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Hydrogen energy has a revolutionary impact on China’s energy structure and consumption system. The hydrogen metallurgy process relying on a hydrogen-based shaft furnace is an effective way to optimize the steel process flow, energy structure, and product structure. It is also a fundamental and disruptive cutting-edge technology for China’s steel industry to achieve carbon neutrality. Based on an overview of the current research and development status of hydrogen metallurgy technologies in China and abroad, this article clarified the prospect of hydrogen metallurgy technologies and analyzed the key issues that constrained the development of the hydrogen-based shaft furnace process in China. On this basis, suggestions for addressing the challenges were proposed.

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氢能对中国能源结构和消费体系产生革命性影响,基于氢基竖炉的氢冶金短流程是优化钢铁工艺流程、能源结构和产品结构的有效途径,是中国钢铁产业实现碳中和的兜底技术和颠覆性前沿技术。文章在概述国内外氢冶金工艺研发现状的基础上,明确氢冶金技术的前景,剖析中国发展氢基竖炉工艺所面临的制约性问题,并提出应对挑战的建议。

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李峰,讲师。主要从事氢冶金关键理论及技术研究。承担国家自然科学基金、国家资助博士后计划、中央高校基本科研业务费等项目8项。发表论文20余篇,授权发明专利10余件。电子信箱:

储满生,教授。东北大学低碳钢铁前沿技术研究院院长,低碳钢铁前沿技术教育部工程研究中心主任,辽宁省低碳钢铁前沿技术工程研究中心主任。国家“万人计划”科技创新领军人才、教育部新世纪人才。主要从事氢冶金、低碳智能化高炉、特色冶金资源高效清洁利用等关键理论及技术研究。主持国家低碳专项、国家高技术研究发展计划、国家自然科学基金、科技部重大国际合作等项目50余项。获省部级科技奖励4项。出版专著6部,发表论文490余篇,授权发明专利60余件。电子信箱:

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李峰,讲师。主要从事氢冶金关键理论及技术研究。承担国家自然科学基金、国家资助博士后计划、中央高校基本科研业务费等项目8项。发表论文20余篇,授权发明专利10余件。电子信箱:

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李峰,讲师。主要从事氢冶金关键理论及技术研究。承担国家自然科学基金、国家资助博士后计划、中央高校基本科研业务费等项目8项。发表论文20余篇,授权发明专利10余件。电子信箱:

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储满生,教授。东北大学低碳钢铁前沿技术研究院院长,低碳钢铁前沿技术教育部工程研究中心主任,辽宁省低碳钢铁前沿技术工程研究中心主任。国家“万人计划”科技创新领军人才、教育部新世纪人才。主要从事氢冶金、低碳智能化高炉、特色冶金资源高效清洁利用等关键理论及技术研究。主持国家低碳专项、国家高技术研究发展计划、国家自然科学基金、科技部重大国际合作等项目50余项。获省部级科技奖励4项。出版专著6部,发表论文490余篇,授权发明专利60余件。电子信箱:

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储满生,教授。东北大学低碳钢铁前沿技术研究院院长,低碳钢铁前沿技术教育部工程研究中心主任,辽宁省低碳钢铁前沿技术工程研究中心主任。国家“万人计划”科技创新领军人才、教育部新世纪人才。主要从事氢冶金、低碳智能化高炉、特色冶金资源高效清洁利用等关键理论及技术研究。主持国家低碳专项、国家高技术研究发展计划、国家自然科学基金、科技部重大国际合作等项目50余项。获省部级科技奖励4项。出版专著6部,发表论文490余篇,授权发明专利60余件。电子信箱:

