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As a core component of high-temperature proton exchange membrane fuel cells, membrane materials determine the commercial viability of hydrogen energy in the commercial vehicle sector, particularly in terms of their high-temperature stability, adaptability under dynamic operating conditions, and cost. Therefore, this paper reviews the technological evolution of high-temperature proton exchange membranes from laboratory research to automotive engineering applications. The performance characteristics and degradation mechanisms of perfluorinated composite membranes, phosphoric acid-doped polybenzimidazole membranes, and novel composite membranes under typical commercial vehicle operating conditions are analyzed. The compatibility bottlenecks between membrane materials and fuel cell systems are examined, along with optimization pathways for better integration. Solutions are proposed from three dimensions: material structural design, preparation process innovation, and system integration synergy. Future development directions, such as digital monitoring and green low-carbon manufacturing, are also discussed.

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膜材料作为高温质子交换膜燃料电池的核心组件,其高温稳定性、动态工况适应性与成本直接决定氢能在商用车领域的商业化进程,因此,梳理了高温质子交换膜从实验室研发到汽车工程化应用的技术演进脉络,分析了全氟复合膜、磷酸掺杂聚苯并咪唑膜及新型复合膜在商用车典型工况下的性能表现与衰减机制,探讨膜材料与燃料电池系统的匹配瓶颈及适配优化路径,从材料结构设计、制备工艺革新与系统集成协同3个维度提出解决方案,并展望了数字化监测、绿色低碳制备等未来发展方向。

, authors=吴磊, authorsList=吴磊, authorCompany=null, correspAuthors=null, authorNote=

吴磊(1993—),男,工程师,硕士学位,研究方向为质子交换膜燃料电池关键材料。

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吴磊(1993—),男,工程师,硕士学位,研究方向为质子交换膜燃料电池关键材料。

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吴磊(1993—),男,工程师,硕士学位,研究方向为质子交换膜燃料电池关键材料。

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高温质子交换膜燃料电池膜材料的应用进展
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吴磊(1993—),男,工程师,硕士学位,研究方向为质子交换膜燃料电池关键材料。

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吴磊(1993—),男,工程师,硕士学位,研究方向为质子交换膜燃料电池关键材料。

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吴磊
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  • 陕西氢能研究院有限公司,西安 712046
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吴磊(1993—),男,工程师,硕士学位,研究方向为质子交换膜燃料电池关键材料。

Progress in Membrane Materials for HT-PEM Fuel Cells
Lei Wu
Affiliations
  • Shaanxi Hydrogen Energy Research Institute Co., Ltd., Xi'an 712046
出版时间: 2026-03-20 doi: 10.19710/J.cnki.1003-8817.20250339
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膜材料作为高温质子交换膜燃料电池的核心组件,其高温稳定性、动态工况适应性与成本直接决定氢能在商用车领域的商业化进程,因此,梳理了高温质子交换膜从实验室研发到汽车工程化应用的技术演进脉络,分析了全氟复合膜、磷酸掺杂聚苯并咪唑膜及新型复合膜在商用车典型工况下的性能表现与衰减机制,探讨膜材料与燃料电池系统的匹配瓶颈及适配优化路径,从材料结构设计、制备工艺革新与系统集成协同3个维度提出解决方案,并展望了数字化监测、绿色低碳制备等未来发展方向。

高温质子交换膜  /  燃料电池汽车  /  动态工况  /  膜电极匹配

As a core component of high-temperature proton exchange membrane fuel cells, membrane materials determine the commercial viability of hydrogen energy in the commercial vehicle sector, particularly in terms of their high-temperature stability, adaptability under dynamic operating conditions, and cost. Therefore, this paper reviews the technological evolution of high-temperature proton exchange membranes from laboratory research to automotive engineering applications. The performance characteristics and degradation mechanisms of perfluorinated composite membranes, phosphoric acid-doped polybenzimidazole membranes, and novel composite membranes under typical commercial vehicle operating conditions are analyzed. The compatibility bottlenecks between membrane materials and fuel cell systems are examined, along with optimization pathways for better integration. Solutions are proposed from three dimensions: material structural design, preparation process innovation, and system integration synergy. Future development directions, such as digital monitoring and green low-carbon manufacturing, are also discussed.

HT-PEM  /  FCV  /  Dynamic operating conditions  /  MEA matching
吴磊. 高温质子交换膜燃料电池膜材料的应用进展. 汽车工艺与材料, 2026 , (3) : 12 -17 . DOI: 10.19710/J.cnki.1003-8817.20250339
Lei Wu. Progress in Membrane Materials for HT-PEM Fuel Cells[J]. Automobile Technology & Material, 2026 , (3) : 12 -17 . DOI: 10.19710/J.cnki.1003-8817.20250339

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doi: 10.19710/J.cnki.1003-8817.20250339
  • 首发时间:2026-09-23
  • 出版时间:2026-03-20
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    陕西氢能研究院有限公司,西安 712046
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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