-103
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热力发电 | 热能科学研究 2023, 52(4): 99-103
Incoloy 800H合金在675 ℃蒸汽中的氧化机理研究
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唐丽英1 , 詹英杰2, 李江1, 徐安2, 龚兵2, 李季1, 周荣灿1, 王庆武2
作者信息
  • 1.西安热工研究院有限公司,陕西 西安 710054
  • 2.华能山东石岛湾核电有限公司,山东 荣成 264312
  • 唐丽英(1978),女,硕士,正高级工程师,主要研究方向为火电、核电用金属材料性能,

Oxidation mechanism of Incoloy 800H alloy in steam at 675 ℃
Liying TANG1 , Yingjie ZHAN2, Jiang LI1, An XU2, Bing GONG2, Ji LI1, Rongcan ZHOU1, Qingwu WANG2
Affiliations
  • 1.Xi'an Thermal Power Research Institute Co., Ltd., Xi'an 710054, China
  • 2.Huaneng Shandong Shidao Bay Nuclear Power Co., Ltd., Rongcheng 264312, China
出版时间: 2023-04-25 doi: 10.19666/j.rlfd.202212146
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Incoloy 800H合金被用于我国首台高温气冷堆核电机组传热管高温段,其最高设计温度达到675 ℃,对其在设计温度下的蒸汽氧化性能进行研究,采用扫描电镜(SEM)、透射电镜(TEM)和X射线能谱(EDS)等表征了Incoloy 800H合金的氧化层结构。试验结果表明:800H合金在675 ℃蒸汽中的氧化动力学曲线接近立方规律,氧化增重的立方与时间接近正比关系。氧化层呈双层结构,外层主要为Fe3O4和Fe2O3及少量Ni,内层为中间分布着少量金属Ni、Al2O3和TiO2颗粒的Cr2O3纳米晶,在邻近氧化层的基体金属中,分布着Cr2O3、Al2O3和TiO2内氧化颗粒。

Incoloy 800H合金  /  蒸汽氧化  /  氧化动力学  /  氧化层  /  内氧化

Incoloy 800H is used for high temperature section of heat transfer tubes of the first high temperature gas-cooled reactor nuclear power unit in China, of which the highest design temperature is 675 ℃. The steam oxidation properties of the Incoloy 800H at the design temperature are investigated. The structure of oxide scale of the Incoloy 800H is characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray energy dispersive spectroscopy (EDS). The results show that, the oxidation kinetic curve of the 800H alloy in steam at 675 ℃ is close to the cubic law, namely the cubic of the weight gain is nearly proportional to the oxidation time. The oxide scale has a double-layer structure. The outer layer is mainly composed of Fe3O4, Fe2O3 and a small amount of Ni, and the inner layer is Cr2O3 nanocrystalline with a small amount of Ni, Al2O3 and TiO2 particles distributed in it. Some internal oxide particles of Cr2O3, Al2O3 and TiO2 are distributed in the matrix metal adjacent to the oxide layer.

Incoloy 800H alloy  /  steam oxidation  /  oxidation kinetics  /  oxide scale  /  internal oxidation
唐丽英, 詹英杰, 李江, 徐安, 龚兵, 李季, 周荣灿, 王庆武. Incoloy 800H合金在675 ℃蒸汽中的氧化机理研究. 热力发电, 2023 , 52 (4) : 99 -103 . DOI: 10.19666/j.rlfd.202212146
Liying TANG, Yingjie ZHAN, Jiang LI, An XU, Bing GONG, Ji LI, Rongcan ZHOU, Qingwu WANG. Oxidation mechanism of Incoloy 800H alloy in steam at 675 ℃[J]. Thermal Power Generation, 2023 , 52 (4) : 99 -103 . DOI: 10.19666/j.rlfd.202212146
  • 国家科技重大专项(2017ZX06906009)
  • 中国华能集团有限公司总部科技项目(HNKJ18-H41)
2023年第52卷第4期
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doi: 10.19666/j.rlfd.202212146
  • 首发时间:2026-01-23
  • 出版时间:2023-04-25
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  • 修回日期:2022-12-13
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Major National Science and Technology Project(2017ZX06906009)
国家科技重大专项(2017ZX06906009)
Science and Technology Project of China Huaneng Group Co., Ltd.(HNKJ18-H41)
中国华能集团有限公司总部科技项目(HNKJ18-H41)
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    1.西安热工研究院有限公司,陕西 西安 710054
    2.华能山东石岛湾核电有限公司,山东 荣成 264312
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2种不同金属材料的力学参数

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种数
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species
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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