Article(id=1309475094234230829, tenantId=1146029695717560320, journalId=1189873562199433220, issueId=1309475082548896055, articleNumber=null, orderNo=null, doi=10.19710/J.cnki.1003-8817.20260138, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=null, receivedDateStr=null, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1790132791336, onlineDateStr=2026-09-23, pubDate=1787155200000, pubDateStr=2026-08-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1790132791336, onlineIssueDateStr=2026-09-23, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1790132791336, creator=13701087609, updateTime=1790132791336, updator=13701087609, issue=Issue{id=1309475082548896055, tenantId=1146029695717560320, journalId=1189873562199433220, year='2026', volume='', issue='8', pageStart='1', pageEnd='72', issueExtLink='null', onlineDate='null', pubDate='1787155200000', pubDateStr='2026-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1790132788550, creator='13701087609', updateTime=1790132870635, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1309475426930614510, tenantId=1146029695717560320, journalId=1189873562199433220, issueId=1309475082548896055, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1309475426930614511, tenantId=1146029695717560320, journalId=1189873562199433220, issueId=1309475082548896055, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=58, endPage=64, ext={EN=ArticleExt(id=1309475095580602414, articleId=1309475094234230829, tenantId=1146029695717560320, journalId=1189873562199433220, language=EN, title=Study on the Influence of Silane-Modified Trivalent Chromium Passivation on the Corrosion Resistance of Rare Earth Magnesium Alloys, columnId=null, journalTitle=Automobile Technology & Material, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Taking the rare earth magnesium alloy as the research object, an organic-inorganic composite passivation film is prepared by using silane-modified trivalent chromium passivation solution. To investigate the effects of process parameters such as silane concentration and passivation time on the quality and performance of the film, micro-morphology, film thickness, adhesion strength, and neutral salt spray tests are conducted. To investigate the influences of process parameters such as silane concentration and passivation time on the quality and performance of the film, microscopic morphology, film thickness, adhesion force and neutral salt spray test are conducted. The results show that the synergistic mechanism between silane and trivalent chromium could effectively fill the defects of the film, improve the compactness, and thereby enhance the corrosion resistance. The silane concentration is a key factor influencing the density of the film. When the silane concentration is too low, the three-dimensional network structure formed through cross-linking could not fully fill the pores of the passivation film, resulting in limited protective effect; while a reasonable silane concentration is conducive to the formation of a dense and uniform passivation film, effectively blocking the corrosive medium. Compared with not adding silane, the annual corrosion rate of the sample decreases by 65.97% (0.211 mm/a), but the duration of the passivation treatment needs to be controlled to avoid the slight dissolution of the passivation film in the trivalent chromium passivation solution, which would subsequently reduce the protective performance.

, authors=Yingchao Xu, Dan Qi, Linyang Zhang, Boyang Liu, Xinqiao Zhao, Qingzhu Yang, authorsList=Yingchao Xu, Dan Qi, Linyang Zhang, Boyang Liu, Xinqiao Zhao, Qingzhu Yang, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1309475096268468271, articleId=1309475094234230829, tenantId=1146029695717560320, journalId=1189873562199433220, language=CN, title=硅烷改性对三价铬钝化稀土镁合金耐腐蚀性的影响研究, columnId=1190284221747925509, journalTitle=汽车工艺与材料, columnName=材料应用, runingTitle=null, highlight=null, articleAbstract=

以稀土镁合金为研究对象,采用硅烷改性三价铬钝化液,制备有机-无机复合钝化膜,为研究硅烷浓度、钝化时间等工艺参数对膜层质量及性能的影响,进行微观形貌、膜层厚度、结合力及中性盐雾试验。结果表明:硅烷与三价铬的协同机制可有效填补膜层缺陷、改善致密性,从而提升耐腐蚀性能。硅烷浓度是影响膜层致密性的关键因素,当硅烷浓度过低时,交联形成的三维网络结构无法充分填补钝化膜孔隙,防护效果有限;而合理的硅烷浓度有利于形成致密均匀的钝化膜,有效阻挡腐蚀介质,相比不添加硅烷的样品,样品的年腐蚀速率下降了65.97%(0.211 mm/a),但需控制钝化处理时长,避免试样在三价铬钝化液中长时间浸泡导致钝化膜轻微溶解,进而降低防护性能。

, authors=徐英超, 齐丹, 张林阳, 刘博洋, 赵心桥, 杨清竹, authorsList=徐英超, 齐丹, 张林阳, 刘博洋, 赵心桥, 杨清竹, authorCompany=null, correspAuthors=null, authorNote=

徐英超(1997—),女,工程师,博士学位,研究方向为金属材料腐蚀与防护。

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徐英超(1997—),女,工程师,博士学位,研究方向为金属材料腐蚀与防护。

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徐英超(1997—),女,工程师,博士学位,研究方向为金属材料腐蚀与防护。

