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The Shockley-Queisser (SQ) limit sets an upper limit on the efficiency of conventional semiconductor photovoltaic devices. A thermophotovoltaic system (consisting of a heat source, a spectrally selective emitter and low bandgap photovoltaic cell) can work as an alternative to break this theoretical efficiency limit. To further improve the power generation efficiency of thermophotovoltaic (TPV) systems, an emitter with a multilayer cross structure based on metamaterials was designed in this work. Through optimization of its geometric size, the emitter demonstrates an excellent narrow-band emission spectrum. This effectively reduces the loss of low-energy photons below the bandgap of PV cells and avoids the absorption of high-energy photons that exacerbate lattice vibrations to cause thermal losses. Its application to TPV systems enables a perfect match with In0.69Ga0.31As cells with a bandgap of 0.6 eV. Detailed theoretical calculations of this TPV system show that the power generation efficiency can exceed the Shockley-Queisser (SQ) limit (41%) at 1 117 ℃, and will be further improved as the emitter temperature increases. When the temperature reaches 2 000 K, the efficiency is as high as 46.75%. Additionally, the narrowband emitter shows good angular insensitivity in the range of 0~60 degrees.
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肖克利-奎伊瑟(SQ)极限为常规半导体光伏器件的效率设置了上限。热光伏系统(由热源、光谱选择性辐射器和低禁带光伏电池组成)可以作为一种替代方案,以突破这一理论效率的限制。为提高热光伏系统的发电效率,基于超材料设计了一个多层十字架结构的辐射器,对其几何尺寸优化后,该辐射器展示出良好的窄带发射光谱。这既减少了光伏电池禁带以下的低能光子损失,又避免了高能光子被吸收后加剧晶格振动而造成热损失。将该辐射器用于热光伏系统可以实现与禁带能量为0.6 eV的In0.69Ga0.31As电池完美匹配。通过对该辐射器与光伏电池联用系统的详细理论计算得到:在1 117 ℃下可以实现发电效率突破SQ极限(41%);并且随着辐射器温度升高,发电效率会进一步提高,在2 000 K时电池输出效率高达46.75%;此外,该窄带辐射器在0°~60°内具有良好的角度不敏感性以及极化不敏感性。
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杨建荣(1982),男,高级工程师,主要研究方向为煤化工生产技术,15011965@chnenergy.com.cn。
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杨建荣(1982),男,高级工程师,主要研究方向为煤化工生产技术,15011965@chnenergy.com.cn。
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21(25): 30724-30730., articleTitle=Broadband metamaterial absorber at mid-infrared using multiplexed cross resonators, refAbstract=null)], funds=[Fund(id=1241694391090336369, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, awardId=2017BY049, language=EN, fundingSource=Ningxia Provincial Key Research and Development Program(2017BY049), fundOrder=null, country=null), Fund(id=1241694391165833844, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, awardId=2017BY049, language=CN, fundingSource=宁夏回族自治区2017年重点研发计划项目(沿黄河试验区科技创新专项)(2017BY049), fundOrder=null, country=null), Fund(id=1241694391266497143, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, awardId=2018BCE01004, language=EN, fundingSource=Ningxia Provincial Key Research and Development Program(2018BCE01004), fundOrder=null, country=null), Fund(id=1241694391413297788, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, awardId=2018BCE01004, language=CN, fundingSource=宁夏回族自治区2018年重点研发计划项目(重大科技专项)(2018BCE01004), fundOrder=null, country=null)], companyList=[AuthorCompany(id=1241694382492012768, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, xref=1., ext=[AuthorCompanyExt(id=1241694382504595681, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, companyId=1241694382492012768, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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Schematic diagram of the emitter structure, figureFileSmall=SJMdUHaakHStfZql+ZTMaw==, figureFileBig=ZnsgSr9gXwpTJmfBwk7IYA==, tableContent=null), ArticleFig(id=1241694387789419028, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=CN, label=图1, caption=
辐射器结构示意, figureFileSmall=SJMdUHaakHStfZql+ZTMaw==, figureFileBig=ZnsgSr9gXwpTJmfBwk7IYA==, tableContent=null), ArticleFig(id=1241694387932025371, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=EN, label=Fig.2, caption=
Comparison of numerical simulation results and experimental results for the structure of tungsten nano-photonic metamaterial emitter designed by reference [26], figureFileSmall=ZtCaOUxU9LwserJheAuUKA==, figureFileBig=b5sgAQ/3f9zxnJqO62W3HQ==, tableContent=null), ArticleFig(id=1241694388070437412, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=CN, label=图2, caption=