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2. Institute for Frontier Technologies of Low-Carbon Steelmaking, Northeastern University, Shenyang 110819, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1242113962758705928, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, authorId=1242113962628682500, language=CN, stringName=刘西财, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, 2, address=1.东北大学冶金学院,沈阳 110819
2.东北大学低碳钢铁前沿技术研究院,沈阳 110819, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1242113961512997599, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, xref=null, ext=[AuthorCompanyExt(id=1242113961521386208, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, companyId=1242113961512997599, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1. School of Metallurgy, Northeastern University, Shenyang 110819, China), AuthorCompanyExt(id=1242113961525580513, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, companyId=1242113961512997599, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.东北大学冶金学院,沈阳 110819)]), AuthorCompany(id=1242113961588495074, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, xref=null, ext=[AuthorCompanyExt(id=1242113961596883683, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, companyId=1242113961588495074, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2. Institute for Frontier Technologies of Low-Carbon Steelmaking, Northeastern University, Shenyang 110819, China), AuthorCompanyExt(id=1242113961605272292, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, companyId=1242113961588495074, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.东北大学低碳钢铁前沿技术研究院,沈阳 110819)])])], keywords=[Keyword(id=1242113962892923657, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=EN, orderNo=1, keyword=hydrogen metallurgy), Keyword(id=1242113962947449610, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=EN, orderNo=2, keyword=hydrogen-based shaft furnace), Keyword(id=1242113963001975563, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=EN, orderNo=3, keyword=coke oven gas), Keyword(id=1242113963052307212, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=EN, orderNo=4, keyword=all-hydrogen shaft furnace), Keyword(id=1242113963106833165, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=CN, orderNo=1, keyword=氢冶金), Keyword(id=1242113963165553422, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=CN, orderNo=2, keyword=氢基竖炉), Keyword(id=1242113963215885071, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=CN, orderNo=3, keyword=焦炉煤气), Keyword(id=1242113963278799632, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=CN, orderNo=4, keyword=全氢竖炉)], refs=[Reference(id=1242113966802015022, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2022, volume=null, issue=null, pageStart=null, pageEnd=null, url=https://www.ceads.net.cn/user/search.php?kwtype=0&pagelang=cn&searchtype=titlekeyword&typeid=105&q=2022, language=null, rfNumber=[1], rfOrder=0, authorNames=CEADs Emerging Economy Carbon Dioxide Emissions Report, journalName=null, refType=null, unstructuredReference=CEADs Emerging Economy Carbon Dioxide Emissions Report, 2022. https://www.ceads.net.cn/user/search.php?kwtype=0&pagelang=cn&searchtype=titlekeyword&typeid=105&q=2022., articleTitle=null, refAbstract=null), Reference(id=1242113966869123887, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2024, volume=null, issue=null, pageStart=null, pageEnd=null, url=null, language=null, rfNumber=[2], rfOrder=1, authorNames=Niu W Q, Li Y, Li Q, journalName=Fuel, refType=null, unstructuredReference=Niu W Q, Li Y, Li Q, et al. Physical and chemical properties of metallurgical coke and its evolution in the blast furnace ironmaking process[J]. Fuel, 2024, 366, doi: 10.1016/j.fuel.2024.131277., articleTitle=Physical and chemical properties of metallurgical coke and its evolution in the blast furnace ironmaking process, refAbstract=null), Reference(id=1242113966919455536, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2022, volume=53, issue=6, pageStart=4075, pageEnd=4086, url=null, language=null, rfNumber=[3], rfOrder=2, authorNames=Zhou Y L, Jiang X, Wang X A, journalName=Metallurgical and Materials Transactions B, refType=null, unstructuredReference=Zhou Y L, Jiang X, Wang X A, et al. Optimizing iron ore proportion aimed for low cost by linear programming method[J]. Metallurgical and Materials Transactions B, 2022, 53(6): 4075-4086., articleTitle=Optimizing iron ore proportion aimed for low cost by linear programming method, refAbstract=null), Reference(id=1242113966973981489, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=10.1007/s40831-020-00276-5, pmid=null, pmcid=null, year=2020, volume=6, issue=2, pageStart=307, pageEnd=332, url=null, language=null, rfNumber=[4], rfOrder=3, authorNames=Harvey L D D, journalName=Journal of Sustainable Metallurgy, refType=null, unstructuredReference=Harvey L D D. Analysis of the theoretical and practical energy requirements to produce iron and steel, with summary equations that can be applied in developing future energy scenarios[J]. Journal of Sustainable Metallurgy, 2020, 6(2): 307-332., articleTitle=Analysis of the theoretical