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硅烷改性对三价铬钝化稀土镁合金耐腐蚀性的影响研究
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徐英超 , 齐丹 , 张林阳 , 刘博洋 , 赵心桥 , 杨清竹
汽车工艺与材料 | 材料应用 2026,(8): 58-64
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汽车工艺与材料 |材料应用 2026 , (8) : 58 -64
硅烷改性对三价铬钝化稀土镁合金耐腐蚀性的影响研究
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徐英超, 齐丹, 张林阳, 刘博洋, 赵心桥, 杨清竹
作者信息
  • 高端汽车集成与控制全国重点实验室,长春 130013
作者简介:

徐英超(1997—),女,工程师,博士学位,研究方向为金属材料腐蚀与防护。

Study on the Influence of Silane-Modified Trivalent Chromium Passivation on the Corrosion Resistance of Rare Earth Magnesium Alloys
Yingchao Xu, Dan Qi, Linyang Zhang, Boyang Liu, Xinqiao Zhao, Qingzhu Yang
Affiliations
  • State Key Laboratory of Advanced Vehicle Integration and Control, Changchun 130013
出版时间: 2026-08-20 doi: 10.19710/J.cnki.1003-8817.20260138
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以稀土镁合金为研究对象,采用硅烷改性三价铬钝化液,制备有机-无机复合钝化膜,为研究硅烷浓度、钝化时间等工艺参数对膜层质量及性能的影响,进行微观形貌、膜层厚度、结合力及中性盐雾试验。结果表明:硅烷与三价铬的协同机制可有效填补膜层缺陷、改善致密性,从而提升耐腐蚀性能。硅烷浓度是影响膜层致密性的关键因素,当硅烷浓度过低时,交联形成的三维网络结构无法充分填补钝化膜孔隙,防护效果有限;而合理的硅烷浓度有利于形成致密均匀的钝化膜,有效阻挡腐蚀介质,相比不添加硅烷的样品,样品的年腐蚀速率下降了65.97%(0.211 mm/a),但需控制钝化处理时长,避免试样在三价铬钝化液中长时间浸泡导致钝化膜轻微溶解,进而降低防护性能。

硅烷改性  /  稀土镁合金  /  钝化  /  耐腐蚀性能

Taking the rare earth magnesium alloy as the research object, an organic-inorganic composite passivation film is prepared by using silane-modified trivalent chromium passivation solution. To investigate the effects of process parameters such as silane concentration and passivation time on the quality and performance of the film, micro-morphology, film thickness, adhesion strength, and neutral salt spray tests are conducted. To investigate the influences of process parameters such as silane concentration and passivation time on the quality and performance of the film, microscopic morphology, film thickness, adhesion force and neutral salt spray test are conducted. The results show that the synergistic mechanism between silane and trivalent chromium could effectively fill the defects of the film, improve the compactness, and thereby enhance the corrosion resistance. The silane concentration is a key factor influencing the density of the film. When the silane concentration is too low, the three-dimensional network structure formed through cross-linking could not fully fill the pores of the passivation film, resulting in limited protective effect; while a reasonable silane concentration is conducive to the formation of a dense and uniform passivation film, effectively blocking the corrosive medium. Compared with not adding silane, the annual corrosion rate of the sample decreases by 65.97% (0.211 mm/a), but the duration of the passivation treatment needs to be controlled to avoid the slight dissolution of the passivation film in the trivalent chromium passivation solution, which would subsequently reduce the protective performance.

Silane modification  /  Rare earth magnesium alloy  /  Passivation  /  Corrosion resistance
徐英超, 齐丹, 张林阳, 刘博洋, 赵心桥, 杨清竹. 硅烷改性对三价铬钝化稀土镁合金耐腐蚀性的影响研究. 汽车工艺与材料, 2026 , (8) : 58 -64 . DOI: 10.19710/J.cnki.1003-8817.20260138
Yingchao Xu, Dan Qi, Linyang Zhang, Boyang Liu, Xinqiao Zhao, Qingzhu Yang. Study on the Influence of Silane-Modified Trivalent Chromium Passivation on the Corrosion Resistance of Rare Earth Magnesium Alloys[J]. Automobile Technology & Material, 2026 , (8) : 58 -64 . DOI: 10.19710/J.cnki.1003-8817.20260138
  • 吉林省、长春市重大科技专项(高性能镁合金开发与制备技术研究)(20250306006ZD)
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doi: 10.19710/J.cnki.1003-8817.20260138
  • 首发时间:2026-09-23
  • 出版时间:2026-08-20
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吉林省、长春市重大科技专项(高性能镁合金开发与制备技术研究)(20250306006ZD)
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    高端汽车集成与控制全国重点实验室,长春 130013
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2种不同金属材料的力学参数
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属数
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genus
种数
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species
占总种数比例
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total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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