文献[26]钨纳米光子超材料辐射器结构数值模拟结果与实验结果对比r=0.45 µm、a=1.1 µm、d=1.5 µm
, figureFileSmall=ZtCaOUxU9LwserJheAuUKA==, figureFileBig=b5sgAQ/3f9zxnJqO62W3HQ==, tableContent=null), ArticleFig(id=1241694388187877929, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=EN, label=Fig.3, caption=
Radiation characteristic curves of this designed emitter, figureFileSmall=VeZQ1FaiuyqZmaIjPplwWA==, figureFileBig=O5k4gPyFf1tmlUUfkZUN4A==, tableContent=null), ArticleFig(id=1241694388296929841, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=CN, label=图3, caption=
辐射器辐射特性曲线, figureFileSmall=VeZQ1FaiuyqZmaIjPplwWA==, figureFileBig=O5k4gPyFf1tmlUUfkZUN4A==, tableContent=null), ArticleFig(id=1241694388410176055, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=EN, label=Fig.4, caption=
Efficiency of In0.69Ga0.31As cells at different emitter temperatures, figureFileSmall=6vHqiRJUQws6wM5tMf7DBA==, figureFileBig=I7F/cyF5fs5IGvY47dcu2A==, tableContent=null), ArticleFig(id=1241694388523422268, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=CN, label=图4, caption=
In0.69Ga0.31As电池在不同辐射器温度下的发电效率, figureFileSmall=6vHqiRJUQws6wM5tMf7DBA==, figureFileBig=I7F/cyF5fs5IGvY47dcu2A==, tableContent=null), ArticleFig(id=1241694388619891264, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=EN, label=Fig.5, caption=
The effect of cross size on the emissivity of emitter., figureFileSmall=j32kUXZMa+VzbbEIVq/XgA==, figureFileBig=c3hctj5aXGk+u3wAmFWdcA==, tableContent=null), ArticleFig(id=1241694388733137480, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=CN, label=图5, caption=
十字架尺寸对辐射器辐射率的影响, figureFileSmall=j32kUXZMa+VzbbEIVq/XgA==, figureFileBig=c3hctj5aXGk+u3wAmFWdcA==, tableContent=null), ArticleFig(id=1241694390259864139, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=EN, label=Fig.6, caption=
The effect of the unit period p and h1 on the emissivity of emitter, figureFileSmall=fErBbx5CaP78ohgUglmI4g==, figureFileBig=s23+GSiiY+r9OtV+6hM0pA==, tableContent=null), ArticleFig(id=1241694390360527440, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=CN, label=图6, caption=
超材料辐射器p和h1对辐射器辐射特性的影响, figureFileSmall=fErBbx5CaP78ohgUglmI4g==, figureFileBig=s23+GSiiY+r9OtV+6hM0pA==, tableContent=null), ArticleFig(id=1241694390469579349, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=EN, label=Fig.7, caption=
Electric field distributions on the surface of the emitter, figureFileSmall=0OviTXHO8bio7YhPUN7h/Q==, figureFileBig=0n2PL/oqpkkRON9TFPV01A==, tableContent=null), ArticleFig(id=1241694390595408476, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=CN, label=图7, caption=
辐射器表面电场分布, figureFileSmall=0OviTXHO8bio7YhPUN7h/Q==, figureFileBig=0n2PL/oqpkkRON9TFPV01A==, tableContent=null), ArticleFig(id=1241694390721237599, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=EN, label=Fig.8, caption=
Angle insensitivity of this emitter, figureFileSmall=yoyPQxmePmUsZPbCobZESA==, figureFileBig=gnW/KmeEyWx8Fo1KsuF6mw==, tableContent=null), ArticleFig(id=1241694390918369894, tenantId=1146029695717560320, journalId=1210938733613449225, articleId=1222503117690758094, language=CN, label=图8, caption=
辐射器角度不敏感性, figureFileSmall=yoyPQxmePmUsZPbCobZESA==, figureFileBig=gnW/KmeEyWx8Fo1KsuF6mw==, tableContent=null)], attaches=null, journal=Journal(id=1210938006006558725, delFlag=0, nameCn=热力发电, nameEn=Thermal Power Generation, nameHistory1=null, nameHistory2=null, issn=1002-3364, eissn=null, cn=61-1111/TM, coden=null, periodic=0, language=CN, oaType=null, ccby=null, superviseOffice=null, ownerOffice=null, pubOffice=null, editorOffice=null, officeType=null, aims=null, clcCode=null, officeProv=null, officeCity=null, officeAddr=null, officeZip=null, officeEmail=null, officePhone=null, editDirector=null, officeDirector=null, officeDirectorPhone=null, officeStaffNum=null, officeEmpNum=null, coverPicUrl=YWgAUXbKXZzTw3c+kJbAIA==, journalPrice=null, startedYear=null, abbrevIsoEn=Thermal Power Generation, journalRemark=null, publicationField=null, createdTime=1766639718774, updatedTime=1766640759031, createdBy=18614031015, updatedBy=13701087609, firstLetterCn=T, firstLetterEn=T, 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