and practical energy requirements to produce iron and steel, with summary equations that can be applied in developing future energy scenarios, refAbstract=This paper derives from first principles simple relationships that can be used to compute energy requirements for the production of hot metal (pig iron) in a blast furnace (BF) or direct reduced iron (DRI) in a direct reduction furnace (DRF), and the transformation of hot metal and DRI into crude steel in a basic oxygen furnace (BOF) or electric arc furnace (EAF) with the addition of scrap iron or scrap steel of varying purity. These relationships account for the impact of changing iron ore grade, in the amount and type of impurities in iron, and the impact of the addition of fluxes and the production of slag. Changing proportions of hot metal and scrap to the BOF, or of DRI and scrap to the EAF, are accounted for. The energy flow analysis presented here, combined with the mass flow analysis presented in a companion paper, provides a foundation for tracking the impact on energy use and iron losses of alternative pathways that might be used in the future as part of a broad-based effort to reduce energy use and associated greenhouse gas emissions.), Reference(id=1242113967036896050, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2019, volume=5, issue=3, pageStart=391, pageEnd=401, url=null, language=null, rfNumber=[5], rfOrder=4, authorNames=Mousa E, Lundgren M, Sundqvist Ökvist L, journalName=Journal of Sustainable Metallurgy, refType=null, unstructuredReference=Mousa E, Lundgren M, Sundqvist Ökvist L, et al. Reduced carbon consumption and CO2 emission at the blast furnace by use of briquettes containing torrefied sawdust[J]. Journal of Sustainable Metallurgy, 2019, 5(3): 391-401., articleTitle=Reduced carbon consumption and CO2 emission at the blast furnace by use of briquettes containing torrefied sawdust, refAbstract=null), Reference(id=1242113967095616307, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2022, volume=12, issue=11, pageStart=null, pageEnd=null, url=null, language=null, rfNumber=[6], rfOrder=5, authorNames=Lan C C, Hao Y J, Shao J N, journalName=Metals, refType=null, unstructuredReference=Lan C C, Hao Y J, Shao J N, et al. Effect of H2 on blast furnace ironmaking: A review[J]. Metals, 2022, 12(11), doi: 10.3390/met12111864., articleTitle=Effect of H2 on blast furnace ironmaking: A review, refAbstract=null), Reference(id=1242113967162725172, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2023, volume=15, issue=12, pageStart=null, pageEnd=null, url=null, language=null, rfNumber=[7], rfOrder=6, authorNames=Zhang Z D, Tang J, Shi Q, journalName=Sustainability, refType=null, unstructuredReference=Zhang Z D, Tang J, Shi Q, et al. Effects of shaft tuyere parameters on gas movement behavior and burden reduction in oxygen blast furnace[J]. Sustainability, 2023, 15(12), doi: 10.3390/su15129159., articleTitle=Effects of shaft tuyere parameters on gas movement behavior and burden reduction in oxygen blast furnace, refAbstract=null), Reference(id=1242113967225639733, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2023, volume=30, issue=9, pageStart=1714, pageEnd=1731, url=null, language=null, rfNumber=[8], rfOrder=7, authorNames=Bao J W, Chu M S, Liu Z G, journalName=Journal of Iron and Steel Research International, refType=null, unstructuredReference=Bao J W, Chu M S, Liu Z G, et al. Evolution behavior and mechanism of iron carbon agglomerates under simulated blast furnace smelting conditions[J]. Journal of Iron and Steel Research International, 2023, 30(9): 1714-1731., articleTitle=Evolution behavior and mechanism of iron carbon agglomerates under simulated blast furnace smelting conditions, refAbstract=null), Reference(id=1242113967275971382, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2023, volume=30, issue=9, pageStart=1651, pageEnd=1666, url=null, language=null, rfNumber=[9], rfOrder=8, authorNames=Shi Q, Tang J, Chu M S, journalName=International Journal of Minerals, Metallurgy and Materials, refType=null, unstructuredReference=Shi Q, Tang J, Chu M S. Key issues and progress of industrial big data-based intelligent blast furnace ironmaking technology[J]. International Journal of Minerals, Metallurgy and Materials, 2023, 30(9): 1651-1666., articleTitle=Key issues and progress of industrial big data-based intelligent blast furnace ironmaking technology, refAbstract=null), Reference(id=1242113967343080247, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2016, volume=55, issue=null, pageStart=537, pageEnd=549, url=null, language=null, rfNumber=[10], rfOrder=9, authorNames=Quader M A, Ahmed S, Dawal S Z, journalName=Renewable and Sustainable Energy Reviews, refType=null, unstructuredReference=Quader M A, Ahmed S, Dawal S Z, et al. Present needs, recent progress and future trends of energy-efficient ultra-low carbon dioxide (CO2) steelmaking (ULCOS) program[J]. Renewable and Sustainable Energy Reviews, 2016, 55: 537-549., articleTitle=Present needs, recent progress and future trends of energy-efficient ultra-low carbon dioxide (CO2) steelmaking (ULCOS) program, refAbstract=null), Reference(id=1242113967397606200, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2023, volume=null, issue=null, pageStart=null, pageEnd=null, url=null, language=null, rfNumber=[11], rfOrder=10, authorNames=Shao L, Xu J, Saxén H, journalName=Fuel, refType=null, unstructuredReference=Shao L, Xu J, Saxén H, et al. A numerical study on process intensification of hydrogen reduction of iron oxide pellets in a shaft furnace[J]. Fuel, 2023, 348, doi: 10.1016/j.fuel.2023.128375., articleTitle=A numerical study on process intensification of hydrogen reduction of iron oxide pellets in a shaft furnace, refAbstract=null), Reference(id=1242113967464715065, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=10.1007/s12613-020-2021-4, pmid=null, pmcid=null, year=2020, volume=27, issue=6, pageStart=713, pageEnd=723, url=null, language=null, rfNumber=[12], rfOrder=11, authorNames=Tang J, Chu M S, Li F, journalName=International Journal of Minerals, Metallurgy and Materials, refType=null, unstructuredReference=Tang J, Chu M S, Li F, et al. Development and progress on hydrogen metallurgy[J]. International Journal of Minerals, Metallurgy and Materials, 2020, 27(6): 713-723., articleTitle=Development and progress on hydrogen metallurgy, refAbstract=Hydrogen metallurgy is a technology that applies hydrogen instead of carbon as a reduction agent to reduce CO(2)emission, and the use of hydrogen is beneficial to promoting the sustainable development of the steel industry. Hydrogen metallurgy has numerous applications, such as H(2)reduction ironmaking in Japan, ULCORED and hydrogen-based steelmaking in Europe; hydrogen flash ironmaking technology in the US; HYBRIT in the Nordics; Midrex H-2 (TM) by Midrex Technologies, Inc. (United States); H2FUTURE by Voestalpine (Austria); and SAL-COS by Salzgitter AG (Germany). Hydrogen-rich blast furnaces (BFs) with COG injection are common in China. Running BFs have been industrially tested by AnSteel, XuSteel, and BenSteel. In a currently under construction pilot plant of a coal gasification-gas-based shaft furnace with an annual output of 10000 t direct reduction iron (DRI), a reducing gas composed of 57vol% H(2)and 38vol% CO is prepared via the Ende method. The life cycle of the coal gasification-gas-based shaft furnace-electric furnace short process (30wt% DRI + 70wt% scrap) is assessed with 1 t of molten steel as a functional unit. This plant has a total energy consumption per ton of steel of 263.67 kg standard coal and a CO(2)emission per ton of steel of 829.89 kg, which are superior to those of a traditional BF converter process. Considering domestic materials and fuels, hydrogen production and storage, and hydrogen reduction characteristics, we believe that a hydrogen-rich shaft furnace will be suitable in China. Hydrogen production and storage with an economic and large-scale industrialization will promote the further development of a full hydrogen shaft furnace.), Reference(id=1242113967523435322, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2021, volume=46, issue=17, pageStart=10548, pageEnd=10569, url=null, language=null, rfNumber=[13], rfOrder=12, authorNames=Liu W G, Zuo H B, Wang J S, journalName=International Journal of Hydrogen Energy, refType=null, unstructuredReference=Liu W G, Zuo H B, Wang J S, et al. The production and application of hydrogen in steel industry[J]. International Journal of Hydrogen Energy, 2021, 46(17): 10548-10569., articleTitle=The production and application of hydrogen in steel industry, refAbstract=null), Reference(id=1242113967594738491, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2019, volume=90, issue=10, pageStart=null, pageEnd=null, url=null, language=null, rfNumber=[14], rfOrder=13, authorNames=Spreitzer D, Schenk J, journalName=Steel Research International, refType=null, unstructuredReference=Spreitzer D, Schenk J. Reduction of iron oxides with hydrogen: A review[J]. Steel Research International, 2019, 90(10), doi: 10.1002/srin.201900108., articleTitle=Reduction of iron oxides with hydrogen: A review, refAbstract=null), Reference(id=1242113967649264444, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2018, volume=40, issue=3, pageStart=26, pageEnd=30, url=null, language=null, rfNumber=[15], rfOrder=14, authorNames=魏侦凯, 郭瑞, 谢全安, journalName=华北理工大学学报(自然科学版), refType=null, unstructuredReference=魏侦凯, 郭瑞, 谢全安. 日本环保炼铁工艺COURSE50新技术[J]. 华北理工大学学报(自然科学版), 2018, 40(3): 26-30., articleTitle=日本环保炼铁工艺COURSE50新技术, refAbstract=null), Reference(id=1242113967703790397, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, doi=null, pmid=null, pmcid=null, year=2018, volume=40, issue=3, pageStart=26, pageEnd=30, url=null, language=null, rfNumber=[15], rfOrder=15, authorNames=Wei Z K, Guo R, Xie Q A, journalName=Journal of North China University of Science and Technology (Natural Science Edition), refType=null, unstructuredReference=Wei Z K, Guo R, Xie Q A. COURSE50 new technology of Japan’s environmental ironmaking process[J]. Journal of North China University of Science and Technology (Natural Science Edition), 2018, 40(3): 26-30. 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Compressive strength of oxidized pellets under different ore blending schemes

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序号 1号
铁精矿/%
2号
铁精矿/%
3号
铁精矿/%
抗压强度/
(N·个-1
配料-1 85 0 15 3 432
配料-2 80 10 10 3 401
配料-3 60 10 30 3 366
配料-4 40 10 50 3 208
配料-5 85 15 0 3 394
), ArticleFig(id=1242113966307087144, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=CN, label=表1, caption=

不同配矿方案下氧化球团抗压强度

, figureFileSmall=null, figureFileBig=null, tableContent=
序号 1号
铁精矿/%
2号
铁精矿/%
3号
铁精矿/%
抗压强度/
(N·个-1
配料-1 85 0 15 3 432
配料-2 80 10 10 3 401
配料-3 60 10 30 3 366
配料-4 40 10 50 3 208
配料-5 85 15 0 3 394
), ArticleFig(id=1242113966370001705, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=EN, label=Table 2, caption=

Comparison of oxidized pellet indicators used in hydrogen-based shaft furnace and blast furnace

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球团指标 高炉 氢基竖炉
TFe/% 62 >67
SiO2/% ≈5 ≤2
抗压强度/N 2 000 2 500
还原膨胀/% <20 <15
还原粉化RDI+3.15/% ≥90 ≥95
还原性RI40/(%·min-1 >0.6 0.9~1.4
), ArticleFig(id=1242113966424527658, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=CN, label=表2, caption=

氢基竖炉与高炉用氧化球团指标对比

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球团指标 高炉 氢基竖炉
TFe/% 62 >67
SiO2/% ≈5 ≤2
抗压强度/N 2 000 2 500
还原膨胀/% <20 <15
还原粉化RDI+3.15/% ≥90 ≥95
还原性RI40/(%·min-1 >0.6 0.9~1.4
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Cost comparison of hydrogen production processes

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制氢工艺 氢气成本/(元·Nm-3 生产规模/(Nm3·h-1 备注
电解水制氢 2.5~4.0 10~200
天然气蒸汽重整制氢 0.8~1.5 200~200 000 含炼厂气制氢
石油蒸汽重整制氢 0.7~1.6 500~200 000 含液化气制氢
甲醇裂解制氢 1.8~2.5 50~500
液氨裂解制氢 2.0~2.5 10~200
丙烷脱氢制丙烯副产氢 0.4~0.8 10 000~200 000 含乙烷/丙烷脱氢
钢铁厂尾气副产氢 0.5~1.0 10 000~200 000 含焦化
煤气化制氢 0.6~1.2 1 000~200 000
), ArticleFig(id=1242113966550356780, tenantId=1146029695717560320, journalId=1146032081894723586, articleId=1157002946429936412, language=CN, label=表3, caption=

常见制氢工艺成本对比

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制氢工艺 氢气成本/(元·Nm-3 生产规模/(Nm3·h-1 备注
电解水制氢 2.5~4.0 10~200
天然气蒸汽重整制氢 0.8~1.5 200~200 000 含炼厂气制氢
石油蒸汽重整制氢 0.7~1.6 500~200 000 含液化气制氢
甲醇裂解制氢 1.8~2.5 50~500
液氨裂解制氢 2.0~2.5 10~200
丙烷脱氢制丙烯副产氢 0.4~0.8 10 000~200 000 含乙烷/丙烷脱氢
钢铁厂尾气副产氢 0.5~1.0 10 000~200 000 含焦化
煤气化制氢 0.6~1.2 1 000~200 000
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Current Status, Challenges, and Development Strategies of Hydrogen Metallurgy Technologies in China
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Feng LI 1, 2 , Mansheng CHU 1, 2, , Jue TANG 1, 2 , Zichuan ZHAO 1, 2 , Jin’ge FENG 1, 2 , Xicai LIU 1, 2
Science and Technology Foresight | Review and Commentary 2024,3(4): 44-57
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Science and Technology Foresight | Review and Commentary 2024, 3(4): 44-57
Current Status, Challenges, and Development Strategies of Hydrogen Metallurgy Technologies in China
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Feng LI1, 2 , Mansheng CHU1, 2, , Jue TANG1, 2, Zichuan ZHAO1, 2, Jin’ge FENG1, 2, Xicai LIU1, 2
Authors
  • 1. School of Metallurgy, Northeastern University, Shenyang 110819, China
  • 2. Institute for Frontier Technologies of Low-Carbon Steelmaking, Northeastern University, Shenyang 110819, China

Corresponding author:

Current Status, Challenges, and Development Strategies of Hydrogen Metallurgy Technologies in China
Feng LI1, 2 , Mansheng CHU1, 2, , Jue TANG1, 2, Zichuan ZHAO1, 2, Jin’ge FENG1, 2, Xicai LIU1, 2
Affiliations
  • 1. School of Metallurgy, Northeastern University, Shenyang 110819, China
  • 2. Institute for Frontier Technologies of Low-Carbon Steelmaking, Northeastern University, Shenyang 110819, China
Published: 2024-12-20 doi: 10.3981/j.issn.2097-0781.2024.04.004
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Hydrogen energy has a revolutionary impact on China’s energy structure and consumption system. The hydrogen metallurgy process relying on a hydrogen-based shaft furnace is an effective way to optimize the steel process flow, energy structure, and product structure. It is also a fundamental and disruptive cutting-edge technology for China’s steel industry to achieve carbon neutrality. Based on an overview of the current research and development status of hydrogen metallurgy technologies in China and abroad, this article clarified the prospect of hydrogen metallurgy technologies and analyzed the key issues that constrained the development of the hydrogen-based shaft furnace process in China. On this basis, suggestions for addressing the challenges were proposed.

hydrogen metallurgy  /  hydrogen-based shaft furnace  /  coke oven gas  /  all-hydrogen shaft furnace

Hydrogen energy has a revolutionary impact on China’s energy structure and consumption system. The hydrogen metallurgy process relying on a hydrogen-based shaft furnace is an effective way to optimize the steel process flow, energy structure, and product structure. It is also a fundamental and disruptive cutting-edge technology for China’s steel industry to achieve carbon neutrality. Based on an overview of the current research and development status of hydrogen metallurgy technologies in China and abroad, this article clarified the prospect of hydrogen metallurgy technologies and analyzed the key issues that constrained the development of the hydrogen-based shaft furnace process in China. On this basis, suggestions for addressing the challenges were proposed.

hydrogen metallurgy  /  hydrogen-based shaft furnace  /  coke oven gas  /  all-hydrogen shaft furnace
李峰, 储满生, 唐珏, 赵子川, 冯金格, 刘西财. 中国氢冶金工艺现状、挑战及发展对策[J]. 前瞻科技, 2024 , 3 (4) : 4 -152 . DOI: 10.3981/j.issn.2097-0781.2024.04.004
Feng LI, Mansheng CHU, Jue TANG, Zichuan ZHAO, Jin’ge FENG, Xicai LIU. Current Status, Challenges, and Development Strategies of Hydrogen Metallurgy Technologies in China[J]. Science and Technology Foresight, 2024 , 3 (4) : 4 -152 . DOI: 10.3981/j.issn.2097-0781.2024.04.004
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doi: 10.3981/j.issn.2097-0781.2024.04.004
  • Received:2024-10-15
  • Published:2024-12-20
  • Release:2024-12-24
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  • 收稿日期:2024-10-15
  • 修回日期:2024-11-01
基金
国家自然科学基金(U23A20608)
Authors
    1. School of Metallurgy, Northeastern University, Shenyang 110819, China
    2. Institute for Frontier Technologies of Low-Carbon Steelmaking, Northeastern University, Shenyang 110819, China

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李峰, 储满生, 唐珏, 赵子川, 冯金格, 刘西财. 中国氢冶金工艺现状、挑战及发展对策[J]. 前瞻科技, 2024 , 3 (4) : 4 -152 . DOI: 10.3981/j.issn.2097-0781.2024.04.004
Feng LI, Mansheng CHU, Jue TANG, Zichuan ZHAO, Jin’ge FENG, Xicai LIU. Current Status, Challenges, and Development Strategies of Hydrogen Metallurgy Technologies in China[J]. Science and Technology Foresight, 2024 , 3 (4) : 4 -152 . DOI: 10.3981/j.issn.2097-0781.2024.04.004
表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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